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991.
Electric fields of the anions, cations and neutral forms of 2-aminopurine and 6-thioguanine have been mapped. Certain important
features of the maps are similar to those found earlier in the neutral and ionic forms of adenine and guanine. The computed
electric field patterns satisfactorily explain reactive sites and biological activity of the molecules. 相似文献
992.
P. C. Chen 《中国化学会会志》1995,42(5):755-760
Three ab initio calculations (HF/6-3IG, HF/6-3IG*, and HF/6-3IG**) on 2,4,6-trinitrotoluene were made, The results compare well with xray data, except dihedral angles of NO2 relative to the plane of the benzene ring. The deviations are attributed to packing forces and steric effects in the crystal. The most stable structure was a torsional angle 10° of the methyl top with the benzene ring, unlike toluene. The rotational barriers of the methyl top and the 4-nitro group are small. Hydrogen bonding, dipole moments and total atomic charges arc calculated. 相似文献
993.
The determination of the enantiomeric purity of 2 or 3-substituted cyclanones, particularly cyclohexanones, is conveniently achieved by derivatisation into cyclic aminals with commercially available (R, R)-1,2-diphenylethylenediamine. The derivatisation procedure is directly done into the NMR tube, instantaneously, and 13C NMR allows an accurate measure of the ee. 相似文献
994.
995.
996.
M. E. Movsesyan A. V. Papoyan C. B. Shmavonyan 《Journal of Russian Laser Research》1995,16(2):172-177
The results of the experimental investigation of the radiation amplification due to the stimulated four-photon parametric process in potassium vapor are reported. Two cells with active medium (an oscillatoramplifier system) are used in the experiments. The dominating role of IR radiation 6S → 5P (3.66 µm) in the amplification of violet radiation 5P → 4S (0.4 µm) generated due to the parametric process at two-photon excitation 4S → 6S is shown. This role is conditioned by optically pumped stimulated emission (OPSE). Optical conditions for the amplification of a seed radiation are determined in accordance with their intensity and the buffer gas (He) pressure. The problem of the image conversion from the IR to a visible one with quantum efficiency above 100% is discussed. 相似文献
997.
The article is concerned with a characterization of quasi-symmetric (QS) designs with intersection numbers 0 and y. It uses the idea of a good block. Such a block G has the property that for any block B with |G ∩ B| = y, every point is on a block containing G ∩ B. It is proved that if a QS design II with intersection numbers 0 and y has a good block, then II must (i) be affine, symmetric, a linear space or (ii) have one of two possible exceptional parameter sets. Only one example is known in case (ii). If all blocks of II are good and II is not a linear space, then it is a projective or affine geometry or it is an extension (in a more general sense than usual) of a projective plane of order y2 or y3+ y. © 1995 John Wiley & Sons, Inc. 相似文献
998.
999.
A novel method for measuring AMP-deaminase activity in human erythrocytes is presented, based on the determination of the reaction product, IMP, using high performance liquid chromatography. IMP formation was found to be proportional both to the incubation time and the amount of haemolysate over a wide range. The minimal detectable AMP-deaminase activity was more than 1000 times lower than the mean activity found in healthy controls (1083 nmol/h/mg Hb). No marked difference of activity was found in the patients with the following inherited purine disorders: familial juvenile gouty nephropathy and deficiencies of adenosine deaminase, hypoxanthine-guanine phosphoribosyltransferase or adenine phosphoribosyltransferase. The activity in the erythrocytes of patients with chronic renal failure was also similar to controls. The existence of subjects with low erythrocyte AMP-deaminase activity in the population has been confirmed. 相似文献
1000.
Differential cross sections of nucleons excited in photonuclear reactions in medium and heavy nuclei are studied by considering all relevant reaction mechanisms leading to the excitation of protons or neutrons. We take advantage of previous microscopic studies for the absorption and scattering of photons and photoproduced pions, and implement a simulation code in order to take into account the propagation of the nucleons as well as their collisions with other nucleons in the nuclear medium, which generate secondary excited nucleons. Comparison with experimental data is done. Cross sections for nucleon emission in coincidence with one pion are also calculated, and some coincidence observables are discussed. 相似文献