首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   231篇
  免费   3篇
  国内免费   4篇
化学   151篇
晶体学   5篇
力学   3篇
数学   54篇
物理学   25篇
  2022年   3篇
  2021年   1篇
  2019年   1篇
  2018年   2篇
  2017年   5篇
  2016年   4篇
  2015年   4篇
  2014年   3篇
  2013年   13篇
  2012年   8篇
  2011年   12篇
  2010年   9篇
  2009年   8篇
  2008年   8篇
  2007年   11篇
  2006年   11篇
  2005年   9篇
  2004年   13篇
  2003年   8篇
  2002年   5篇
  2001年   8篇
  2000年   10篇
  1999年   2篇
  1998年   5篇
  1997年   4篇
  1996年   7篇
  1995年   11篇
  1994年   10篇
  1993年   10篇
  1992年   4篇
  1991年   4篇
  1990年   4篇
  1989年   2篇
  1988年   1篇
  1985年   1篇
  1984年   2篇
  1982年   2篇
  1981年   1篇
  1980年   2篇
  1979年   1篇
  1978年   1篇
  1977年   2篇
  1976年   1篇
  1975年   2篇
  1974年   2篇
  1972年   1篇
排序方式: 共有238条查询结果,搜索用时 15 毫秒
21.
We present a combination of theoretical calculations and experiments for the low-lying vibrational excitations of H and D atoms adsorbed on the Pt(111) surface. The vibrational band states are calculated based on the full three-dimensional adiabatic potential energy surface obtained from first-principles calculations. For coverages less than three quarters of a monolayer, the observed experimental high-resolution electron peaks at 31 and 68 meV are in excellent agreement with the theoretical transitions between selected bands. Our results convincingly demonstrate the need to go beyond the local harmonic oscillator picture to understand the dynamics of this system.  相似文献   
22.
A thin-layer chromatography/densitometry method was developed and validated for the determination of oxycodone hydrochloride in oral solutions by using silica gel plates. A horizontal technique was used for development of the plates. The optimum composition for the mobile phase, which provided a suitable Rf value of 0.6 for oxycodone, was propanol-acetic acid-water-25% ammonia-methanol (20 + 1 + 1 + 3 + 10). Detection was at 234 nm. Oxycodone hydrochloride was stable on the sorbent and was precisely and accurately measured in the range of 0.3-1.5 microg/band.  相似文献   
23.
A method is presented for measuring the change of the intensity of x-ray diffraction peaks of cellulose specimens as a consequence of humidity changes of the specimens. Measurements performed showed a decrease of this intensity after drying pulp specimens initially kept in humid air. Thus the order in cellulose decreased during drying.  相似文献   
24.
Viscous overstability (oscillatory instability) may play an important role in the formation of small scale structure in dense planetary rings such as Saturn's B ring. We investigate the growth and saturation of such modes in local particle simulations. Starting from a hydrodynamic model, we develop a set of ordinary differential equations to model the evolution of the amplitudes of the linearly overstable modes in the nonlinear regime. The NASA/ESA space probe Cassini can make direct observations of these modes in Saturn's rings, including their sizes and temporal development.  相似文献   
25.
A new pulse sequence, long-range CPMG-adjusted heteronuclear single quantum coherence (LR-CAHSQC), is proposed for the determination of long-range JCH coupling constants from a long-range 1H-13C correlation experiment. The long-range heteronuclear coupling constants can be directly extracted from COSY-type antiphase peak patterns. The current approach utilizes CPMG-sequences for polarization transfer, and thus avoids the evolution of homonuclear JHH couplings, which normally may introduce abnormalities into the cross peak pattern. The differences between LR-CAHSQC and normal LR-HSQC are discussed.  相似文献   
26.
A high-performance thin-layer chromatography (HPTLC) method was developed for fast evaluation of the purity of solid-phase synthesis products. The results obtained were in good agreement with results obtained by the LC-MS method (r(2) = 0.8404) or by the LC-UV method (r(2) = 0.8053), confirming the suitability of HPTLC for purity analysis of combinatorial syntheses. The synthesis products can be quantified and identified by measuring UV densitograms or in situ UV spectra or by ESI-MS after isolation of the zone of interest. A new, simple, and fast method for transferring the zone of the analyte from the plate to the ESI-MS equipment is described. The new HPTLC method enables rapid and efficient analysis of approximately 40 samples in parallel. As such, it offers a cheaper and easier way to analyze the purity of synthesis products than the commonly used LC-UV-MS.  相似文献   
27.
1H-detected two-dimensional double-/zero-quantum experiments are described for measurement of homonuclear 2JHH-couplings of NH2 or CH2 groups in proteins. These experiments utilize multiple-quantum coherence for determination of the size and the absolute sign of the geminal scalar and dipolar couplings in the presence of broad lines. Spectra are simplified by gradient selection and spin-state selective filters.  相似文献   
28.
Editorial     
JPC – Journal of Planar Chromatography – Modern TLC -  相似文献   
29.
Common design principles apply to design of mechanical and biological machine structures. Most of the main properties of machines and creatures are determined by programmed genetics. These determine the geometry, material selection, functioning of machines and biological creatures and the fitness for service. The present approach of innovation and optimum design is based on basic mechanics with fuzzy goal formulations and heuristics, like axiomatic design. These models are combined synergistically to formulate the desired properties of the machines. First, engineering mechanics and heuristics are shown to have a finalistic guidance on the conceptual design of optimal fluid conveying channels consisting of a branch and a closing device. Then a multi-objective algorithm is tested in an industrial case study design of a preloaded screw fastened flange plate and it is shown to be a reliable tool for testing and innovating new solutions. The goals and constraints are modellled consistently by the same goal function form. The joints have to be reliable against risks of separation, relaxation, fatigue and creep fracture due to pressure differences. Compared to conventional results it gives nearly the same technical and safety functions even at half the cost. This approach is useful for optimizing new concepts and also existing machine designs showing possibilities for notable cost savings.  相似文献   
30.
Mannersalo  Petteri  Norros  Ilkka  Salminen  Paavo 《Queueing Systems》2004,46(3-4):557-577
In this paper we introduce a storage process with singular continuous input. The input process is defined as the local time of a stationary reflecting Brownian motion with drift. Many basic charateristics of the process are computed explicitly, e.g., stationary distribution, distributions of the starting and ending time of on-going busy and idle periods. We also consider the multifractal spectrum of the input process and observe that it is independent of system parameters.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号