全文获取类型
收费全文 | 2314篇 |
免费 | 87篇 |
国内免费 | 21篇 |
专业分类
化学 | 1698篇 |
晶体学 | 27篇 |
力学 | 110篇 |
综合类 | 1篇 |
数学 | 264篇 |
物理学 | 322篇 |
出版年
2024年 | 6篇 |
2023年 | 16篇 |
2022年 | 152篇 |
2021年 | 105篇 |
2020年 | 58篇 |
2019年 | 66篇 |
2018年 | 59篇 |
2017年 | 53篇 |
2016年 | 93篇 |
2015年 | 74篇 |
2014年 | 84篇 |
2013年 | 199篇 |
2012年 | 155篇 |
2011年 | 159篇 |
2010年 | 88篇 |
2009年 | 78篇 |
2008年 | 82篇 |
2007年 | 88篇 |
2006年 | 74篇 |
2005年 | 57篇 |
2004年 | 53篇 |
2003年 | 56篇 |
2002年 | 63篇 |
2001年 | 40篇 |
2000年 | 49篇 |
1999年 | 18篇 |
1998年 | 22篇 |
1997年 | 17篇 |
1996年 | 24篇 |
1995年 | 22篇 |
1994年 | 23篇 |
1993年 | 13篇 |
1992年 | 13篇 |
1991年 | 19篇 |
1990年 | 14篇 |
1989年 | 16篇 |
1988年 | 9篇 |
1987年 | 15篇 |
1986年 | 10篇 |
1985年 | 22篇 |
1984年 | 18篇 |
1983年 | 19篇 |
1982年 | 17篇 |
1981年 | 13篇 |
1980年 | 11篇 |
1979年 | 10篇 |
1978年 | 6篇 |
1977年 | 9篇 |
1975年 | 9篇 |
1973年 | 5篇 |
排序方式: 共有2422条查询结果,搜索用时 15 毫秒
191.
In this study, a new nonlinear and full adaptive backstepping speed tracking control scheme is developed for an uncertain permanent magnet synchronous motor (PMSM). Except for the number of pole pairs, all the other parameters in both PMSM and load dynamics are assumed unknown. Three phase currents and rotor speed are supposed to be measurable and available for feedback in the controller design. By designing virtual control inputs and choosing appropriate Lyapunov functions, the final control and parameter estimation laws are derived. The overall control system possesses global asymptotic stability; all the signals in the closed loop system remain bounded, according to stability analysis results based on Lyapunov stability theory. Further, the proposed controller does not require computation of regression matrices, with the result that take the nonlinearities in quite general. Simulation results clearly exhibit that the controller guarantees tracking of a time varying desired reference speed trajectory under all the uncertainties in both PMSM and load dynamics without singularity and overparameterization. The results also show that all the parameter estimates converge to their true values on account of the fact that reference speed signal chosen to be sufficiently rich ensures persistency of excitation condition. Consequently, the proposed controller ensures strong robustness against all the parameter uncertainties and unknown bounded load torque disturbance in the PMSM drive system. Numerical simulations demonstrate the performance and feasibility of the proposed controller. 相似文献
192.
Iron Oxide Supported on Al2O3 Catalyst for Methane Decomposition Reaction: Effect of MgO Additive and Calcination Temperature 下载免费PDF全文
Ahmed S. Al‐Fatesh Anis H. Fakeeha Ahmed A. Ibrahim Wasim U. Khan H. Atia R. Eckelt Biswajit Chowdhury 《中国化学会会志》2016,63(2):205-212
Production of hydrogen is a challenging task and have significant impact in the recent scenario. The alumina supported iron oxide nanoparticle synthesized using non‐ionic surfactant Triton‐X was found very effective for steady production of hydrogen through methane decomposition reaction. The high surface area, easily reducible catalyst calcined at 500 °C and 800 °C temperature showed steady activity towards methane decomposition reaction. At a higher reaction temperature there was catalyst deactivation. The doping of MgO facilitated particle growth rendering the poor catalytic activity. The TPR study showed that reducibility of TPR was difficult in presence of MgO additive. The formation of Fe? Mg? Al solid solution confirmed by XRD study was found mainly responsible for the lower catalytic activity. The bamboo‐shaped carbon nanotube formed from 20 % Fe/Al2O3 catalyst which is mainly because of the poor wetting property of quasi‐liquid metal and carbon nanotube. 相似文献
193.
Talaat Ibrahim El‐Emary 《中国化学会会志》2006,53(2):391-401
New derivatives of pyrazolo[3,4‐b]pyrazine and related heterocycles were prepared starting from 6‐amino‐3‐methyl‐1‐phenyl‐1H‐pyrazolo[3,4‐b]pyrazine‐5‐carbonitrile ( 2 ) and using the key intermediates 4 , 5 , 6 , 14 , 15 and 16 . Some of the prepared compounds were evaluated for their antifungal and antibacterial activities. 相似文献
194.
A new sol–gel hybrid methyltrimethoxysilane‐chloropropyltriethoxysilane was prepared as sorbent for solid‐phase extraction. The extraction efficiency of the prepared sol–gel hybrid methyltrimethoxysilane‐chloropropyltriethoxysilane was assessed by using three selected organophosphorus pesticides, namely, chlorpyrifos, profenofos, and malathion. Gas chromatography–mass spectrometry was used for detection of organophosphorus pesticides. Several vital parameters were optimized to identify the best extraction conditions. Under the optimum extraction conditions, solid‐phase extraction‐methyltrimethoxysilane‐chloropropyltriethoxysilane method showed good linearity range (0.05‐1 μg/mL) with coefficient of determination more than 0.995. The limits of detection obtained were in the range of 0.01–0.07 μg/mL and limits of quantification ranging from 0.03 to 0.21 μg/mL. The limits of detection obtained for the developed method were 2.3–6.5× lower than the limits of detection of commercial octadecyl silica sorbent. Real samples analysis was carried out by applying the developed method on red apple and purple grape samples. The developed method exhibited good recoveries (88.33–120.7%) with low relative standard deviations ranging from 1.6 to 3.3% compared to commercial octadecyl silica sorbent, which showed acceptable recoveries (70.3–100.2%) and relative standard deviations (6.3–8.8%). The solid‐phase extraction‐methyltrimethoxysilane‐chloropropyltriethoxysilane method is presented as an alternative extraction method for determination of organophosphorus pesticides. 相似文献
195.
5-Arylidenes 1a and 1b, on reaction with ethyl cyanoacetate and diethyl malonate in the presence of ammonium acetate under Michael condensation, yield pyridine derivatives 2 and 3, respectively. Cyclopentapyrimidine derivative 4 can also be obtained by the reaction of 1a with malononitrile in the presence of piperidine. The reaction of 5-arylidene lb with monochloroacetic acid in an alkaline medium gives the thiazol derivative 5. Also, spiro-[3′, 5′]cyclohexenyl pyrimidine derivative 6 could be obtained from the reaction of 1d with maleic anhydride. On the other hand, 5-arylidene 1e reacts with maleic anhydride to give 2-thiobarbituric acid derivative 7. The condensation reaction of 2-thiovioluric acid 8 with some hydrazines affords the triazole derivatives 9a-d. Finally, barbituric acid condenses with isatin to give 5-arylidene 1f, which can be cyclized with phosphorous pentoxide to afford 10. 相似文献
196.
Ashraf A. Aly Stefan Brse Alaa A. Hassan Nasr K. Mohamed Lamiaa E. Abd El-Haleem Martin Nieger Nesrin M. Morsy Mohammed B. Alshammari Mahmoud A. A. Ibrahim Elshimaa M. N. Abdelhafez 《Molecules (Basel, Switzerland)》2020,25(23)
Three new series of paracyclophanyl-dihydronaphtho[2,3-d]thiazoles and paracyclophanyl-thiazolium bromides were designed, synthesized, and characterized by their spectroscopic data, along with X-ray analysis. One-dose assay results of anticancer activity indicated that 3a–e had the highest ability to inhibit the proliferation of different cancer cell lines. Moreover, the hybrids 3c–e were selected for five-dose analyses to demonstrate a broad spectrum of antitumor activity without apparent selectivity. Interestingly, series I compounds (Z)-N-substituted-4,9-dihydronaphtho[2,3-d]thiazol-3(2H)-yl)-4′-[2.2]paracyclophanylamide) that are carrying 1,4-dihydronaphthoquinone were more active as antiproliferative agents than their naphthalene-containing congeners (series II: substituted 2-(4′-[2.2]paracyclophanyl)hydrazinyl)-4-(naphth-2-yl)-thiazol-3-ium bromide hybrids) and (series III: 3-(4′-[2.2]paracyclophanyl)amido-2-(cyclopropylamino)-4-(naphth-2-yl)thiazol-3-ium bromide) toward the SK-MEL-5 melanoma cell line. Further antiproliferation investigations of 3c and 3e on the healthy, normal unaffected SK-MEL-5 cell line indicated their relative safety. Compound 3c showed an inhibition of eight isoforms of cyclin-dependent kinases (CDK); however, it exhibited the lowest IC50 of 54.8 nM on CDK1 in comparison to Dinaciclib as a reference. Additionally, compound 3c revealed a remarkable downregulation of phospho-Tyr15 with a level (7.45 pg/mL) close to the reference. 3c mainly showed cell cycle arrest in the pre-G1 and G2/M phases upon analysis of the SK-MEL-5 cell line. The sequential caspase-3 assay for 3c indicated a remarkable overexpression level. Finally, a molecular docking study was adopted to elucidate the binding mode and interactions of the target compounds with CDK1. 相似文献
197.
A new N-TEMPO-3,5-di-tert-butylsalicylaldimine radical (1) has been synthesized and characterized by single crystal X-ray diffraction, elemental analysis, IR, UV–vis, and EPR spectroscopy and temperature dependent magnetic susceptibility. X-ray diffraction revealed that H-atoms of γ-CH in TEMPO and CH3 in salicylaldimine moieties, are located in close contact with the neighboring N–O radical group in crystal 1. The temperature dependence of the magnetic susceptibility (χm) of 1 has been fitted by the Curie–Weiss law with θ = −0.3 K within 10–300 K, suggesting the presence of a weak intermolecular antiferromagnetic interaction between radical centers at T < 10 K. It has been demonstrated that radical 1 possesses crystal structure involving co-existence of antiferromagnetic and ferromagnetic interactions through C–H?O–N contacts of γ-CH and tBu groups hydrogen atoms, in which the former path dominates over the latter. 相似文献
198.
199.
Fatemeh KhaleghiLaily Bin Din Ibrahim JantanWan Ahmad Yaacob Mohammad A. Khalilzadeh 《Tetrahedron letters》2011,52(52):7182-7184
An efficient and simple synthesis of 1,4-benzoxazepin-2-one derivatives has been achieved via the reaction of isoquinoline, activated acetylenes, and 1-(6-hydroxy-2-isopropenyl-1-benzofuran-yl)-1-ethanone in water without using any catalyst. This one-pot reaction occurs in high yields under mild conditions. 相似文献
200.
Some binary and ternary complexes of Ni(II) with arylideneanthranilic acids and Lewis bases have been prepared and characterized by elemental analyses, IR spectra and X-ray powder diffraction. On the basis of the IR spectra it was found that the Schiff bases used act as monobasic bidentate ligands except for the ortho-hydroxy derivative which acts as a dibasic tridentate ligand. From X-ray analysis it is concluded that the binary Ni(II) chelates are isostructural, and the ternary Ni(II) complexes are also isostructural. 相似文献