全文获取类型
收费全文 | 2857篇 |
免费 | 106篇 |
国内免费 | 15篇 |
专业分类
化学 | 1825篇 |
晶体学 | 15篇 |
力学 | 123篇 |
数学 | 438篇 |
物理学 | 577篇 |
出版年
2023年 | 28篇 |
2022年 | 23篇 |
2021年 | 54篇 |
2020年 | 60篇 |
2019年 | 62篇 |
2018年 | 41篇 |
2017年 | 32篇 |
2016年 | 73篇 |
2015年 | 69篇 |
2014年 | 62篇 |
2013年 | 123篇 |
2012年 | 159篇 |
2011年 | 190篇 |
2010年 | 93篇 |
2009年 | 75篇 |
2008年 | 174篇 |
2007年 | 158篇 |
2006年 | 182篇 |
2005年 | 141篇 |
2004年 | 80篇 |
2003年 | 82篇 |
2002年 | 57篇 |
2001年 | 51篇 |
2000年 | 28篇 |
1999年 | 30篇 |
1998年 | 36篇 |
1997年 | 30篇 |
1996年 | 33篇 |
1995年 | 27篇 |
1994年 | 24篇 |
1993年 | 25篇 |
1992年 | 29篇 |
1991年 | 29篇 |
1990年 | 26篇 |
1989年 | 20篇 |
1988年 | 22篇 |
1987年 | 27篇 |
1986年 | 32篇 |
1985年 | 25篇 |
1984年 | 26篇 |
1983年 | 19篇 |
1982年 | 21篇 |
1981年 | 34篇 |
1980年 | 35篇 |
1978年 | 30篇 |
1977年 | 31篇 |
1976年 | 26篇 |
1975年 | 23篇 |
1974年 | 22篇 |
1972年 | 16篇 |
排序方式: 共有2978条查询结果,搜索用时 31 毫秒
161.
Orthorhombic LaFeO3, with spontaneous lattice strain (b - a)/(b + a) = 2.38 × 10−4, is shown by X-ray methods to be ferroelastic. The highly twinned as-grown crystals are detwinned by applying a compressive stress of about 2 MNm−2 along a combined a, b direction. The [010] direction in a single crystal is reproducibly transformable into the [100] direction under uniaxial stress. The resulting ferroelastic transformation is caused by atomic displacements of 0.23 Å for La, 0.48 Å for OI and 0.79 A for OII, the Fe atom remaining invariant at an inversion center. Coupling is expected between the ferroelasticity and the dominant antiferromagnetic spin orientation, but not with the weak ferromagnetism. 相似文献
162.
Extension of the nova model is applied to γ + p → π + anything. The concept of a photon is motivated from vector dominance, and the parameters describing the production of photon novas are estimated from hadron results. The model is essentially without arbitrary parameters. We compare with inclusive and exclusive data at 9.3 GeV/c, where we find excellent agreement. Predictions for 20 GeV/c are also presented. 相似文献
163.
A theory has been given for the scattering of neutrons by anharmonic crystals, for which terms of the typeV
(3) (k
1j1; —k
1j1;o
j) which contribute to the sublattice displacements are not neglected. Using the standard perturbation theory in the interaction
picture or Green’s function method, an expression has been derived for the differential scattering cross-section which brings
in the shift and the width of the phonons in one-phonon energy exchange processes. It is shown that the sublattice displacements
will modify the phase factor arising from the scattering by any atom in the unit cell, and the Debye-Waller factor also gets
altered both by the sublattice displacements as well as by higher order terms arising from anharmonicity. It is shown that
the differential scattering cross-section contains a term linearly depending on the third order anharmonicity coefficientV
(3) (k
1j1;k
2j2;k
3j3) and neutron scattering by crystals should provide a useful method for evaluating the third order anharmonicity coefficients. 相似文献
164.
165.
Jacob Philip 《Journal of Physics and Chemistry of Solids》1980,41(5):461-463
The Grüneisen parameter and lattice thermal expansion of the A-15 compounds V3Si and V3Ge at room temperature are evaluated on the basis of the method due to Brugger and Fritz [1] from the third order elastic constants reported earlier [2]. The calculated values are compared with available experimental values and are found to fit satisfactorily. 相似文献
166.
Abstract— As previously demonstrated, there is a considerable increase in the photodynamic activity of anthraquinone-sulphonic acid on the addition of ethylene glycol, glycerol and sugars in concentrations of the order of 0.4 M . This system exhibits cytostatic activity. With H2 O2 at higher concentrations there is also formation of aldehydes in approximately equivalent yields as follows:
R.CH2 OH+Q → QH2 +R.CHO
QH2 +O2 → Q+H2 O2
In accordance with the recent results of Warburg this accounts for the fundamental importance of glyceraldehyde in cancer research.
Our results on the irradiation of Proteus vulgaris SG2 in buffered medium with the addition of glycerin to anthraquinone-sulphonic acid show the existence of a similar cytostatic effect. One hour's irradiation with visible light reduces the cell count by about 50 per cent. 相似文献
R.CH
QH
In accordance with the recent results of Warburg this accounts for the fundamental importance of glyceraldehyde in cancer research.
Our results on the irradiation of Proteus vulgaris SG2 in buffered medium with the addition of glycerin to anthraquinone-sulphonic acid show the existence of a similar cytostatic effect. One hour's irradiation with visible light reduces the cell count by about 50 per cent. 相似文献
167.
The new method of azulene synthesis, described in the preceding communication, has been extended to the synthesis of guaiazulene and Se-guaiazulene. 相似文献
168.
Jacob Sagiv 《Tetrahedron》1977,33(17):2303-2313
The influence of substitution on the benzenoid 1Lb, 1La and 1B transitions is studied by the technique of linear dichroism in stretched polyethylene films.The total intensity of the 1Lb system is resolved into induced and vibrational components and the influence of various substitution patterns on the magnitude and polarization of both components is analyzed quantitatively. As expected from theoretical considerations, the vibrational components like the induced intensity are found to be strongly affected by the substituent strength and the symmetry of substitution pattern. The previously accepted assumption, according to which the vibrational intensity is regarded as a constant, appears to be completely unrealistic when dealing with cases of strong substituents. A satisfactory quantitative treatment of both weak and strong substituents using the same simple theoretical approach seems possible only if the systematic variations observed in the vibrational intensity are not neglected.A qualitative analysis is given for the 1La, and 1B systems. The results are compared with available theoretical predictions and previous experimental data.Practical implications of the present new experimental information to the study of aromatic optical activity are discussed. 相似文献
169.
G. Grimmer J. Jacob K. W. Naujack G. Dettbarn 《Fresenius' Journal of Analytical Chemistry》1981,309(1):13-19
Summary Polycyclic aromatic hydrocarbons (= PAH), sulphur- and oxygen-containing polycyclic aromatic compounds (= S- resp. O-PAC) which occur in concentrations higher than 1.5 mg/kg in a used motor oil sample originating from a gasoline powered engine were identified by comparison with reference substances (41) or, if reference compounds were lacking, characterized by mass spectrometry (about 110 compounds). Glass-capillary gas-chromatography combined with mass spectrometry was used for this inventory.To obtain a survey of the range of PAC- concentrations in different used oils from gasoline and Diesel fuel powered engines, 50 samples have been examined for a selected number of PAC.Inventory and Biological Impact of Polycyclic Carcinogens in the Environment, Part 13 相似文献
170.
The experimental charge density distribution of dimethyl-trans-2-oxohexahydro-pyrimidine-4,6-dicarboxylate 1 has been determined using single-crystal X-ray diffraction data measured at 100 K, in terms of the rigid-pseudoatom formalism. Multipole refinement converged at R(F) = 0.034 for 7283 reflections with I > 3 sigma (I) and sin theta/lambda < or = 1.13 A(-1). Covalent and hydrogen bonding interactions are analyzed using a topological analysis of the Laplacian of the charge density. The experimentally derived electrostatic potential mapped onto the reactive surface of the molecule reveals the potential binding sites of 1. 相似文献