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51.
The application of micellar electrokinetic capillary chromatography (MECC) to the analysis of illicit drug seizures is presented. Areas investigated include general screening and qualitative and, in some instances, quantitative analysis of various drugs, including heroin, opium, cocaine, amphetamines, LSD and anabolic steroids. Due to its high efficiency, high selectivity and general applicability, MECC is well suited for forensic drug analyses.  相似文献   
52.
We report the results of a comprehensive reinvestigation of the rotational spectrum of diethyl ether based on broadband millimetre-wave spectra recently recorded at The Ohio State University and in Warsaw, covering the frequency region 108-366 GHz. The data set for the ground vibrational state of trans-trans diethyl ether has been extended to over 2000 lines and improved spectroscopic constants have been determined. Rotational spectra in the first excited vibrational states of the three lowest vibrational modes of trans-trans-diethyl ether, ν20, ν39, and ν12 have been assigned. The v20 = 1 and v39 = 1 states are near 100 cm−1 in vibrational term value and are coupled by a strong c-axis Coriolis interaction, which gives rise to many spectacular manifestations in the rotational spectrum. All of these effects have been successfully fitted for a dataset comprising over 3000 transitions, leading to precise determination of the energy difference between these states, (ΔE/hc)=10.400222(5) cm−1. A newly developed software package for assignment and analysis of broadband spectra is described and made available.  相似文献   
53.
The anion radical of 1,2-diphenylcyclobutene was studied by electron spin resonance. The hyperfine splittings were found to be 0·47 and 0·74 G for the meta-positions, 2·23 and 2·69 G for the ortho-positions and 4·21 G for the para-positions of the phenyl rings. The methylene proton splittings were 4·27 G, which would imply that the value of Q is 27 G, much lower than that of other cyclobutene anions. It was also estimated that the angle between the axis of the p-orbitals of the ethylene group and that of the phenyl group is about 30°, in agreement with that found for the tetraphenylethylene anion.  相似文献   
54.
We have designed and operated a positive branch 6.3 mm diameter rod Nd:YAG unstable resonator oscillator with a 12 nsec, 200 mJ Q-switched output at 10 Hz repetition rate. When followed by a single 9 mm diameter Nd:YAG amplifier output energies up to 750 mJ were obtained with a divergence less than 0.5 mrad.  相似文献   
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We count labeled acyclic digraphs according to the number sources, sinks, and edges.  相似文献   
58.
The kinetics of the disappearance of propagating butadiene radicals produced in the grafting of butadiene to poly(vinyl chloride) was followed by electron spin resonance measurements. The radical species observed in the temperature range 213–298°K is the conjugated allylic radical: The reaction conditions were adjusted to provide a highly viscous medium in which the propagation reaction took place. Under these conditions the radicals were stabilized and a precise ESR spectrum was obtained. Arrhenius plots of the second-order decay rate constants yield an activation energy of 5 kcal/mole. This suggests that the bimolecular termination reaction is controlled by the segmental motion of the grafted side chains.  相似文献   
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In this article we have described an invariant imbedding method for calculating the smallest eigenlength of a singular TPBVP with the singularity at the origin. The invariant imbedding yields a first-order nonlinear equation called a Riccati equation and also gives the initial conditions at the origin for this equation. With the aid of Theorem 8 in Section 3 we numerically integrate the Riccati equation to “blowup” which gives our computed eigenlength.In closing, we would like to comment on the numerical merits of the integration-to-blowup technique. On the basis of the examples presented it appears that this technique combined with the available numerical integrators with variable step size is capable of producing accurate results. The feature of a variable step size is essential as the value of z approaches the actual eigenlength. However, it is desirable to have a priori estimate or bounds of the eigenlength similar to those of Boland and Nelson [2] for the nonsingular case. The singular system, however, presents difficulties due to the lack of sign conditions on the coefficient matrices in obtaining such bounds. Hopefully an investigation of the matrix R(z) will yield these results.  相似文献   
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