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711.
Khlebnikova Yu. V. Rodionov D. P. Egorova L. Yu. Suaridze T. R. 《Technical Physics》2018,63(12):1771-1783
Technical Physics - The structure of a hafnium crystal undergoing β → α (bcc → hcp) polymorphic transformation upon gradual cooling and the structure of Hf55Ti45 and Hf30Ti70... 相似文献
712.
Bayirta V. Egorova Lyubov S. Zamurueva Anastasia D. Zubenko Anna V. Pashanova Artem A. Mitrofanov Anna B. Priselkova Yuri V. Fedorov Alexander L. Trigub Olga A. Fedorova Stepan N. Kalmykov 《Molecules (Basel, Switzerland)》2022,27(10)
A synthetic procedure for the synthesis of azacrown ethers with a combination of pendant arms has been developed and the synthesized ligand, characterized by various techniques, was studied. The prepared benzoazacrown ether with hybrid pendant arms and its complexes with copper and lead cations were studied in terms of biomedical applications. Similarly to a fully acetate analog, the new one binds both cations with close stability constants, despite the decrease in both constants. The calculated geometry of the complexes correlate with the data from X-ray absorption and NMR spectroscopy. Coordination of both cations differs due to the difference between the ionic radii. However, these chelation modes provide effective shielding of cations in both cases, that was shown by the stability of their complexes in the biologically relevant media towards transchelation and transmetallation. 相似文献
713.
Vladimir A. Bershtein Larisa M. Egorova Valery A. Ryzhov Pavel N. Yakushev 《Macromolecular Symposia》2000,149(1):87-92
Differential scanning calorimetry (DSC) and laser‐interferometric creep rate spectroscopy (CRS) were used for kinetic and discrete analysis of segmental motion within (and close to) glass transition range in polystyrene ‐ poly(α‐methyl styrene) (PS/PMS) and polystyrene ‐ poly(vinyl methyl ether) (PS/PVME) miscible blends. Two kinds of segmental dynamics heterogeneity were found. Separate ‘unfreezing’ of PS and PMS segmental motions was observed that manifested itself in two Tgs and simultaneous large drop in the Tg s, as well as glass transition activation energy, motional event scale and cooperativity degree values, down to the β‐relaxation parameters. The wide activation energy dispersion within a single broad glass transition in PS/PVME blends was found, and this relaxation region was subdivided, by CRS, into several predicted kinds of segmental motion. Both results are treated in the framework of the concept of common segmental nature of α‐ and β‐relaxations in flexible chain polymers. 相似文献
714.
Two major termination processes in the GTP of methacrylates and acrylates have been studied. For methacrylates, intramolecular cyclization is the dominant, if not sole, termination reaction. Both cyclization and O/C-silyl isomerization of the chain end are observed for acrylates. Oligomerization experiments were used to study the relative rates of cyclization and propagation and the influence of temperature, catalyst and dp. Under typical GTP conditions for methacrylates, cyclization is at least two orders of magnitude slower than monomer addition. 相似文献