Formation Mechanism and Stability Study of Konjac Glucomannan Helical Structure

The formation mechanism and stability of konjac glucomannan (KGM) helical structure were investigated by molecular dynamic simulation and experimental method. The results indicate that the molecular conformation of KGM is a non-typical helical structure. In detail, helical structure of KGM is mainly sustained by acetyl group, whose size and stability are affected by the molecular polymerization degree of KGM. In vacuum among the non-bonding interactions, electrostatic force is the greatest factor affecting its helical structure, but in water solution, hydrogen bond affects the helical arrangement greatly. To our interest, temperature exhibits a reversible destroying effect to some extent; the helical structure will disappear completely and present a ruleless clew-like arrangement till 341 K. This work suggests that the method of combining molecular dynamic simulation and experiment tools can be effective in the study of KGM helical structure.     

SEBS-g-MAH对LLDPE结晶行为的影响

利用差示扫描量热法结合Avrami方程研究了线性低密度聚乙烯(LLDPE)、LLDPE与苯乙烯-乙烯-丁烯-苯乙烯嵌段共聚物(SEBS)共混体系及LLDPE与不同接枝率的SEBS共聚物接枝马来酸酐(SEBS-g-MAH)共混体系的非等温结晶动力学,探讨了SEBS-g-MAH对LLDPE结晶行为的影响.通过偏光显微镜(POM)观察了各体系的结晶形态.通过Gupta法、Jeziorny法和莫志深法分别对非等温结晶过程进行表征,结果显示:热塑性弹性体SEBS及其接枝物SEBS-g-MAH的加入阻碍了LLDPE分子链的规则排列,影响了链段在结晶扩散迁移过程中的规整排列速率,使得结晶速率变慢,对LLDPE晶体生长起了抑制作用.样品的Avrami指数均为1.1～1.5,说明LLDPE的结晶成核机理和生长方式没有改变.     

熔融织构的YBCO超导体的交流磁化率频率响应

在涡漩玻璃理论的基础上，我们推导出了交流磁化率的虚部峰值温度和频率的标度方程，可表示为Tp=Cf^1/（v（z-1））．实验结果表明我们的标度方程和实验符合得很好．利用标度方程可以确定样品在磁场下的涡漩玻璃转变温度Tg和指数v（z-1）的数值．     

非线性最优化一个可行序列等式约束二次规划算法

本文针对非线性不等式约束优化问题,提出了一个新的可行序列等式约束二次规划算法．在每次迭代中,该算法只需求解三个相同规模且仅含等式约束的二次规划(必要时求解一个辅助的线性规划),因而其计算工作量较小．在一般的条件下,证明了算法具有全局收敛及超线性收敛性．数值实验表明算法是有效的．     

Gd掺杂的Bi系2212相单晶电子状态的X射线光电子能谱研究

利用X射线光电子能谱(XPS)研究了Bi系纯2212相超导单晶和Gd掺杂的2212相绝缘体单晶的电子状态的区别。实验结果表明Gd掺杂引起超导电性的变化是由于D_2p轨道空穴填充引起。本文还对Cu2p_3/2XPS卫星峰与主峰强度之比(I_s/I_m),Bi-O层性质以及Bi系Fermi能级附近态密度的来源等问题进行了讨论。 关键词：     

掺Ba对Bi系2212相超导电性的影响

研究了掺Ｂａ对Bi₂Sr_2-xBa_xCaCu₂O_y（０≤ｘ≤０．１５，０．３）单晶和多晶样品超导电性的影响，结果表明，有少量Ｂａ^２＋离子进入了超导相，且有固溶度极限．对于２２１２相单晶，ｃ轴参数和Ｔ_c均随Ｂａ含量增加而增加；对于慢冷多晶样品，掺Ｂａ可明显提高Ｔ_c；然而对于淬大多晶样品，Ｔ_c没有明显变化，用掺Ｂａ 关键词：     

半无限超晶格的原子均方位移

本文在简立方晶体的简单模型下,应用格林函数方法计算了半无限超晶格中的原子均方位移,并讨论了表面和界面对晶格振动的效应。 关键词：     

J-J型方程的动力行为

本文用严格的数学方法,研究了J-J型方程的动力行为,在β>2/(1+δ)(|(?)|<1)的限制下,问题得到了完全解决。     

Transmission Loss due to Modes Conversion Caused by Random Surface Imperfections in Left-Handed-Material Slab Waveguides

Based on the orthogonality relations among the modes in left-handed-material （LHM） slab waveguides （SWGs）, we derive the coupled equations among the modes caused by imperfect surfaces, and compute the transmission loss due to mode conversion. The computation shows that the transmission loss is very large, which is due to three facts： （1） there exist slow waves in the LHM SWG, whose electric field is mainly distributed in the surface; （2） the absence of fundamental node-less modes, so the fundamental modes have a node, whose electric field is also mainly distributed in the surface, and （3） the different focusing effects of the random RHM and LHM imperfections cause the electric field to suffer from severe deformations aggravated by the electric field distribution of the guided wave and the slow wave, which of course dissipates the power carried by the guided wave more severely. Therefore, we can safely conclude that the LHM SWG is unsuitable for transmitting the fundamental modes with a node.