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941.
V. V. Pakal’nis I. V. Zerova S. I. Yakimovich 《Russian Journal of General Chemistry》2007,77(10):1732-1741
Acylhydrazines react with 1,3-diketones of the general formula CF3COCH2COR (where R is an aryl or hetaryl group) at both carbonyl groups. The reaction at the trifluoroacetyl group is favored by donor substituents in the aromatic ring of the 1,3-diketone or by the 2-furyl and, especially, 2-thienyl group as a hetaryl substituent, as well as by elevated temperature. The condensation products at the carbonyl group contiguous to the aryl or hetaryl ring have the structure of 5-hydroxy-4,5-dihydropyrazoles and do not undergo tautomeric transformations in solution. The condensation products at the trifluoroacetyl group have either 5-hydroxy-4,5-dihydropyrazole or hydrazone structure and give rise to ring-chain tautomeric equilibrium in solution. Electron-withdrawing substituents in the aromatic ring of the 1,3-dicarbonyl fragment and CDCl3 as solvent favor formation of the cyclic tautomer. The state of the tautomeric equilibrium is weakly sensitive to structural variations in the hydrazine component. 相似文献
942.
The reaction of 2-(2-acetoxyethyl)amino-4-chloro-6-methylpyrimidine with aromatic amines leads to a series of 4-arylamino-2-(2-acetoxyethyl)amino-6-methylpyrimidines. Deacetylation of these compounds proceeds in both acidic and basic media. Most of the arylaminopyrimides obtained exhibit a pronounced antituberculous effect. 相似文献
943.
944.
V. A. Titov V. I. Rakhlin A. A. Titov F. A. Kuznetsov M. G. Voronkov 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2006,80(12):1907-1910
The thermodynamic properties of several silicon-containing derivatives of asymmetric dimethylhydrazine were estimated by comparative methods. The CVD diagrams of the deposition of silicon nitride and dioxide from gas media containing these reagents were constructed. 相似文献
945.
946.
947.
Ya. I. Korenman N. N. Popova T. A. Kuchmenko 《Russian Journal of Applied Chemistry》2007,80(6):955-959
The quantitative and kinetic parameters of sorption of formic and acetic acids on thin films of various modifiers of piezoelectric quartz resonator electrodes are determined. Parameters of film formation on the electrodes (application procedure and thickness) are optimized. Methods for joint and separate determination of formic and acetic acids in air by piezoelectric microweighing with single- and double-sensor devices are developed. 相似文献
948.
949.
In order to check whether superconductivity occurs in the acceptor doped fullerenes C60(MF6)2 (M=As, P, Sb) and to study their magnetic and structural properties, we have carried out magnetic, EPR and NMR measurements of these compounds. Temperature dependences of magnetic susceptibility down to 5 K and field dependences of magnetic moment at 5 K show no ‘bulk’ transition in superconducting state. Some reasons of the absence of superconductivity, such as insufficient charge transfer between C60 and intercalated species and inhomogeneity of the compounds under study, are discussed. 相似文献
950.
V. I. Burkov E. P. Peredereĭ E. V. Fedotov B. V. Mill’ Yu. V. Pisarevskiĭ 《Crystallography Reports》2008,53(5):843-846
The absorption and circular dichroism spectra of langasite family crystals are studied. Wide bands in the range of 285–500 nm that are related to the structure lattice defects are found. For all the crystals, these bands are in approximately the same spectral region, have identical structures, and can be attributed to one type of defects formed by cation vacancies and excess oxygen atoms in the optically active positions. 相似文献