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111.
On the one hand, for a general Calabi–Yau complete intersection X, we establish a decomposition, up to rational equivalence, of the small diagonal in X×X×X, from which we deduce that any decomposable 0-cycle of degree 0 is in fact rationally equivalent to 0, up to torsion. On the other hand, we find a similar decomposition of the smallest diagonal in a higher power of a hypersurface, which provides us an analogous result on the multiplicative structure of its Chow ring. 相似文献
112.
Dr. Marc Devillard Dr. Andreas Ehlers Dr. Maxime A. Siegler Dr. Ir. Jarl Ivar van der Vlugt 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(15):3875-3883
Ligands with reactive carbon sites in the periphery of a metal center have emerged as a powerful approach for metal–ligand bond activation. These reactive carbon sites are commonly generated by deprotonation strategies. Carbon–silicon bond cleavage is a potential alternative to access such constructs. Herein, the monodesilylation of bis-silyl-substituted P,N scaffold PNSi2 in the coordination sphere of [RhI(Cl)(CO)( PNSi2 )] ( 1 ) with sodium azide is disclosed. This affords a unique dinucleating anionic κ2-C,N-κ1-P ligand with a carbanionic methine carbon atom directly bound to rhodium as part of a four-membered Rh-N-C-C rhodacycle. This dimer undergoes meta-pyridine C−H activation facilitated by weak bases, which leads to a desymmetrization of the system and provides a σ,π-bridging 3-pyridyl fragment bound to RhI. The facile Si−C cleavage strategy may pave the way to studying the reactivity and functionalization of a variety of κ2-C,N-coordinated pyridine scaffolds for selective transformations. 相似文献
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Ivar Ekeland 《Milan Journal of Mathematics》2014,82(1):67-79
This is a talk delivered at the conference “Mathematics in a Complex World”, on the occasion of the 150th anniversary of the Politecnico di Milano. Asymmetry of information, i.e. the possibility for human beings to hide their information, or not to keep their promises, is a fundamental fact of social life, and must be taken into account. I will show how this creates complexity, even in the very simple situation of a contract between two parties, one of whom commits to work for the other, but cannot be monitored. 相似文献
117.
In Situ Photocatalytically Heterostructured ZnOAg Nanoparticle Composites as Effective Cathode‐Modifying Layers for Air‐Processed Polymer Solar Cells
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Kai Yuan Prof. Dr. Lie Chen Prof. Dr. Yiwang Chen 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(33):11899-11906
A heterostructured semiconductor–metal ZnO?Ag nanoparticle (NP) composite was constructed through a straightforward photocatalytic strategy by using UV irradiation of ZnO NPs and an aqueous solution of Ag precursor. The ZnO?Ag NP composites serve as an effective cathode‐modifying layer in polymer solar cells (PSCs) with increased short‐circuit current density owing to the light‐trapping effect, and improved optical and electrical conductivity properties compared with pure ZnO NPs. The Ag NPs, which are photodeposited in situ on ZnO NPs, can act as effective antennas for incident light to maximize light harvesting and minimize radiative decay or nonradiative losses, consequently resulting in the enhanced photogeneration of excitons in PSCs. Systematic photoelectron and ‐physical investigations confirm that heterostructured ZnO?Ag NPs can significantly improve charge separation, transport, and collection, as well as lower charge recombination at the cathode interface, leading to a 14.0 % improvement in air‐processed device power conversion efficiency. In addition, this processable, cost‐effective, and scalable approach is compatible with roll‐to‐roll manufacturing of large‐scale PSCs. 相似文献
118.
We present the single-slit diffraction of the arbitrary vector fields with different parameters m, n, and φ0theoretically and experimentally. The single slit covers the polarization singularity in the center and therefore the influence of the polarization singularity on the diffraction fringes is analyzed. The experimental results which agree well with the simulation results show that the total intensity of the diffraction field is related only to the topological charge m, but the polarization distribution of the diffraction field is related to all the parameters m, n, and φ0. Therefore, the diffraction patterns allow to determine all the parameters of the arbitrary vector fields. 相似文献
119.
Ivar M. McDonald Robert Mate Alicia Ng Hyunsoo Park Richard E. Olson 《Tetrahedron letters》2018,59(8):751-754
Three novel tricyclic diamines (1,7-diazaisoadamantane, 1,5-diazaisoadamantane and 1,6-diazahomobrendane) were prepared. A flexible synthetic strategy was employed which used flat, aromatic azaindoles as the starting materials. The requisite azaindoles were prepared by a tandem Sonogashira coupling/intramolecular cyclization reaction. Ring saturation, appropriate functionalization and intramolecular alkylation provided the three novel tricyclic diamines cores. 相似文献
120.
Synthesis of the previously unreported 1,4-diazaadamantane is described. The overall strategy involves complete saturation of a flat, aromatic heterocycle, appropriate functionalization and intramolecular double alkylation. The alkylation takes place via an iminophosphorane under anhydrous conditions, which produced superior results vs. alkylation of the corresponding primary amine. 相似文献