Collective gyromagnetic ratio and moment of inertia from density-dependent Hartree-Fock calculations

The collective gyromagnetic ratio and moment of inertia of deformed even-even axially symmetric nuclei are calculated in the cranking approximation using wave functions obtained with the Skyrme force S-III. Good agreement is found for g_R, while the moment of inertia is about 20 % too small. The cranking formula leads to better agreement than the projection method.     

过氧化物酶催化反应的底物结构的研究

研究了２３种物对过氧化物酶催化过氢氧化佳味醇反应的竞争性抑制作用，提出抑制常数Ｋｉ值的计算方法，并通过对各种物质抑制常数大小的比较和分析，提出了过氧化物酶催化氧化还原反应的最佳底物结构。     

Quasi-steady-state approximations in air pollution modeling: Comparison of two numerical schemes for oxidant prediction

A numerical method to solve the set of differential equations which describes the chemical development in polluted air is presented. The photochemical lifetimes, continuously monitored for all compounds, determine how the integrations are performed at all times. Components with lifetimes less than 10% of the time step, which is taken as 30 sec, are assumed to be in photochemical equilibrium, while compounds with photochemical lifetimes greater than 100 times the time step are computed according to Euler's method. All other components are calculated from the exponential solution of the continuity equation. The computational accuracy may be improved by iteration on components assumed to be determined by the instant values of other components. The convergence of the iteration is speeded up by ordering the short-lived compounds in a hierarchical sequence. Since computational errors connected with QSSA methods are difficult to assess, comparison with an automatic scheme is necessary. Our method has been compared with Gear's method for a range of model mixtures of hydrocarbons, nitrogen oxides, and air, thought to cover most conceivable situations of atmospheric pollution. The agreement with Gear's method is within a few percent for all components all the time, in most cases even within 1%. No accumulation of deviations occur during long-term integrations (e.g., 48 hr with day and night shiftings), and differences which appear during periods with strong concentration gradients (e.g., after sunrise) vanish when the activity has culminated. The method presented here is considerably more efficient than Gear's method, with respect to both computer time and storage.     

Periodic solutions of Hamiltonian equations and a theorem of P. Rabinowitz

The existence of nontrivial orbits with prescribed period is proved by a direct variational method.     

Vibrational spectra oftrans-dichlorodiiodoethylene

The infrared spectra oftrans-dichlorodiiodoethylene as a solid and in solution were recorded in the region 4000–25 cm^–1. Raman spectra of the compound were obtained and semiquantitative polarization data were calculated.The mutual exclusion between the infrared and Raman frequencies are in agreement with the expectedC _2h (2/m) symmetry for this molecule. The fundamentals have been assigned and a normal coordinate analysis carried out. Thermodynamic functions and the root mean square amplitudes of vibration have been obtained.The authors wish to acknowledge financial support from theNorwegian Research Council for Science and the Humanities.     

Front tracking for one-dimensional quasilinear hyperbolic equations with variable coefficients

A new front tracking method is developed for the variable coefficient equation . The method is a generalization of Dafermos' method for the constant coefficient case and is well-defined also for certain discontinuous velocity fields V. We give an explicit inequality stating the stability with respect to flux function, velocity field, and initial data. The numerical method is unconditionally stable and has linear convergence. It is well suited for numerical calculations, as is demonstrated in four examples. This revised version was published online in June 2006 with corrections to the Cover Date.     

热塑性聚氨酯基聚合物电解质的制备与表征

采用非溶剂诱导相转化法（NIPS）制备了热塑性聚氨酯/醋酸纤维素（TPU/CA）新型聚合物隔膜。然后,将隔膜浸入液体电解质中得到TPU/CA凝胶聚合物电解质（GPEs）。研究TPU与CA的质量比对GPEs性能的影响。通过X射线衍射（XRD）、扫描电镜（SEM）、热重（TG）、差示扫描量热（DSC）、线性扫描伏安（LSV）、电化学阻抗（EIS）等对TPU/CA膜进行表征。结果表明,在共混隔膜中引入CA可以降低TPU的结晶度,增加隔膜的吸液率。其中,室温下TPU/CA = 7/3基电解质的离子电导率为1.04 mS·cm^-1,电化学窗口为5.1 V(vs. Li/Li⁺)。组装的电池LiFePO₄/TPU/CA/Li在0.5 C循环100次后,仍具有较高的放电比容量和较好的容量保持率,具有良好的循环稳定性。这些结果表明,这种新型的TPU/CA共混GPEs是锂离子电池的理想选择。     

L/C双波段高功率微波同轴馈源的辐射特性

 设计了一种高功率微波双波段同轴馈源,从理论分析和数值仿真两方面进行了验证。它采用同轴结构馈电,C波段的工作中心频率为4.15 GHz,利用加入轴向波纹的圆波导结构馈电;L波段的工作中心频率为1.75 GHz,利用同轴波导馈电。通过调整外筒半径的大小,可有效抑制低频段高阶模的传输,同时径向波纹结构可有效改善高频段微波的辐射特性。利用模式匹配法和组合散射矩阵理论对馈源结构进行了分析,理论计算和数值仿真结果具有良好的一致性,所设计的双波段馈源结构紧凑,副瓣电平低,E面和H面方向图等化特性良好。