The pyrolytic identification of organic molecules: II. A quantitative evaluation

Results are presented of an investigation made to set up a system for the study of pyrolysis of organic compounds, and to determine some of the important conditions in this system. Acetone, methanol, ethanol, and n-propanol were used as model compounds. Degradation of the compounds was studied quantitatively over a temperature range of 300–1200 °C using flash vaporization into a heated reaction chamber. The volatile products were analyzed by gas chromatographic techniques. A mechanism of the thermal decomposition of acetone by its high-temperature pyrolysis is proposed.     

A global simulation method for obtaining reduced reaction mechanisms for use in reactive blast wave flows

A finite rate chemistry solver usually consumes the largest part of the computing time in the numerical simulation of reactive flows. To reduce these costs, a global simulation method has been developed for systematically simplifying detailed reaction mechanisms and a reduced reaction mechanism for CH₄−O₂ is presented. This reduced mechanism accurately replicates the associated detailed mechanism whilst significantly reducing the required computing time. A shock induced methane combustion problem is computed by coupling the reduced reaction mechanism to a 1-D viscous compressible flow solver. As a comparison, a simulation of non-reactive shock flow having the same initial conditions is also performed. These calculations reveal some of the key features found in reactive shock flows. This article was processed by the author using Springer-Verlag TEX PJour2g macro package version 1.1     

Some Forthcoming Papers

This is a pedagogical note of warning about the use of phasors in the matric equations of electrical network theory.