WO3表面的氧缺陷

用不同能量的Ar⁺和H⁺轰击WO₃表面,观察到W_4f峰的位移和加宽。通过谱分解处理得到相应于W_4f电子的W⁶⁺,W⁴⁺和W⁰3个不同的双峰。用表面产生氧缺陷的机理解释了还原过程。UPS谱显示出氧缺陷的存在增加了靠近费密能级处的态密度。H₂O的吸附结果说明WO₃表面的活性与W^{5+< 关键词：}     

自由电子激光放大器频谱振荡现象的研究

本文从单粒子模型出发,导出了考虑相对论能量因子一级扰动量影响的色散方程。结果表明:当入射电子能量足够大时,自由电子激光放大器出现频谱振荡现象,产生这种现象的原因是由于相对论能量因子的扰动作用。文中对此进行了比较详细的讨论。 关键词：     

High power 1.3414 μm Nd:YAP cw laser

The eigen-oscillation mode of the Nd:YAP cw laser has been analysed. The influence of thermal effects arising from the pumping process on the output character of the 1.3414 μm Nd:YAP cw laser has been discussed. The crack problem of the reflective film at a 1.34 μm dielectric mirror has been solved. Based on the aforementioned work, we have been able to achieve an 82.8 W laser output at 1.3414 μm with a nearly polarized beam from a 5.8 mm diameter by 111 mm Nd:YAP rod. The overall efficiency and the slope efficiency are 1.15% and 2.02% respectively, and the fluctuation of the output power at 62 W is less than 1% during continuous operation for 45 min.     

GROWTH CHARACTERISTICS OF DIAMOND FILMS DEPOSITED ON Si AND W SUBSTRATES

Growth characteristics of diamond films synthesized by using a dc arc discharge plasma CVD were studied by means of XRD,SEM and reflection electron diffraction. The results showed that columnar growth of the diamond films was observed, the columns having an average diameter of about 15μm, with sharp and regular base edges. Diamond grains grows on the substrata were initially of uniform polygons. An interfacial transition layer of polycrystalline SiC was observed between the diamond film and Si substrate. Diamond grains grown during the early-stage on W substrate were also uniform, and an interfacial transition layer of polycrystalline WC was observed between the diamond film and the substrate.     

Nd2Fe14B化合物磁晶各向异性起源的理论研究

本文根据Nd₂Fe₁₄B化合物中存有少量巡游电子的基本实验事实,提出了在Nd₂Fe₁₄B中配位子所产生的晶场和巡游电子所产生的电场共同造成了Nd离子磁晶各向异性的理论模型。提出并解决了计算巡游电子同中心Nd离子相互作用的理论方法。在同时考虑Nd离子所受配位子的晶场和巡游电子的电场的作用情况下,用单离子模型计算了Nd₂Fe₁₄B中Nd离子所产生的磁晶各向异性及其随温度的变化。所 关键词：     

顺磁物质CeF3磁光Faraday效应及其温度特性的量子理论

本文计算了顺磁物质CeF₃因Ce³⁺离子从基态能级4f至5d的电偶极跃迁产生的Fara-day旋转。讨论晶场对Ce⁺³离子4f和5d能级的影响,通过唯象地引入一个与磁化强度M成正比的“附加磁场”H_m=λM,由此获得4f离子在外加磁场和“附加磁场”的共同作用下的一级Zeeman分裂。经劈裂后的两个子能级上各自产生左、右圆偏振光激发的电偶极跃迁,导致磁光Faraday效应。对于波长为0.6328μm的入射光,在60—300 关键词：     

一组新型络合物晶体结构与光学性能的研究

研究了二氯三烯丙基硫脲合镉(ATCC),二氯三烯丙基硫脲合汞(ATMC)和二溴三烯丙基硫脲合镉(ATCB)三种晶体的结构特点.首次报道了ATMC和ATCB晶体的非线性光学系数及倍频性能;文中分析比较了三种晶体的非线性光学性能;讨论了晶体结构与性能的关系,为探索高效非线性光学新材料提供依据.     

同步辐射X射线衍射的谐波成分计算

结合动力学衍射公式和同步辐射谱,导出了衍射谐波的计算公式。作为应用的例子,计算了完美Si单晶常用的几个衍射晶面的同步辐射X射线衍射的谐波成分。数据适用于北京正负电子对撞机同步辐射实验室形貌站(4W1A光束线)。结果表明:(333)衍射中谐波成分丰富,而其它衍射中谐波成分较弱。 关键词：