Streuung elektromagnetischer Wellen an einer rauhen Oberfläche

Mar?elja's theory of a superconductor without long-range order is cast in a microscopic form. As a consequence, it is found that such a superconductor is gapless. Therefore, measurements of the tunneling density of states should provide a test of this theory.     

Binary fission in Tb and Ag by 600 MeV protons

The binary fission process in ¹⁵⁹Tb and ^natAg induced by 600 MeV protons has been investigated yielding fission cross sections (1.9 and 1.0 mb, respectively) and mean values of the total kinetic energies (100 and 62 MeV, respectively).     

Mass yields in the binary fission of Ag,La and Tb

The mass distributions from the binary fission of Ag, La and Tb induced by 600 MeV protons are presented. The experimental results are compared with the predictions of macroscopic theories, in particular the version of the liquid drop model including dynamical and statistical effects.     

Comparative yields of alkali elements and thallium from uranium irradiated with GeV protons,3He and12C

Mass-separated ion beams of the alkali elements Na, K, and Fr, and of the element Tl, were produced by bombarding a uranium target with 600 MeV protons, 890 MeV³He^{2 +}, and 936 MeV¹²C^{4 +}. Isotopic production yields are reported. In the case of the¹²C beam, these are thick target yields. Absolute cross-sections for the proton beam data were deduced by normalizing the delay-time corrected yield curves to measured cross-sections. For products farthest away from stability, the³He^{2 +} beam generally gives the highest yields.     

Mobile Rayleigh Doppler wind lidar based on double-edge technique

<正>We describe a mobile molecular Doppler wind lidar(DWL) based on double-edge technique for wind measurement of altitudes ranging from 10 to 40 km.A triple Fabry-Perot etalon is employed as a frequency discriminator to determine the Doppler shift proportional to the wind velocity.The lidar operates at 355 nm with a 45-cm-aperture telescope and a matching azimuth-over-elevation scanner that provides full hemispherical pointing.To guarantee wind accuracy,a single servo loop is used to monitor the outgoing laser frequency to remove inaccuracies due to the frequency drift of the laser or the etalon.The standard deviation of the outgoing laser frequency drift is 6.18 MHz and the corresponding velocity error is 1.11 m/s.The wind profiles measured by the DWL are in good agreement with the results of the wind profile radar(WPR).Evaluation is achieved by comparing at altitudes from 2 to 8 km.The relative error of horizontal wind speed is from 0.8 to 1.8 m/s in the compared ranges.The wind accuracy is less than 6 m/s at 40 km and 3 m/s at 10 km.     

A molecular dynamics study of carbon dioxide in water: diffusion,structure and thermodynamics

Atomistic simulations are reported of a model of CO₂ in water. CO₂ is modelled by partial charges and Lennard-Jones interaction sites on each atom; the SPC/E model for water is used. Good agreement with experiment is found for the translational diffusion constants. The variation of the dynamics with the potential parameter was investigated. As expected, the orientational correlation times increase as the magnitude of the quadrupole moment is increased, but the translational diffusion constants are found to be surprisingly insensitive to the magnitude of the CO₂ quadrupole moment. The translational friction coefficient was resolved into electrostatic, Lennard-Jones and cross-terms; the Lennard-Jones contribution is found to be the largest. Varying the Lennard-Jones size parameter affects both translational and reorientational motion. In order to try to understand these results further, the variation of solvation free energy was investigated and the solvent structure around carbon dioxide was examined as the electrostatic and Lennard-Jones parameters were changed. The temperature dependence of the self-diffusion constant of pure SPC/E water was determined.     

A kinetic model for polytropic gases with internal energy

We consider a mixture of N ideal, polytropic gases. Each species is described by a distribution function f_i(t, x, v, I) ≥ 0, 1 ≤ i ≤ N, defined on , and its evolution is governed by a Boltzmann-type equation. In order to recover the energy law of polytropic gases, the authors of [4] proposed a kinetic model in the framework of a weighted L¹ space. Another approach has been developed in [3] in the context of polyatomic gases. Following this previous lead, our model provides a L² framework in both variables v and I, to eventually perform a mathematical study of the diffusion asymptotics, as it was done in [2] for a model without energy exchange. (© 2013 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)     

Synthesis,characterization and cytotoxic activity of organoruthenium(II)-halido complexes with 5-chloro-1H-benzimidazole-2-carboxylic acid

Three new ruthenium(II)-arene halido complexes, [(η⁶-p-cymene) RuX(L)] (1–3), were synthesized in a reaction of [(η⁶-p-cymene)RuX₂]₂ with 5-chloro-1H-benzimidazole-2-carboxylic acid (HL) in ethanol (X^– = Cl^– (1), Br^– (2), I^– (3)). The complexes were characterized by elemental analysis, mass spectrometry, IR, ¹H and ¹³C NMR spectroscopy. The cytotoxic activity of the ligand precursor and its ruthenium complexes was tested by MTT assay in human cancer cell lines: lung adenocarcinoma (A549), myelogenous leukemia (K562) as well as in one normal human fetal lung fibroblast cell line (MRC-5). The results show that ruthenium(II)-arene complexes possess enhanced cytotoxicity when compared to HL in the range of concentrations up to 300 µM. In terms of halido ligand substitution, cytotoxic activity toward A549 and K562 cell lines in 1–3 serie significantly increased (e.g., IC₅₀ values for K562: 1: 205.76 µM; 2: 174.77 µM; 3: 83.97 µM). All studied compounds were found to be ineffective toward MRC-5. Hydrolysis of 1–3 was followed by UV-vis spectroscopy at 25?°C, revealing ligand-substitution reactions at the Ru(II) center. Compounds 2 and 3 underwent rapid hydrolysis ranging from a few minutes for the aquation to ca. 20?min, confirming typical Ru-arene behavior in aqueous solutions.