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71.
Activation of Molecular Hydrogen by Bis(η5,η1‐pentafulvene)‐titanium Complexes – Efficient Formation of Titanium(III)hydrides 下载免费PDF全文
The synthesis and crystal structures of two dinuclear titanocene hydride complexes are reported. Both complexes, namely bis(η5‐(di‐para‐tolylmethyl)cyclopentadienyl)titanium hydride dimer, [(η5‐C20H19)2Ti(μ‐H)]2 ( 2a ), and bis(η5‐2‐adamantylcyclopentadienyl)‐titanium hydride dimer, [(η5‐C15H19)2Ti(μ‐H)]2 ( 2b ), are formed via activation of molecular hydrogen by the corresponding bis(η5,η1‐pentafulvene)titanium complexes 1a and 1b at ambient temperatures and pressures in high yields. The hydride complexes 2a and 2b exhibit planar [Ti2H2] cores and, as a result of the heterolytic cleavage of molecular hydrogen, substituted Cp Ligands were formed during the reaction. 相似文献
72.
Sebastian Mendrek Aleksandra Mendrek Hans-Juergen Adler Andrzej Dworak Dirk Kuckling 《Colloid and polymer science》2010,288(7):777-786
Temperature-sensitive poly(glycidol)-b-poly(N-isopropylacrylamide) block copolymers (PGl55PNIPAAmy) were synthesised and their aqueous solutions investigated by different methods including differential scanning calorimetry
(DSC), UV-VIS spectroscopy as well as dynamic and static light scattering. The cloud point temperature (T
c) depended on the composition of the investigated block copolymers and increased with decreasing length of the PNIPAAm block
in PGl55PNIPAAmy copolymers. In contrast, the enthalpy of phase separation of PNIPAAm segments measured by DSC decreased with decreasing length
of the PNIPAAm block in the polymer. These findings can be correlated with the behaviour of homo-PNIPAAm with similar molecular
weights indicating that the influence of PGl on the local environment and phase separation of PNIPAAm chains is similar to
the influence observed for PNIPAAm chains bearing different low molecular weight end group. Using DLS measurement, it was
shown that the aggregation process depended on the PGl/PNIPAAm block ratio. If the PGl/PNIPAAm ratio was low, stable core-shell
aggregates were formed. In contrast, the tendency to formation of large unstable, loose aggregates was observed for copolymers
with high PGl/PNIPAAm ratio. 相似文献
73.
J.H. Adler J. Brannick C. Liu T. Manteuffel L. Zikatanov 《Journal of computational physics》2011,230(17):6647-6663
This paper develops a first-order system least-squares (FOSLS) formulation for equations of two-phase flow. The main goal is to show that this discretization, along with numerical techniques such as nested iteration, algebraic multigrid, and adaptive local refinement, can be used to solve these types of complex fluid flow problems. In addition, from an energetic variational approach, it can be shown that an important quantity to preserve in a given simulation is the energy law. We discuss the energy law and inherent structure for two-phase flow using the Allen–Cahn interface model and indicate how it is related to other complex fluid models, such as magnetohydrodynamics. Finally, we show that, using the FOSLS framework, one can still satisfy the appropriate energy law globally while using well-known numerical techniques. 相似文献
74.
Khachatryan V Sirunyan AM Tumasyan A Adam W Bergauer T Dragicevic M Erö J Fabjan C Friedl M Frühwirth R Ghete VM Hammer J Hänsel S Hartl C Hoch M Hörmann N Hrubec J Jeitler M Kasieczka G Kiesenhofer W Krammer M Liko D Mikulec I Pernicka M Rohringer H Schöfbeck R Strauss J Taurok A Teischinger F Wagner P Waltenberger W Walzel G Widl E Wulz CE Mossolov V Shumeiko N Suarez Gonzalez J Benucci L Cerny K De Wolf EA Janssen X Maes T Mucibello L Ochesanu S Roland B Rougny R Selvaggi M Van Haevermaet H 《Physical review letters》2011,106(11):112001
Measurements of the total and differential cross sections dσ/dp(T)(B) and dσ/dy(B) for B(+) mesons produced in pp collisions at sqrt[s]=7 TeV are presented. The data correspond to an integrated luminosity of 5.8 pb(-1) collected by the CMS experiment operating at the LHC. The exclusive decay B(+)→J/ψK(+), with J/ψ→μ(+)μ(-), is used to detect B(+) mesons and to measure the production cross section as a function of p(T)(B) and y(B). The total cross section for p(T)(B)>5 GeV and |y(B)|<2.4 is measured to be 28.1±2.4±2.0±3.1 μb, where the first uncertainty is statistical, the second is systematic, and the last is from the luminosity measurement. 相似文献
75.
Khachatryan V Sirunyan AM Tumasyan A Adam W Bergauer T Dragicevic M Erö J Fabjan C Friedl M Frühwirth R Ghete VM Hammer J Hänsel S Hartl C Hoch M Hörmann N Hrubec J Jeitler M Kasieczka G Kiesenhofer W Krammer M Liko D Mikulec I Pernicka M Rohringer H Schöfbeck R Strauss J Taurok A Teischinger F Waltenberger W Walzel G Widl E Wulz CE Mossolov V Shumeiko N Suarez Gonzalez J Benucci L Ceard L Cerny K De Wolf EA Janssen X Maes T Mucibello L Ochesanu S Roland B Rougny R Selvaggi M Van Haevermaet H 《Physical review letters》2011,106(1):011801
The results of the first search for long-lived gluinos produced in 7 TeV pp collisions at the CERN Large Hadron Collider are presented. The search looks for evidence of long-lived particles that stop in the CMS detector and decay in the quiescent periods between beam crossings. In a dataset with a peak instantaneous luminosity of 1×10(32) cm-2 s-1, an integrated luminosity of 10 pb-1, and a search interval corresponding to 62 hours of LHC operation, no significant excess above background was observed. Limits at the 95% confidence level on gluino pair production over 13 orders of magnitude of gluino lifetime are set. For a mass difference mg - mχ1(0) >100 GeV/c2, and assuming BR(g→gχ1(0))=100%, mg < 370 GeV/c2 are excluded for lifetimes from 10 μs to 1000 s. 相似文献
76.
Signatures of the non-Abelian statistics of quasiparticles in the ν=5/2 quantum Hall state are predicted to be present in the current-voltage characteristics of tunneling through one or two quantum Hall puddles of Landau filling ν(a) embedded in a bulk of filling ν(b) with (ν(a),ν(b))=(2,5/2) and (ν(a),ν(b))=(5/2,2). 相似文献
77.
For grafting polypyrrole layers on oxidic substrates, the synthesis and characterization of a new adhesion promoter 11‐(pyrrol‐3‐yl) undecyl trimethoxysilane (PyTMS) were described in this article. The oxidation potential of PyTMS was determined by cyclic voltammetry. The grafting behavior of such an adhesion promoter on oxidized surface and chemical deposition of polypyrrole over the modified oxidized surface were studied. The adsorbed layer on the oxidized substrates thus formed was determined by both contact angle measurements and X‐ray photoelectron spectroscopy. Chemical polymerization of terminal pyrrole moieties on such substrates yielded adhesive polypyrrole films, and SEM image showed that the morphology of the polypyrrole films was influenced by the experimental conditions. 相似文献
78.
79.
80.
V. E. Adler 《Theoretical and Mathematical Physics》2000,124(1):897-908
The relation between the Sklyanin chain and the Bäcklund transformations for the Landau-Lifshits equation is established. The stationary solutions of the chain determine an integrable mapping, which is a kind of classical Heisenberg spin chain. Some multifield generalizations are found. 相似文献