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91.
Manuel María Mahamud 《Applied Surface Science》2007,253(14):6019-6031
In this paper two series of active carbons obtained at different flow rates of the activating agent, CO2, are characterized in order to establish the different mechanisms of pore development during the activation step. This study complements previous works on textural development during the different steps in the process of obtaining active carbons: coal oxidation, coal pyrolysis and char gasification. As the characteristics of the original and intermediate materials are of capital importance in the pore development of active carbons, the properties of the active carbons, precursor chars and coals were considered and analyzed together. Mercury porosimetry and helium picnometry were used to determine classical textural parameters as well as to perform a more detailed study of the pore volume generation during the different conditions of the activation step. Data obtained from the mercury porosimetry determinations was also employed for fractal determinations according to the methodologies proposed by Friesen and Mikula, Zhang and Li and the procedure of Neimark. Average surface fractal dimensions as well as fractal profiles and local surface fractal dimensions were calculated. The use of different flow rates during the activation step produces changes not only in the ordinary textural parameters but also in the fractal characteristics of the active carbons. Activation at higher flow rates leads to smoother fractal profiles and also to lower values of the average surface fractal dimensions of the active carbons. 相似文献
92.
93.
G. De Marzi H.J. TrodahlJ. Bok A. CantareroF. Sapiña 《Solid State Communications》2003,127(4):259-264
We report on the first Raman data of Cu substituted La1−ySryMn1−xCuxO3 (0≤x≤0.10 and 0.17≤y≤0.3, accordingly in order to have the same Mn4+/[Mn4++Mn3+] ratio), collected in the frequency range 100-900 cm−1 and at room temperature, with parallel (ei∥es) and crossed (ei⊥es) polarizations of the incident (ei) and scattered (es) light. Spectra were fitted with a Drude-Lorentz model, and peaks at 190-220 and 430 cm−1, together with two broad structures centered at near 500 and 670 cm−1, have been found. We also have observed that the A1g mode is substantially shifted with increasing Cu substitution. The A1g phonon shift is a linear function of the tolerance factor t and the rhombohedral angle αr, thus following the structural changes of the MnO6 octahedra in the system. 相似文献
94.
A. G. García M. A. Hernndez-Medina 《Journal of Mathematical Analysis and Applications》2003,280(2):221-231
The close relationship between discrete Sturm–Liouville problems belonging to the so-called limit-circle case, the indeterminate Hamburger moment problem and the search of self-adjoint extensions of the associated semi-infinite Jacobi matrix is well known. In this paper, all these important topics are also related with associated sampling expansions involving analytic Lagrange-type interpolation series. 相似文献
95.
96.
SbPO4, a phosphate with a layered structure, was tested as an electrode material for lithium cells spanning the 3.0-0.0 V range. Two main electrochemical processes were detected as extensive plateaus at ca. 1.6 and 0.7 V in galvanostatic measurements. The first process was found to be irreversible, thus excluding a potential intercalation-like mechanism for the reaction and being better interpreted as a decomposition reaction leading to the formation of elemental Sb. This precludes the use of this compound as a cathodic material for lithium cells. By contrast, the process at 0.7 V is reversible and can be ascribed to the formation of lithium-antimony alloys. The best electrochemical response was obtained by cycling the cell at a C/20 discharge rate over the voltage range 1.25-0.25 V. Under these conditions, the cell delivers an average capacity of 165 Ah/kg—a value greater than those reported for other phosphates—upon successive cycling. 相似文献
97.
Nonlocal character of entangled photon pairs generated in spontaneous parametric downconversion is demonstrated. One photon from a pair propagates through a Mach-Zehnder interferometer and is detected in coincidence-count measurement with its twin. Width of the coincidence-count interference pattern (measured for various values of path difference in the Mach-Zehnder interferometer) depends on spectral width of the twin as a result of entanglement of photons in a pair. The experimental setup is analyzed for a Gaussian spectral filter and a Fabry-Perot resonator. It is shown that nonlocal interference is much stronger for cw pumping in comparison with femtosecond pulsed pumping for values of parameters commonly used in spontaneous parametric downconversion experiments. 相似文献
98.
Guido Consonni Piero Veronese Eduardo Gutirrez-Pea 《Journal of multivariate analysis》2004,88(2):335-364
Reference analysis is one of the most successful general methods to derive noninformative prior distributions. In practice, however, reference priors are often difficult to obtain. Recently developed theory for conditionally reducible natural exponential families identifies an attractive reparameterization which allows one, among other things, to construct an enriched conjugate prior. In this paper, under the assumption that the variance function is simple quadratic, the order-invariant group reference prior for the above parameter is found. Furthermore, group reference priors for the mean- and natural parameter of the families are obtained. A brief discussion of the frequentist coverage properties is also presented. The theory is illustrated for the multinomial and negative-multinomial family. Posterior computations are especially straightforward due to the fact that the resulting reference distributions belong to the corresponding enriched conjugate family. A substantive application of the theory relates to the construction of reference priors for the Bayesian analysis of two-way contingency tables with respect to two alternative parameterizations. 相似文献
99.
Francisco Jesús Castro-Jiménez José Marı́a Ucha-Enrı́quez 《Comptes Rendus Mathematique》2004,338(6):461-466
We prove a duality theorem for some logarithmic -modules associated with a class of divisors. We also give some results for the locally quasi-homogeneous case. To cite this article: F.J. Castro-Jiménez, J.M. Ucha-Enr??quez, C. R. Acad. Sci. Paris, Ser. I 338 (2004). 相似文献
100.
F. Tercero J. A. López Fernández E. García L. de Haro M. C. Carter A. Barcia B. Galocha J. L. Besada 《International Journal of Infrared and Millimeter Waves》2003,24(5):669-681
The Beam Mode Expansion (BME) approach for corrugated conical feed horn plus meniscus lens is presented. This approach is useful for providing the radiation pattern as it propagates through an optical system. A developed theoretical model has been verified measuring near and far field of a built horn and lens. These results have been used for designing the optical system of a Cassegrain antenna at 100GHz using the fundamental Gaussian beam mode (GBM) of the new approach. Multimode analysis has been performed with the pre-designed system in order to test the fundamental GBM results. 相似文献