γ辐照 聚全氟乙丙烯(F46)的电子自旋共振研究 I.真空中俘获自由基的定量研究

A method for determining respectively the concentration of free radicials...CF2-CF2.(RI), ...CF2-CF-CF2...(RII)and...CF2- C(CF3)-CF2...(RIII) trapped in γ-irradiated F46 in vacuum at room temperature by analysing the ESR overlapping spectra is proposed. A quantitative relation between the concentration of free readicals and the total dose of γ-irradiation has been studied. The generating rate o free radicals caused by irradiation, i.e. G-value, has been calculated; it is 2.0 for RIII, 1.2 for RI, and 0.59 for RII. the magnitude of G value of free radicals is in the reverse order of their stability. Hence, we assume that the G value of free radicals in F46 mainly depends on the escaping rate of F2 and other fluorine-containing small molecules from surface of polymer into space. Therefore the looser the molecular chain, the larger becomes the G value of free radical. From that, we consider that both unstable free radicals RIII and RI with larger G-value mainly locate in the amorphous region, and the stable free radical RII with lower G-value is in the crystalline region. Recombinations between free radicals RII and RIII, or between RII and RI are forbidden at the temperature lower than 80C. An explanation for the saturation phenomenon of concentration of free radicals is given.     

THE MEASUREMENT OF THE EXCITATION FUNCTIONS OF ISOTOPES OF Fr AND At,PRODUCED IN THE BOMBARDMENT OF 12C ON 209Bi

Excitation functions for Fr and At isotopes produced in ¹²C on ²⁰⁹Bi had been measured in the energy range 60—72 MeV. It was quite obvious that ²¹³Fr and ²¹⁴Fr were formed by the reactions ²⁰⁹Bi (¹²C,4n) ²¹⁷Ac and ²⁰⁹Bi (¹²C,3n) ²¹⁸Ac following the a decay of the Ac isotopes respectively, and ^214mFr was produced probably by compound nucleus evaporation of neutrons and an α particle, i.e. (¹²C, α 3n). ²¹¹At was mainly contributed by a multi-nucleon transfer reaction （e.g. ⁸Be transfer）. The experimental data for neutron evaporation reaction were fitted by the Jackson formula.     

ChemInform Abstract: Binding of Nitric Oxide to First-Transition-Row Metal Cations: An ab initio Study

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.     

非晶调制多层膜Nb/Si中的互扩散研究

利用原位Ｘ射线衍射技术得到非晶调制多层膜Ｎｂ／Ｓｉ中的互扩散系数与退火温度的关系，调制周期Ｌ＝３.２ｎｍ的非晶调制多层膜是用粒子溅射方法制备的．温度范围为４２３—５２３Ｋ的有效互扩散系数通过原位测量多层膜的一级调制峰强度与退火温度之间的关系而得到．利用缺陷陷阱延迟扩散机制解释了所得到的扩散系数与退火温度的关系．建立了可以解释较小前置系数的模型 关键词：     

Inclined periodic homoclinic breather and rogue waves for the (1+1)-dimensional Boussinesq equation

A new method, homoclinic (heteroclinic) breather limit method (HBLM), for seeking rogue wave solution to nonlinear evolution equation (NEE) is proposed. (1+1)-dimensional Boussinesq equation is used as an example to illustrate the effectiveness of the suggested method. Rational homoclinic wave solution, a new family of two-wave solution, is obtained by inclined periodic homoclinic breather wave solution and is just a rogue wave solution. This result shows that rogue wave originates by the extreme behaviour of homoclinic breather wave in (1+1)-dimensional nonlinear wave fields.     

对数型折射率饱和非线性介质中光孤子高斯型呼吸模式

根据对数型折射率饱和非线性介质中光束尺寸和波阵面曲率变化所遵循的方程,详细描述了空间光孤子高斯型呼吸模式．采用势函数分析方法,对光束尺寸一阶导数的正、负号进行了正确的选择,并计算了呼吸模式的光束尺寸、波阵面曲率半径、呼吸周期等重要参量. 关键词：     

开发趣味实验 培养创新能力

在化学教学中,我们本着为学生未来着想的宗旨,以趣味化学实验为突破口,对学生的创新能力进行培养,收到了良好的效果。     

三元Ⅲ─V半导体合金的基态有序结构

利用了自旋１／２二维Ｉｓｉｎｇ模型及其“不等式方法”,确定了三元Ⅲ─Ｖ半导体会金（００１）面外延生长中的二维平面基态有序结构和基态相图,并通过层状叠加得到了合金中可能出现的长程有序结构,较好地说明了实验发现的（００１）衬底外延生长中的长程有序现象．     

有机薄膜电致发光失效过程的多重分形谱研究

用多重分形谱描述了荧光显微镜原位观察到的有机薄膜电致发光的失效过程.实验观察表明：有机层/金属电极界面上气泡的产生是电致发光的失效的原因.多重分形谱的分析显示：随薄膜工作时间愈长或工作电压愈高,分形谱的宽度愈窄,表明气泡的数量逐渐增加并愈加均匀地分布在界面上,这一结果和实验观察完全一致,因此多重分形谱可以很好地描述这种失效过程.     

高温超导磁悬浮系统中横向运动对悬浮力和导向力影响的研究

高温超导磁悬浮列车在运行过程中，导轨磁场的不连续或者机电耦合会引起车身的横向偏移．针对这一实际问题，本文研究了横向运动对竖直悬浮力和水平导向力的影响．实验中系统同时测试横向运动过程中不断变化悬浮力和导向力．研究发现运动过程中的悬浮力衰减与最大横向偏移量和往返运动次数有关；但导向力在第一次往返运动之后的往返运动中迟滞曲线基本不变．该工作可能为高温超导磁悬浮列车系统提供一定科学依据．