Spezifische Drehung einiger vegetabilischer Prote?ne

Ohne ZusammenfassungAus einem gütigst zugesandten Abdruck aus dem Journal of the American chemical Society25, No. 8, bearbeitet und übersetzt von Dr. Griessmayer.     

Thermo-XRD-analysis and peptization study of the adsorption of alizarinate by Co-, Ni-, and Cu-montmorillonite

The adsorption of the monovalent anionic dye alizarinate onto Co-, Ni- and Cu-montmorillonite was carried out by adding the dye into aqueous clay suspensions. During the loading of the clay suspension by alizarinate, only some of the added organic anion is adsorbed by the clay forming d-coordination chelate complexes on the clay surface. Maximum adsorption of Co-, Ni- and Cu-clay were 13, 13 and 25 mmol dye per 100 g clay. Since the capacity of the clay for these transition metal cations is 38 mmol per 100 g clay, these saturations indicate that only part of the transition metal cations form positively charged d-coordination chelate complexes with metal:ligand ratio of 1. The complex cations can be located inside the interlayer spaces or on the broken bonds surfaces. Thermo-XRD-analysis and peptization studies of the solids and the clay water systems respectively were used here to identify the sorption sites. The Co and Ni complexes were obtained on the broken bonds surfaces whereas the Cu complexes were obtained in the interlayer space. Co²⁺, Ni²⁺ and Cu²⁺ were extracted from the clay into suspensions containing excess alizarinate.     

On the design of open resonators for quasi-optical gyrotrons

In the design of a 120 GHz 200 kW quasi-optical gyrotron, we have analyzed the influence of the open resonator geometry (two circular mirrors facing one another) on the electronic efficiency, the ohmic losses, the output coupling and the multimode behavior. The method we have used to optimized the resonator design will be presented. Mode selectivity is improved by using a resonator formed by two mirrors each of which has a central step. Numerical simulations show that single mode operation can also be attained in the more favorable situation of a magnetic field having a positive taper over the interaction region.     

Observation of particle unstable 4H in pion absorption in 7Li

A particle unstable state of ⁴H has been identified in the reaction $\text{π}{}^{\mathrm{?}}\text{+}{}^7\text{Li}\text{→}{}^4\text{H+t}\text{,}{}^4\text{H}\text{→}\text{t}\text{+π}$ by observing the two emitted tritons. A resonance energy E_Γ=(2.7±0.6) MeV and a reduced width γ²=(2.3±0.6) MeV were deduced, in agreement with the parameters of the ground-state level (J^π=2^?) found in the p-wave of n-t-scattering. The yield per stopped pion is (5.6±1.8)×10^?4. Previous measurements in pion absorption are in disagreement with our results.     

Mild pre-heating of organic cation-exchanged clays enhances their interactions with nitrobenzene in aqueous environment

Aqueous sorption kinetics and equilibrium isotherms of nitrobenzene were studied on two series of sorbents that were prepared by (i) replacing inorganic exchangeable cations in Wyoming bentonite with tetraethylammonium (TEA) and benzyltrimethylammonium (BTMA) and (ii) heating synthesized complexes in air at different temperatures (between 150 and 420°C). The aim of this work was to examine recently observed enhancement of aqueous sorption of a probe organic sorbate on organoclays after mild thermal pre-treatment of sorbents. Thermal pre-treatment of TEA- and BTMA-clays at 150°C results in the maximal enhancement of nitrobenzene–sorbent interactions as compared with treatment of original bentonite and its exchange complexes formed with long-chain quaternary ammonium (n-hexadecyltrimethylammonium, HDTMA). Based on C, N content data and FTIR spectra of TEA- and BTMA-clay complexes, no indications of decomposition of organic matter were found in organoclays heated at 250°C (and below this temperature). Suppressed hydration of pre-heated sorbents resulting in a lessening of water–organic sorbate competition for sorption sites is considered to be responsible for thermally induced enhancement of nitrobenzene–sorbent interactions. In the HDTMA-based organoclays, the long-chain aliphatic groups of the quaternary ammonium can additionally interact with clay surface thus competing with organic sorbate–sorbent surface interactions and, in this way, mitigating the enhancement of nitrobenzene sorption on thermally treated sorbents.     

The reversing number of a diagraph

A minimum reversing set of a diagraph is a smallest sized set of arcs which when reversed makes the diagraph acyclic. We investigate a related issue: Given an acyclic diagraph D, what is the size of a smallest tournament T which has the arc set of D as a minimun reversing set? We show that such a T always exists and define the reversing number of an acyclic diagraph to be the number of vertices in T minus the number of vertices in D. We also derive bounds and exact values of the reversing number for certain classes of acyclic diagraphs.