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91.
92.
Inés CarrancoJosé Luis D?&#x;az Oscar JiménezRodolfo Lavilla 《Tetrahedron letters》2003,44(46):8449-8452
The Lewis acid-catalyzed interaction of dihydropyridines with ethyl glyoxalate and primary aliphatic amines yields, depending on the reaction conditions, bicyclic aminals or rearranged tetrahydropyridines in one-pot multicomponent reactions. 相似文献
93.
Gravimetric measurements of thermodesorption of n-hexane and n-heptane were performed under quasi-equilibrium conditions. Differential thermodesorption profiles for ZSM-5 and ZSM-11 showed two peaks, but for Y zeolites, only one thermodesorption peak was observed. A model function, derived from the Langmiur adsorption model, was fitted to the experimental data, and the model parameters (the adsorption entropy and enthalpy) were estimated. The two-step desorption profiles observed for ZSM-5 and ZSM-11 were attributed to the commensurate freezing effect, i.e. a transition in the adsorbed phase resulting in ordering of the adsorbed molecules in the zeolite channels. The results observed for ZSM-11 indicate that the zigzag channels typical for ZSM-5 micropore system are not necessary for this transition to occur. 相似文献
94.
求解非对称线性方程组的QMRGCGS方法 总被引:2,自引:1,他引:1
1 引言 求解非对称线性方程组Ax=b的双共轭梯度方法(BCG)[3]和它的变形共轭梯度平方方法(CGS)[6]都有典型的不规则收敛行为,后来Freund和Nachtigal提出一种BCG类方法,即拟极小剩余方法(QMR)[7],用来补救BCG方法的收敛性并且产生了光滑的收敛曲线。然而,象BCG方法一样,QMR方法要用到系数矩阵A及其转置A~T与向量的乘积,为了解决这一问题,Freund提出TFQMR方法,此方法具有拟极小剩余性,同时不需用到A~T与向量的乘积。 相似文献
95.
R. Ochoa-Land?&#x;n M. Flores-Acosta R. Ram?&#x;rez-Bon H. Arizpe-Chávez F.F. Castillón-Barraza 《Journal of Physics and Chemistry of Solids》2003,64(11):2245-2251
CdS clusters were synthesized in A type zeolite by reaction in alkaline aqueous solution at temperatures from 30 to 70 °C. The optical properties of the samples were studied by diffuse reflectance and photoluminescence spectroscopy. Their crystalline structure and morphology were studied by X-ray diffraction and by transmission and scanning electron microscopy. We found that at lower temperatures the CdS clusters are encapsulated in the zeolite cages. We compared the properties of these clusters with those encapsulated in the cages of zeolites X and Y, prepared by similar methods. CdS clusters smaller than the CdS exciton diameter are also formed outside the cages in the zeolite matrix. The size of these clusters increases with temperature producing a red-shift of the absorption edge in the optical absorption spectra. 相似文献
96.
Mihai Tib?r 《Topology》2003,42(3):629-639
We show that the complex link of a large class of space germs (X,x0) is characterized by its “simplicity”, among the Milnor fibres of functions with isolated singularity on X. This amounts to the minimality of the Milnor number, whenever this number is defined. Such a phenomenon has been first pointed out in case (X,x0) is an isolated hypersurface singularity, by Teissier (Cycles évanescents, sections planes et conditions de Whitney, in: Singularités à Cargèse 1972, Asterisque, Nos. 7 et 8, Soc. Math. France, Paris, 1973, pp. 285-362). 相似文献
97.
Ruili?ZhangEmail author Jianming?Dai Wenhai?Song Yongqing?Ma Jie?Yang Yuping?Sun 《中国科学G辑(英文版)》2004,47(1):113-120
It is helpful to study the photo-induced effect in the perovskite manganites not only for elucidating the mechanism of colossal
magnetoresistance (CMR) effect but also for potential applications in technology. The laser-induced effect in the Co doping
layered perovskite manganites La1.2Sr1.8Mn1.8Co0.2O7, is studied in this paper and the obtained results are also compared with that gained in the Nd-doping manganites with cubic
perovskite structure. 相似文献
98.
The effect of hydrostatic pressure on the ferroelectric phase transition temperature in [NH2(CH3)2]3[Sb2Cl9] (DMACA) has been studied by electric permittivity measurements at pressures up to 400 MPa. The pressure-temperature phase diagram is given. The phase transition temperature (Tc) increases with increasing pressure up to 150 MPa, passes through a maximum and then decreases with a further increase of pressure. The unexpected nonlinear decrease in Tc with pressure increasing above 150 MPa suggests that the mechanism of ferroelectric phase transition in DMACA is different from hitherto assumed. 相似文献
99.
Dragan Vukoti? 《Journal of Mathematical Analysis and Applications》2004,291(1):189-202
For arbitrary composition operators acting on a general Bergman space we improve the known lower bound for the norm and also generalize a related recent theorem of D.G. Pokorny and J.E. Shapiro. Next, we obtain a geometric formula for the norms of composition operators with linear fractional symbols, thus extending a result of C. Cowen and P. Hurst and revealing the meaning of their computation. Finally, we obtain a lower bound for essential norm of an arbitrary composition operator related to the well-known criterion of B. MacCluer and J.H. Shapiro. As a corollary, norms and essential norms are obtained for certain univalently induced noncompact composition operators in terms of the minimum of the angular derivative of the symbol. 相似文献
100.