Three-dimensional integral imaging with large depth of focus by use of real and virtual image fields

We present an integral imaging method to enhance the depth of a three-dimensional image by displaying it throughout real and virtual image fields. When the product of depth and resolution square of the displayed three-dimensional image is used as a figure of merit in integral imaging systems, our method can maximize this merit especially when three-dimensional images with large depth of focus are displayed. The feasibility of our method is experimentally demonstrated by generation of elemental images by a computer.     

Contents of Volume 64 (2003)

Volume Contents

Contents of Volume 64 (2003)     

Numerical investigation and electro-acoustic modeling of measurement methods for the in-duct acoustical source parameters

It is known that the direct method yields different results from the indirect (or load) method in measuring the in-duct acoustic source parameters of fluid machines. The load method usually comes up with a negative source resistance, although a fairly accurate prediction of radiated noise can be obtained from any method. This study is focused on the effect of the time-varying nature of fluid machines on the output results of two typical measurement methods. For this purpose, a simplified fluid machine consisting of a reservoir, a valve, and an exhaust pipe is considered as representing a typical periodic, time-varying system and the measurement situations are simulated by using the method of characteristics. The equivalent circuits for such simulations are also analyzed by considering the system as having a linear time-varying source. It is found that the results from the load method are quite sensitive to the change of cylinder pressure or valve profile, in contrast to those from the direct method. In the load method, the source admittance turns out to be predominantly dependent on the valve admittance at the calculation frequency as well as the valve and load admittances at other frequencies. In the direct method, however, the source resistance is always positive and the source admittance depends mainly upon the zeroth order of valve admittance.     

Quantitative comparison of kinetic stabilities of metallomacrocycle-based rotaxanes

Four mononuclear metallomacrocycles with identical cavities but different transition metals (Os(VI), Pd(II), Pt(II), and Re(I)) were prepared. With these metallomacrocycles, the corresponding rotaxanes 2-Os, 2-Pd, 2-Pt, and 2-Re were self-assembled by hydrogen-bonding interactions. The kinetic stabilities of the rotaxanes were determined quantitatively and compared with each other by (1)H NMR spectroscopic techniques, including two-dimensional exchange spectroscopy (2D-EXSY) experiments. The activation free energies (DeltaG( not equal )) for the exchange between the rotaxanes 2-Os, 2-Pd and 2-Pt and their free components were determined to be 15.5, 16.0, and 16.4 kcal mol(-1), respectively. These magnitudes imply that the rotaxanes 2-Os, 2-Pd and 2-Pt are kinetically labile at room temperature and exist only as equilibrium mixtures with free components in solution. In contrast, the rotaxane 2-Re is kinetically stable enough to be isolated in pure form by silica gel chromatography under ordinary laboratory conditions. However, at higher temperatures (>60 degrees C) 2-Re was slowly disassembled into its components until the equilibrium was established. The rate constants were measured at three different temperatures, and the Eyring plot yielded the activation enthalpy DeltaH(not equal)=35 kcal mol(-1) and the activation entropy DeltaS(not equal)=27 eu for the disassembly of the rotaxane 2-Re in Cl(2)CDCDCl(2). These thermodynamic parameters gave the activation free energy DeltaG(not equal)(off)=27.1 kcal mol(-1) at 25 degrees C. Consequently, 2-Re is one example of a novel metallomacrocycle-based rotaxane that contains a coordination bond with enough strength to allow both for isolation in pure form around room temperature and for self-assembly at higher temperatures.     

Synthesis of nanoparticles and suspensions by pulsed laser ablation of microparticles in liquid

Recent studies demonstrated that the process to produce metal and oxide nanoparticles by laser ablation of consolidated microparticles is a convenient and energy-efficient way to prepare nanoparticles. In this work, the novel process is applied to nanoparticle synthesis in the liquid environment and the results are compared with those by the gas-phase process. Metal and oxide nanoparticles are synthesized by pulsed laser ablation of the compacted metal microparticles using a Q-switched Nd:YAG laser in water. It is shown that the process is effective for preparing nanoparticle suspensions having relatively uniform size distributions. While the laser fluence and the degree of compaction strongly influence the size of the produced nanoparticle in air, the sedimentation time is shown to be the most critical factor to determine the mean size of the suspended particles.     

An enhanced common path interference optic measurement system for refractive indices and thickness

This study proposes a common path interference optical system for the measurement of refractive indices and thickness of uniaxial crystal material. The measurement system comprises an accurate Mach–Zehnder laser interferometer, a single-axis rotary stepping motor, and a computer. The laser interferometer is composed of a single-frequency He–Ne laser, two-beam splitters and two reflectors. The Mach–Zehnder laser interferometer measures the optical length difference by using its linear measurement accuracy. The proposed solution procedure enables both the refractive indices and the thickness of the optical waveplate to be obtained. The proposed design differs from conventional designs in that it does not use a heterodyne modulator with a lock-in technique. It is shown that the refractive indices and thickness of the tested optical elements can be measured rapidly and accurately.     

TEMPO-Assisted Free Radical-Initiated Peptide Sequencing Mass Spectrometry (FRIPS MS) in Q-TOF and Orbitrap Mass Spectrometers: Single-Step Peptide Backbone Dissociations in Positive Ion Mode

The present study demonstrates that one-step peptide backbone fragmentations can be achieved using the TEMPO [2-(2,2,6,6-tetramethyl piperidine-1-oxyl)]-assisted free radical-initiated peptide sequencing (FRIPS) mass spectrometry in a hybrid quadrupole time-of-flight (Q-TOF) mass spectrometer and a Q-Exactive Orbitrap instrument in positive ion mode, in contrast to two-step peptide fragmentation in an ion-trap mass spectrometer (reference Anal. Chem. 85, 7044–7051 (30)). In the hybrid Q-TOF and Q-Exactive instruments, higher collisional energies can be applied to the target peptides, compared with the low collisional energies applied by the ion-trap instrument. The higher energy deposition and the additional multiple collisions in the collision cell in both instruments appear to result in one-step peptide backbone dissociations in positive ion mode. This new finding clearly demonstrates that the TEMPO-assisted FRIPS approach is a very useful tool in peptide mass spectrometry research.

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Excited-state double proton transfer of 7-azaindole in water nanopools

The excited-state proton-transfer dynamics of 7-azaindole occurring in the water nanopools of reverse micelles has been investigated by measuring time-resolved fluorescence spectra and kinetics, as well as static absorption and emission spectra, with varying water content and isotope. 7-Azaindole molecules are found to exist in the bound-water regions of reverse micelles. The rate constant and the kinetic isotope effect of proton transfer are smaller than those in bulk water although both increase with the size of the water nanopool. The retardation of proton transfer in the bound regions is attributed to the increased free energy of prerequisite solvation to form a cyclically H-bonded 1:1 7-azaindole/water complex.     

Strong visible PL from the nc-Si thin film by Ni silicide mediated crystallization

We studied the growth of nanocrystalline silicon (nc-Si) thin film exhibiting a strong room temperature photoluminescence (PL) at 1.81–2.003 eV. The amorphous silicon was crystallized by Ni silicide mediated crystallization (Ni SMC) and then Secco-etched to exhibit the PL. The PL peak energy and intensity increase with increasing the metal density on the a-Si because of the reduction in the grain size down to 2 nm. The photoluminescence energy and peak intensity depend strongly on the Secco etch time because the grain size is reduced by etching the grain boundaries.