全文获取类型
收费全文 | 3002篇 |
免费 | 80篇 |
国内免费 | 9篇 |
专业分类
化学 | 2150篇 |
晶体学 | 31篇 |
力学 | 35篇 |
数学 | 318篇 |
物理学 | 557篇 |
出版年
2023年 | 21篇 |
2022年 | 50篇 |
2021年 | 87篇 |
2020年 | 53篇 |
2019年 | 58篇 |
2018年 | 36篇 |
2017年 | 38篇 |
2016年 | 81篇 |
2015年 | 67篇 |
2014年 | 81篇 |
2013年 | 180篇 |
2012年 | 180篇 |
2011年 | 206篇 |
2010年 | 113篇 |
2009年 | 126篇 |
2008年 | 136篇 |
2007年 | 177篇 |
2006年 | 161篇 |
2005年 | 139篇 |
2004年 | 108篇 |
2003年 | 101篇 |
2002年 | 88篇 |
2001年 | 62篇 |
2000年 | 50篇 |
1999年 | 28篇 |
1998年 | 23篇 |
1997年 | 21篇 |
1996年 | 36篇 |
1995年 | 39篇 |
1994年 | 18篇 |
1993年 | 30篇 |
1992年 | 24篇 |
1991年 | 19篇 |
1990年 | 30篇 |
1988年 | 13篇 |
1987年 | 19篇 |
1986年 | 25篇 |
1985年 | 26篇 |
1984年 | 18篇 |
1983年 | 25篇 |
1982年 | 14篇 |
1981年 | 20篇 |
1980年 | 19篇 |
1979年 | 17篇 |
1978年 | 29篇 |
1977年 | 14篇 |
1975年 | 14篇 |
1974年 | 15篇 |
1973年 | 15篇 |
1969年 | 14篇 |
排序方式: 共有3091条查询结果,搜索用时 31 毫秒
11.
Morten Nielsen 《Advances in Computational Mathematics》2007,27(2):195-209
Given a dilation matrix A :ℤd→ℤd, and G a complete set of coset representatives of 2π(A
−Tℤd/ℤd), we consider polynomial solutions M to the equation ∑
g∈G
M(ξ+g)=1 with the constraints that M≥0 and M(0)=1. We prove that the full class of such functions can be generated using polynomial convolution kernels. Trigonometric
polynomials of this type play an important role as symbols for interpolatory subdivision schemes. For isotropic dilation matrices,
we use the method introduced to construct symbols for interpolatory subdivision schemes satisfying Strang–Fix conditions of
arbitrary order.
Research partially supported by the Danish Technical Science Foundation, Grant No. 9701481, and by the Danish SNF-PDE network. 相似文献
12.
A method for the deposition of BN onto graphite and other substrates is described. Boron trichloride (BCl3) and ammonia (NH3) diluted with Ar were used as reacting gases. The deposition process was carried out at 1300 K as well as lower temperatures in an open system at pressures of 1 atm. The consequences of the introduction of hydrogen to the system were considered. It was demonstrated that the replacement of argon with hydrogen increases the efficiency of the process as well as the theoretical rate of BN deposition. However, the acceleration of the deposition seems to be unprofitable, because the resulting supersaturation leads to the formation of an amorphous phase. The modification of the experimental conditions were proposed.Dedicated to Professor Dr. rer. nat. Dr. h.c. Hubertus Nickel on the occasion of his 65th birthday 相似文献
13.
A E Abdel-Megied P Hansen E B Pedersen C M Nielsen 《Acta chemica Scandinavica (Copenhagen, Denmark : 1989)》1991,45(10):1060-1063
The 3'-iodonucleoside 4 and the 3'-O-methylsulfonylthymidine 9 have been synthesized by condensation of silylated uracils 2 with methyl 5-O-tert-butyldiphensilyl-2,3-dideoxy-3-iodo-D-threo-pentofuran oside (3) and methyl 5-O-tert-butyldiphenylsilyl-2-deoxy-3-methylsulfonyl-D-erythro- pentofuranoside (8), respectively. The nucleoside 4 and 9 produced the corresponding 2',3'-didehydro-2',3'-dideoxynucleosides 5 in an elimination reaction on treatment with sodium methoxide. The compounds 5b showed no antiviral activity against HIV-1. 相似文献
14.
Frank Abild-Pedersen Ole Lytken Jakob Engbk Gunver Nielsen Ib Chorkendorff Jens K. Nrskov 《Surface science》2005,590(2-3):127-137
We have, theoretically and experimentally, investigated the dissociation of methane on the terraces and steps of a Ni(1 1 1) surface. Using Density Functional Theory (DFT) total energy calculations combined with Ultra High Vacuum (UHV) experiments, we find that the steps exhibit a higher activity than the terraces. We have, furthermore, investigated how carbon and sulfur present on the surface will deactivate the steps, leaving only the terraces active. We find the intrinsic sticking probabilities of methane on the steps and terraces at 500 K to be 2.8 × 10−7 for the steps and 2.1 × 10−9 for the terraces, in complete agreement with our calculated difference in activation energy of 17 kJ/mol. 相似文献
15.
JPC – Journal of Planar Chromatography – Modern TLC - Emodin and twelve phenolic acids (ellagic, gallic, protocatechuic, homoprotocatechuic, caffeic, p-hydroxybenzoic, p-coumaric,... 相似文献
16.
17.
The title compound (C14H8N2O7,M
r
=306.2) crystallizes in the orthorhombic space group Pbca witha=6.962(1).b=24.688(1), andc=15.890(1)Å,V=2731.0 Å3,D
x
=1.489 g·cm–3 forZ=8,=0.98 mm–1,F(000)=1296,T=293 K. FinalR=0.053 for 1873 observed reflections. The structure was solved by direct methods. Approximately planar molecules lie perpendicular to the [100] direction and show partial stacking. The structure is the first example of a symmetric anhydride which does not retain the symmetry in the crystal state. The two independent nitro groups twist out of the ring planes by 10.5 and 14.8°, respectively. 相似文献
18.
Gajdek P Bober B Mej E Bialczyk J 《Journal of photochemistry and photobiology. B, Biology》2004,76(1-3):103-106
UV radiation was applied to degrade cyanobacterial hepatotoxin, microcystin-LR in the presence of phycocyanin as a model natural sensitiser. The concentrations of both the toxin and the pigment used in the experiments were higher by several orders of magnitude than found in the environment. The photoreaction parameters were optimised. The process was found to be of limited use for water treatment due to its low efficacy. Additionally, pronounced UV-induced bleaching of the pigment significantly reducing the photoreaction rates of the toxin was observed for the highest UV radiation intensities applied. 相似文献
19.
The mechanism of the indium electrodeposition on gold from acidic KBr solutions has been investigated by means of the rotating ring-disc electrode technique. The measurements showed that the overall electrode reaction In(III) + 3 e In consists of two successive charge transfer steps, i.e. In(III) + 2 e In(I) and In(I) + e In, with soluble monovalent indium as an intermediate. The current efficiency for In(I) generation under steady-state conditions is 100% in the case of low disc current densities. The disproportionation of In(I) in the bulk of solution occurs in slightly acidified solutions,pH=2, in addition to the In(I) electrochemical reduction. Based on the ring current transients, it was established that the two-electron transfer step is preceded by the formation of a thin passive film of indium metal.
Untersuchung der elektrochemischen Reduktion von In(III)-Ionen an Gold in sauren Bromidlösungen mit der rotierenden Ring-Scheiben-Elektrode
Zusammenfassung Mit Hilfe der rotierenden Ring-Scheiben-Elektrode wurde der Mechanismus der kathodischen Abscheidung von Indium auf Gold in sauren KBr-Lösungen untersucht. Aus den Messungen folgt, daß die Bruttoreaktion In(III) + 3e In über zwei aufeinanderfolgende Durchtrittsreaktionen, In(III) + 2 e In(I) und In(I) + e In, mit löslichem einwertigem Indium als Zwischenprodukt abläuft. Bei kleinen Stromdichten werden die In(I)-Ionen mit 100%iger Stromausbeute erzeugt. In schwächer sauren Lösungen (pH=2) konnte außer der elektrochemischen Reduktion von In(I) zusätzlich dessen Disproportionierung innerhalb der Lösung ermittelt werden. Auf Grund der Ringstrom-Zeit-Kurven wurde auch festgestellt, daß die Bildung von einer dünnen In-Metallschicht, die ein passives Verhalten aufweist, dem Zweielektronenübergang vorangegangen ist.相似文献
20.