Visible Channeled Spectra of a Multilayer Wood Filter

The transmission factor of multilayer Wood filters containing quartz and rutile layers was simulated in order to avoid the experimental trials for obtaining optical filters with predicted transmission. The main refractive indices of uniaxial crystals—quartz and rutile—were interferometrically determined and Cauchy constants were obtained by simulation. The transmission factor of optical devices consisting of quartz and rutile layers was simulated using the Maple Program.     

Jordan isomorphisms of generalized structural matrix rings

We describe the sub-bimodules of matrix bimodules over two structural matrix rings. Structural matrix bimodules arise as particular such sub-bimodules, and we discuss when such a bimodule is faithful or indecomposable. As an application, we obtain a large class of rings whose Jordan isomorphisms are either ring isomorphisms or ring anti-isomorphisms. Complete upper block triangular matrix rings over 2-torsion-free indecomposable rings are elements of this class.     

Feedback Stabilization for a Reaction-Diffusion System with Nonlocal Reaction Term

We consider a two-component reaction-diffusion system with a nonlocal reaction term. A necessary condition and a sufficient condition for the internal stabilizability to zero of one of the two components of the solution while preserving the nonnegativity of both components have been established in [6 S. Ani?a , W.-E. Fitzgibbon , and M. Langlais ( 2009 ). Global existence and internal stabilization for a class of predator-prey systems posed on non coincident spatial domains . Discrete Cont. Dynam. Syst. B 11 : 805 – 822 .[Crossref], [Web of Science ®] , [Google Scholar]]. In case of stabilizability, a feedback stabilizing control of harvesting type has been indicated. The rate of stabilization (for the indicated feedback control) is given by the principal eigenvalue of a certain non-selfadjoint operator. A large principal eigenvalue leads to a fast stabilization. The first main goal of this article is to approximate this principal eigenvalue. This is done in two steps. First, we investigate the large-time behavior of the solution to a logistic population dynamics with migration, and next we derive as a consequence a method to approximate the principal eigenvalue. The other main goal is to derive a conceptual iterative algorithm to improve the position of the support of the control in order to get a faster stabilization. Our results apply to prey-predator systems.     

Performance of Pleurotus ostreatus Mushrooms and Spent Substrate for the Biosorption of Cd(II) From Aqueous Solution

The capacities of Pleurotus ostreatus mushroom and spent substrate were evaluated for the biosorption of cadmium (II) from aqueous solution in order to select the most efficient material for bioremediation. The optimum sorption conditions were optimized, including the pH of the aqueous solution, contact time, biomass dosage, initial metal concentration, and temperature. The sorption of cadmium on both biosorbents was also evaluated by several kinetic, equilibrium, and thermodynamic models. The possible heavy metal biosorption mechanisms were evaluated through point of zero charge (pH_pzc), Fourier-transform infrared (FTIR) spectroscopy and scanning electron microscopy coupled with energy dispersive X-ray microanalysis (SEM-EDX). Based on the results of column studies, the effectiveness of the P. ostreatus spent substrate was confirmed as a biosorbent for Cd(II) removal from aqueous solutions.     

Brown HT

Journal of Thermal Analysis and Calorimetry - Thermal behavior of Brown HT food dye was studied in correlation with the physical and biological antioxidant properties. Brown HT’s structure...     

On the Oxidation State of Cu2O upon Electrochemical CO2 Reduction: An XPS Study

The encouraging selectivity of copper oxides for the electroreduction of CO₂ into ethylene and alcohols has led to a vivid debate on the possible relation between their operando (sub-)surface oxidation state (i. e. fully reduced or partially oxidized) and this distinct reactivity. The high roughness of the Cu oxides used in previous studies on this matter adds complexity to this controversy and motivated us to prepare quasi-planar Cu₂O thin films that displayed a CO₂ reduction selectivity similar to that of oxide-derived copper catalysts reported in previous studies. Most importantly, when the post-mortem thin films were transferred for characterization in an air-free environment, X-ray photoelectron spectroscopy measurements confirmed their complete reduction in the course of the CO₂ reduction reaction. Thus, our results indicate that the selectivity of the Cu oxides featured in previous studies stems from their enhanced roughness, highlighting the importance of controlled sample transfer upon post-mortem characterization with ex situ techniques.     

Magnetically induced Freedericksz transition and relaxation phenomena in nematic liquid crystals doped with azo-dyes

A static and dynamic investigation was performed on liquid crystal cells containing pure nematics and nematics doped with an azo-dye (Methyl Orange). It was found that the critical field for magnetic Freedericksz transition was decreased in samples containing the “trans” isomer and increased in those containing the “cis  ” isomer. Changes in the relaxation time _τA${\tau }_A$, _τB${\tau }_B$ intervening when switching on/off the magnetic field were also noticed. A theoretical model was elaborated to explain these phenomena.     

Four-Step Spin Crossover in a New Cyano-Bridged Iron-Silver Coordination Polymer

Spin-crossover complexes with multistep transitions attract much attention due to their potential applications as multi-switches and for data storage. A four-step spin crossover is observed in the new iron(II)-based cyanometallic guest-free framework compound Fe(2-ethoxypyrazine)₂{Ag(CN)₂}₂ during the transition from the low-spin to the high-spin state. A reverse process occurs in three steps. Crystallographic studies reveal an associated stepwise evolution of the crystal structures. Multiple transitions in the reported complex originate from distinct Fe^II sites which exist due to the packing of the ligand with a bulky substituent.