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941.
Sofia Curland Leah Javitt Isabelle Weissbuch David Ehre Meir Lahav Igor Lubomirsky 《Angewandte Chemie (International ed. in English)》2020,59(36):15570-15574
By performing icing experiments on hydrophilic and hydrophobic surfaces of pyroelectric amino acids and on the x‐cut faces of LiTaO3, we discovered that the effect of electrofreezing of super cooled water is triggered by ions of carbonic acid. During the cooling of the hydrophilic pyroelectric crystals, a continuous water layer is created between the charged hemihedral faces, as confirmed by impedance measurements. As a result, a current of carbonic acid ions, produced by dissolved environmental CO2, flows through the wetted layer towards the hemihedral faces and elevates the icing temperature. This proposed mechanism is based on the following: (i) on hydrophilic surfaces, water with dissolved CO2 (pH 4) freezes at higher temperatures than pure water of pH 7. (ii) In the absence of the ionic current, achieved by linking the two hemihedral faces of hydrophilic crystals by a conductive paint, water of the two pH levels freeze at the same temperature. (iii) On hydrophobic crystals with similar pyroelectric coefficients, where there is no continuous wetted layer, no electrofreezing effect is observed. 相似文献
942.
Liyang Yue Zengbo Wang Bing Yan James N. Monks Yasir Joya Rakesh Dhama Oleg V. Minin Igor V. Minin 《Annalen der Physik》2020,532(10):2000373
A Teflon (polytetrafluoroethylene) sphere can be used as a focusing lens in the applications of imaging and sensing due to its low-loss property in the terahertz band. Herein, field intensities and focusing parameters are analytically calculated for Teflon spheres at different low-loss levels and then a super-enhancement focusing effect in the spheres with particular size parameters was discovered, which can stimulate about 4000 times stronger field intensity than that for incident radiation as well as the great potential of overcoming diffraction limit despite high sensitivity to the magnitude of Teflon loss. A subsequent analysis of scattering amplitudes proves that the strong scattering of a single-order mode in the internal electric or magnetic field is the main factor causing this phenomenon. 相似文献
943.
Sergey A. Anufriev Igor B. Sivaev Hiroyuki Nakamura 《Phosphorus, sulfur, and silicon and the related elements》2020,195(11):910-917
AbstractTwo ways of synthesis of theragnostic compounds for Gd-guided boron neutron capture therapy of cancer are proposed. The first way is based on modification of DO3A ligand, which a capable to form stable complexes with gadolinium, with attachment of boron-containing moieties and additional functional groups which can be used for conjugation with various biomacromolecules. The second way is based on the introduction of additional chelating groups into a boron-containing moiety—carborane-based ligand. It is expected that this will significantly improve the stability of the gadolinium bis(dicarbollide) complexes. 相似文献
944.
Mudaris N. Dimukhametov Vladimir F. Mironov Daut R. Islamov Igor A. Litvinov Oleg I. Gnezdilov Yuliya V. Danilova 《Mendeleev Communications》2021,31(1):107-109
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945.
Dr. Gabriel dos Passos Gomes Dr. Guangcan Xu Dr. Xiaolei Zhu Dr. Lise-Marie Chamoreau Dr. Yongmin Zhang Dr. Olivia Bistri-Aslanoff Dr. Sylvain Roland Prof. Igor V. Alabugin Prof. Matthieu Sollogoub 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(31):8127-8142
What happens when a C−H bond is forced to interact with unpaired pairs of electrons at a positively charged metal? Such interactions can be considered as “contra-electrostatic” H-bonds, which combine the familiar orbital interaction pattern characteristic for the covalent contribution to the conventional H-bonding with an unusual contra-electrostatic component. While electrostatics is strongly stabilizing component in the conventional C−H⋅⋅⋅X bonds where X is an electronegative main group element, it is destabilizing in the C−H⋅⋅⋅M contacts when M is Au(I), Ag(I), or Cu(I) of NHC−M−Cl systems. Such remarkable C−H⋅⋅⋅M interaction became experimentally accessible within (α-ICyDMe)MCl, NHC-Metal complexes embedded into cyclodextrins. Computational analysis of the model systems suggests that the overall interaction energies are relatively insensitive to moderate variations in the directionality of interaction between a C−H bond and the metal center, indicating stereoelectronic promiscuity of fully filled set of d-orbitals. A combination of experimental and computational data demonstrates that metal encapsulation inside the cyclodextrin cavity forces the C−H bond to point toward the metal, and reveals a still attractive “contra-electrostatic” H-bonding interaction. 相似文献
946.
Dr. Baptiste Joalland Nuwandi M. Ariyasingha Hassan R. Younes Shiraz Nantogma Dr. Oleg G. Salnikov Dr. Nikita V. Chukanov Dr. Kirill V. Kovtunov Prof. Igor V. Koptyug Prof. Juri G. Gelovani Prof. Eduard Y. Chekmenev 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(8):2774-2781
Many MRI contrast agents formed with the parahydrogen-induced polarization (PHIP) technique exhibit biocompatible profiles. In the context of respiratory imaging with inhalable molecular contrast agents, the development of nonflammable contrast agents would nonetheless be highly beneficial for the biomedical translation of this sensitive, high-throughput and affordable hyperpolarization technique. To this end, we assess the hydrogenation kinetics, the polarization levels and the lifetimes of PHIP hyperpolarized products (acids, ethers and esters) at various degrees of fluorine substitution. The results highlight important trends as a function of molecular structure that are instrumental for the design of new, safe contrast agents for in vivo imaging applications of the PHIP technique, with an emphasis on the highly volatile group of ethers used as inhalable anesthetics. 相似文献
947.
Dr. Esther Frederick Dr. Quinn Campbell Dr. Igor V. Kolesnichenko Dr. Luis F. Peña Dr. Angelica Benavidez Dr. Evan M. Anderson Dr. David R. Wheeler Dr. Shashank Misra 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(53):13337-13341
Ultradoping introduces unprecedented dopant levels into Si, which transforms its electronic behavior and enables its use as a next-generation electronic material. Commercialization of ultradoping is currently limited by gas-phase ultra-high vacuum requirements. Solvothermal chemistry is amenable to scale-up. However, an integral part of ultradoping is a direct chemical bond between dopants and Si, and solvothermal dopant-Si surface reactions are not well-developed. This work provides the first quantified demonstration of achieving ultradoping concentrations of boron (∼1e14 cm2) by using a solvothermal process. Surface characterizations indicate the catalyst cross-reacted, which led to multiple surface products and caused ambiguity in experimental confirmation of direct surface attachment. Density functional theory computations elucidate that the reaction results in direct B−Si surface bonds. This proof-of-principle work lays groundwork for emerging solvothermal ultradoping processes. 相似文献
948.
Chernyakova Katsiaryna Vrublevsky Igor Jagminas Arunas Klimas Vaclovas 《Journal of Solid State Electrochemistry》2021,25(4):1453-1460
Journal of Solid State Electrochemistry - The purpose of this work was to study and analyze the effect of electrolyte temperature and anodization voltage on cell morphology of thin films of... 相似文献
949.
This review summarises the high potential of immobilised cells systems for the fermentative production of compounds, mainly produced by representatives of the Clostridium genus. Microorganisms of Clostridium species are recognised as good producers of a wide range of chemicals in almost every sector of industry. The combination of this microorganism with its immobilisation opens up new possibilities and renders the fermentation process more sophisticated than in a free-cell system. This review provides a comprehensive summary of techniques used in immobilisation of Clostridium species with regard to specific products and types of fermentation. In addition, comparisons of particular types of immobilisation techniques used in fermentation processes are summarised by specific products. 相似文献