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191.
192.
A Branch and Contract Algorithm for Problems with Concave Univariate, Bilinear and Linear Fractional Terms 总被引:1,自引:0,他引:1
A new deterministic branch and bound algorithm is presented in this paper for the global optimization of continuous problems that involve concave univariate, bilinear and linear fractional terms. The proposed algorithm, the branch and contract algorithm, relies on the use of a bounds-contraction subproblem that aims at reducing the size of the search region by eliminating portions of the domain in which the objective function takes only values above a known upper bound. The solution of contraction subproblems at selected branch and bound nodes is performed within a finite contraction operation that helps reducing the total number of nodes in the branch and bound solution tree. The use of the proposed algorithm is illustrated with several numerical examples. 相似文献
193.
Multielemental trace analysis of biological materials using double focusing inductively coupled plasma mass spectrometry detection 总被引:4,自引:0,他引:4
Juan Manuel Marchante-Gay n Cristina Sariego Mu iz Jos Ignacio Garcí a Alonso Alfredo Sanz-Medel 《Analytica chimica acta》1999,400(1-3):307-320
The analytical potential of double focusing-inductively coupled plasma-mass spectrometry (DF-ICP-MS) for total elemental analysis in clinical samples (serum, blood, urine and other biological fluids), tissues and food products is illustrated by reviewing typical applications recently published. Also, the use of DF-ICP-MS as specific detector for trace element speciation in biological samples is discussed. After adequate separation of interferences in the chromatographic column, low resolution measurements (R = 300) can be used to provide enhanced sensitivities of more than 100 times compared with quadrupole-inductively coupled plasma-mass spectrometry (Q-ICP-MS). This capability is extremely valuable in speciation studies. Also, the use of DF-ICP-MS at low resolution could provide very precise isotope ratio measurements for isotope dilution analysis due to the ‘flat topped’ peaks obtained at this resolution. Unfortunately, the literature on these last two issues is rather scarce so far, in spite of their extremely high analytical possibilities for biological research. Moreover, the bright future of DF-ICP-MS as a most powerful multielemental detector for trace element applications in biological systems will be highlighted. Apart from applications detailed above other important application fields can be envisaged. In particular, we will speculate on its possible use to confirm/establish ‘reference values’ of trace element content in ‘normal’ populations and so to help to diagnose health and disease status, related with trace element total content or their speciation in clinical specimens. 相似文献
194.
Francisco Torrens Jos SnchezMarín Ignacio NebotGil 《Journal of computational chemistry》2001,22(5):477-487
A method for the computation of a dimension index D is implemented in program TOPO and applied to calculate the solvent‐accessible surfaces of molecules. Our algorithm distinguishes external from internal atoms, and uses such a feature to give two fractal‐like dimension indices, D and D′. The D′−D difference is a sensitive method to elucidate the occurrence of atoms that are hidden to solvents. For molecules with buried atoms this difference is great (e.g., faujasite). The procedure is compared with the GEPOL code, which provides high‐quality results. TOPO systematic error can be easily corrected by simple addition of a small constant value (0.011). Correlation models between indices D and D′, globularity, rugosity, dipole moment and other properties make clear the existence of a homogeneous molecular structure in each series. Additional applications are the extrapolation of D to infinite polymers, the variation of the D with generations of dendrimers and a revision of D for lysozyme. © 2001 John Wiley & Sons, Inc. J Comput Chem 22: 477–487, 2001 相似文献
195.
Carlos Franco-Paredes Peter Carrasco Jose Ignacio Santos Preciado 《Journal of immune based therapies and vaccines》2009,7(1):2-6
Influenza viruses pose a permanent threat to human populations due to their ability to constantly adapt to impact immunologically
susceptible individuals in the forms of epidemic and pandemics through antigenic drifts and antigenic shifts, respectively.
Pandemic influenza preparedness is a critical step in responding to future influenza outbreaks. In this regard, responding
to the current pandemic and preparing for future ones requires critical planning for the early phases where there is no availability
of pandemic vaccine with rapid deployment of medical supplies for personal protection, antivirals, antibiotics and social
distancing measures. In addition, it has become clear that responding to the current pandemic or preparing for future ones,
nation states need to develop or strengthen their laboratory capability for influenza diagnosis as well as begin preparing
their vaccine/antiviral deployment plans. Vaccine deployment plans are the critical missing link in pandemic preparedness
and response. Rapid containment efforts are not effective and instead mitigation efforts should lead pandemic control efforts.
We suggest that development of vaccine/antiviral deployment plans is a key preparedness step that allows nations identify
logistic gaps in their response capacity. 相似文献
196.
Ricardo E. Rivas Ignacio López-GarcíaManuel Hernández-Córdoba 《Spectrochimica Acta Part B: Atomic Spectroscopy》2009
A new procedure for the determination of inorganic arsenic (III,V) and antimony (III,V) in water samples by dispersive liquid–liquid micro extraction separation and electrothermal atomic absorption spectrometry (ETAAS) is presented. At pH 1, As(III) and Sb(III) are complexed with ammonium pyrrolidine dithiocarbamate and extracted into the fine droplets formed when mixing carbon tetrachloride (extraction solvent), methanol (disperser solvent) and the sample solution. After extraction, the phases are separated by centrifugation, and As(III) and Sb(III) are determined in the organic phase. As(V) and Sb(V) remain in the aqueous layer. Total inorganic As and Sb are determined after the reduction of the pentavalent forms with sodium thiosulphate. As(V) and Sb(V) are calculated by difference. The detection limits are 0.01 and 0.05 µg L− 1 for As(III) and Sb(III), respectively, with an enrichment factor of 115. The relative standard deviation is in the 2.9–4.5% range. The procedure has been applied to the speciation of inorganic As and Sb in bottled, tap and sea water samples with satisfactory results. 相似文献
197.
Julio Llorca‐Porcel Esther Martínez‐Soriano Ignacio Valor 《Journal of separation science》2009,32(9):1425-1429
An optimised method using stir bar sorptive extraction (SBSE) and a thermal desorption‐GC‐electron capture detector (GC‐ECD) for the determination of short‐chain chlorinated paraffins from water samples was developed. Recoveries near to 100% were obtained by using 20 mm×0.5 mm (length×film thickness) PDMS commercial stir bars from 200 mL spiked water samples and 20% methanol addition with an extraction period of 24 h. Method sensitivity, linearity and precision were evaluated for surface water and wastewater spiked samples. A LOD of 0.03 and 0.04 μg/L was calculated for surface and wastewater, respectively. The precision of the method given as an RSD was below 20% for both matrices. The developed method was applied for the analysis of two real samples from a contaminated river and a wastewater treatment plant. Results were in accordance with those obtained using a previously developed method based on solid phase microextraction (SPME). 相似文献
198.
Flix Antonio Corts-Aldana Mnica García-Meln Ignacio Fernndez-de-Lucio Pablo Aragons-Beltrn Rocío Poveda-Bautista 《European Journal of Operational Research》2009,199(3):387
Universities develop technology transfer mechanisms as the tools required to undertake missions committed to the socioeconomic environment. In this work a new proposal to measure the extent to which the goals or strategic objectives of a university are aligned with the results obtained through its technology transfer mechanisms with the local community is presented. This will enable to perform a diagnosis, by comparing the situation sought by the University Management team (expected case) with the actual one that derives from the application of the plans that implement the technology transfer mechanisms (real case). To achieve this, two different Multicriteria Decision Analysis techniques e.g. Analytic Network Process (ANP) and Analytic Hierarchy Process (AHP) will be used. Both the methodology and the MCDA techniques proposed need to be explained and clarified to the different experts who collaborate in the study, hence the facilitating process, key to the whole procedure, will be analysed in detail.The model proposed in this study is applied to analyse the case of the National University of Colombia – Bogotá Campus. Findings show that the following questions can be answered: (i) How much importance is granted by the University Management to the objectives of the University? (ii) To what extent are the objectives of the university fulfilled by the technology transfer mechanisms to the socioeconomic environment? (iii) Are the objectives of the university aligned with the results achieved through the technology transfer mechanisms? 相似文献
199.
Ignacio Martínez-Lpez Isabel María Ortiz-Rodríguez Carmelo Rodríguez-Torreblanca 《Applied Mathematics Letters》2009,22(12):1892-1895
This paper is concerned with constructing optimal designs for rational models which are used for modeling problems in Agriculture and other disciplines. Homoscedastic and weighted models are considered. An analytical characterization of these designs is obtained as zeros of a polynomial solution of a second order differential equation. 相似文献
200.
We extend a well-known theorem of Jones and Makarov [8] on the singularity of boundary distortion of planar conformal mappings.
Using a different technique, we recover the previous result and generalize the result to quasiconformal mappings of the unit
ball ⊂_∝
n
, n ≥ 2. We also establish an estimate on the Hausdorff (gauge) dimension of the boundary of the image domain outside an exceptional
set of given size on the sphere ∂ and show that this estimate is essentially sharp. 相似文献