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61.
Structures and energetics of various types of silicon nanowires have been investigated using both quantum and classical molecular dynamics simulations to determine the most stable forms. The tetrahedral type nanowires have been found to be the most stable and, surprisingly, the polycrystalline forms of nanowires, while having the smallest surface to bulk ratio, are found to be the least stable. We also show that the cagelike nanowires have greater thermal stability than the tetrahedral nanowires. Furthermore, their electrical conducting properties are found to be better than those of tetrahedral nanowires, suggesting useful molecular electronic applications. 相似文献
62.
Inna Bumagina 《Israel Journal of Mathematics》2001,124(1):279-284
The rank of a groupG is the minimal number of elements that generateG. For any natural numbern we construct two groups,G
1 of rankr(G
1)=n andG
2 of rankr(G
2)=2n such that their amalgamated product over an infinite cyclic subgroup, malnormal in both factors, is generated by 2n=r(G
1)+r(G
2)−n elements. We also consider an example of an amalgamated product ofn factors:
such thatr(G)=n +1, andr(A)≥1. This example realizes the lower bound given by Weidmann [W1] (see Theorem 2 in the present paper). 相似文献
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68.
Zornitza Tosheva Antoine Kies Inna Taskaeva 《International journal of environmental analytical chemistry》2013,93(9):653-661
A time-saving and sensitive method for monitoring low concentration (activities) of 210Pb, 232Th, and 230Th and 238U, 234U, and 235U in water samples has been developed. Through the combination of co-precipitation and extraction chromatography by 3M RAD disks and UTEVA (Eichrom) columns effective radiochemical separation of the analytes was carried out. Thorium and uranium activities were determined by alpha spectrometry and lead activity by LSC, respectively. The minimal detectable activities obtained were 0.6?Bq?m?3 for uranium, 0.29?Bq?m?3 for thorium, and 2.5?Bq?m?3 for 210Pb. More than 150 different waters were analysed for uranium content and only 30 for lead and thorium. The investigations are still in progress. 相似文献
69.
Alexander N. Shikov Veronika A. Shikova Anastasiia O. Whaley Marina A. Burakova Elena V. Flisyuk Andrei K. Whaley Inna I. Terninko Yulia E. Generalova Irina V. Gravel Olga N. Pozharitskaya 《Molecules (Basel, Switzerland)》2022,27(22)
The roots of licorice (Glycyrrhiza glabra L.) have been widely used in traditional and officinal medicines for the treatment of different diseases. Natural deep eutectic solvents (NADES) have become popular for the extraction of active principles from medicinal plants. However, the ability of NADES to co-extract trace elements during the isolation of target active compounds is rarely investigated. The aim of this study was to analyze the content of trace elements in acid-based NADES extracts from the roots of G. glabra and the health risks associated with them. In this study, we have tested for the first time the ability of several acid-based NADES to co-extract glycyrrhizic acid (GA) and trace elements from the roots of G. glabra. GA has been identified as the dominant phytochemical in G. glabra NADES extracts (0.145–0.495 mg/g). Due to the close pKa of lactic acid and GA, the yield of GA in lactic acid-based NADES was higher in comparison with other tested NADES. The yield of GA in NADES3-NADES5 was statistically significant and surpassed the yield of GA in water. The recovery of all elements (except Li) by all tested NADES was low (less than 6%). According to an ANOVA test, the hydrogen bond donor type plays a decisive role in the extraction of elements. A strong positive correlation between the recovery of GA and MPI was noted. The metal pollution index, hazard quotient, hazard index, and chronic daily intake were calculated and suggest that all tested NADES extracts of G. glabra roots were nontoxic and possess no health risk for both ingestion and topical application. 相似文献
70.
Evgeny Y. Grigoryev Inna M. Grigorieva Alexander S. Lyakhov Ludmila S. Ivashkevich Vadim E. Matulis Ludmila G. Lavrenova Sergei V. Voitekhovich Dr. Yuri V. Grigoriev 《无机化学与普通化学杂志》2023,649(1):e202200290
2,6-Di(1H-tetrazol-1-yl)pyridine (DTP) was prepared by a four-stage procedure, including step-by-step heterocyclization of both amino groups of 2,6-diaminopyridine with triethyl orthoformate and sodium azide. According to quantum-chemical calculations and single crystal X-ray diffraction data, DTP crystallizes in the form of the thermodynamically most stable conformer and has an almost flat molecular geometry. DTP was found to react with CuCl2 ⋅ 2H2O in ethanol to give the [Cu(DTP)Cl2(H2O)]n complex, which is a 1D coordination polymer, formed at the expense of bridging DTP ligand via the tetrazole ring nitrogen atoms N4. Possible coordination cites in DTP molecule are discussed using the data of quantum chemical calculations. The pyridine ring nitrogen atom of DTP does not participate in the formation of either coordination or intermolecular hydrogen bonds. This is explained by the results of quantum chemical calculations showing that this atom is less basic than N3 and N4 atoms of DTP molecule. 相似文献