Pressure effects in a plastic columnar discotic triphenylene

The effect of hydrostatic pressure on the structure of a plastic columnar discotic triphenylene has been investigated. The goal was to determine whether pressure can be used to modify electronic properties via changes in structural properties of columnar discotics to any significant extent. The findings are that (i) the intra- and inter-columnar distances are reduced in a nearly isotropic fashion, (ii) that the crystal sizes are reduced and (iii) that a transition takes place from a more highly ordered plastic columnar to a less ordered hexagonal columnar state with increasing pressure. The induced decrease of the molecular distances, amounting to 6% for pressures up to 17 kbar, are clearly too small to induce an appreciable modification of the electronic structure and thus opto-electronic properties.     

Application of N,N‐bis(diphenylphosphino)aniline palladium(II) complexes as pre‐catalysts in Heck coupling reactions

Palladium(II) complexes with N,N‐bis(diphenylphosphino)aniline ligands catalyse the Heck reaction between styrene and aryl bromides, affording stilbenes in good yield. The structures of two of the complexes used as pre‐catalysts have been determined by single‐crystal X‐ray diffraction. Copyright © 2007 John Wiley & Sons, Ltd.     

QUALITATIVE AND QUANTITATIVE ANALYSIS OF STOCHASTIC PROCESSES BASED ON MEASURED DATA, II: APPLICATIONS TO EXPERIMENTAL DATA

Analysis of stochastic processes governed by the Langevin equation is discussed. The analysis is based on a general method for non-parametric estimation of deterministic and random terms of the Langevin equation directly from given data. Separate estimation of the terms corresponds to the decomposition of process dynamics into deterministic and random components. Part I of the paper presented several possibilities for qualitative and quantitative analysis of process dynamics based on such decomposition. In Part II, some of these analysis possibilities are applied to experimental datasets from metal cutting and laser-beam welding.     

Needle Variations and Almost Lower Semicontinuous Differential Inclusions

It is shown that the construction of needle variations can be carried out for almost lower semicontinuous differential inclusions rather than for the case of ordinary single-valued continuously differentiable vector fields usually considered in the literature. The construction leads to needle variations whose flows are in general set-valued but still have good differentiability properties. The variations are constructed by using single-valued selections that are not necessarily continuous with respect to the state variable, but have instead a much weaker 'integral continuity' property, somewhat more general that the 'directional continuity' considered in previous work by A. Cambini and S. Querci, A. Pucci, and A. Bressan. The existence of many such selections is proved by slightly adapting an argument due to Bressan, extending it from the lower semicontinuous to the almost lower semicontinuous case, and strengthening it to yield not only directional continuity at all points but also full continuity at a specified point.     

Scientific heritage of Boris Lukich Laptev (4/23/05–1/15/89)

Biographical information on the eminent Soviet geometer Boris Lukich Laptev (4/23/05–1/15-89) is given as well as a survey of his research in the areas of differential geometry and history of mathematics.Translated from Itogi Nauki i Tekhniki, Seriya Problemy Geometrii, Vol. 21, pp.27–42, 1989.     

A Second-Order Theory for Electron Plasma Solitary Waves in a Cylindrical Waveguide

To describe the long time asymptotic behaviour of weakly nonlinear plasma waves propagating in a strongly magnetized plasmafilled cylindrical waveguide the usual KDV equation which is first order in wave amplitude is extended to second order including the effects of finite temperature, mobile ions and giving a proper treatment to the radial co-ordinate for all possible modes of propagation. The second-order effects on the first-order solitary wave profile, phase speed and first order correction to the wavelength are all determined and discussed.     

Galactic model of element formation

A cosmological model is presented that produces He, C, O, D, Li, Be, and B in their observed abundances without a Big Bang. The elements are produced during the 1.5-Gy formation period of a galaxy, with C, O, and other heavy elements produced by stars of M>12 M₃ , He by stars of 6 M_s<M<12 M_s, and D, Li, Be, and B by cosmic-ray reactions in a nearly pure H plasma halo. Thus, the model shows that the major elements used in astrophysical studies can be produced during galactic formation by exactly the same processes known to function today at much lower rates     

Adaptive local grid refinement algorithms for finite-element collocation

An adaptive grid refinement procedure allows accurate solutions to advection-dominated, time-dependent flows using finite-element collocation. The technique relies on a data structure that is readily amenable to parallel computing. The paper discusses computational aspects of the method.     

On Critical Stability of Three Quantum Charges Interacting Through Delta Potentials

We consider three one-dimensional quantum, charged and spinless particles interacting through delta potentials. We derive sufficient conditions which guarantee the existence of at least one bound state.