A new method for solving Biot＇s consolidation of a finite soil layer in the cylindrical coordinate system

A new method is developed to solve Biot＇s consolidation of a finite soil layer in the cylindrical coordinate system. Based on the governing equations of Biot＇s consolidation and the technique of Laplace transform, Fourier expansions and Hankel transform with respect to time t, coordinate θ and coordinate r, respectively, a relationship of displacements, stresses, excess pore water pressure and flux is established between the ground surface （z = 0） and an arbitrary depth z in the Laplace and Hankel transform domain. By referring to proper boundary conditions of the finite soil layer, the solutions for displacements, stresses, excess pore water pressure and flux of any point in the transform domain can be obtained. The actual solutions in the physical domain can be acquired by inverting the Laplace and the Hankel transforms.     

Some features of the solid-state polymerization of diacetylenes

Simple models of the initial polymerization stage and the polymerization kinetics are considered on the example of the solid state topochemical polymerization of diacetylenes. These models take into account the reaction specifity of the solid state process and the nonlinear character of the monomer units interactions.     

Cationic ≠3-allylmetal complexes, 13a) electrical properties of new poly(phenylacetylene) obtained from nickel catalysts

Monometallic complexes of Nickel have been successfully, tested in reaction with olefinic and acetylenic compounds. This paper is devoted to one of the resulting products, a polyphenylacetylene which presents interesting properties. It is readily obtained avoiding the step of a polymer precursor; it is soluble in several solvents, stable in air up to 200° C and may possess a rather high conductivity, depending on polymerization conditions. This is a noticeable difference versus previously reported polyphenylacetylenes which were insulating materials.