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981.
982.
In the 21st century, hydrogen energy is a novel energy source. Its use is expected to mitigate the problems of environmental pollution and global warming caused by the excessive use of conventional fossil fuels. The hydrogen evolution reaction (HER) for water splitting has attracted considerable attention because of its environmental friendliness. To improve electrocatalyst performance and reduce operation cost, carbon-based metal hybrid materials exhibiting high efficiency and catalytic activity have been developed. Among them, carbon dots (CDs) have garnered significant research attention and have been widely applied in biosensing, bioimaging, and energy conversion/storage because of their facile synthesis, biocompatibility, tunable photoluminescence, excellent stability, and good electronic properties. CDs are widely used as carriers in the construction of electrocatalysts prepared from carbon-based metal hybrid materials. At present, it is believed that CDs exhibit excellent confinement effects, which can effectively inhibit the growth and agglomeration of metal nanoparticles, thereby preparing well-distributed carbon-based metal hybrid materials with a uniform and controllable size. However, the formation process of the small-molecule raw materials of CDs has not been elucidated. In this study, CDs and small-molecule raw materials from synthetic CDs were used as precursors to prepare nitrogen-doped CD-supported ruthenium nanoparticle (Ru@CDs) and small-molecule-supported ruthenium nanoparticle (Ru@Molecule) hybrid materials, respectively. The interaction between the small molecules and Ru in the process of CD formation and the effect on HER performance were explored. Moreover, we prepared different carriers such as metal organic frameworks(MOF), carbon nanotubes (CNTs), and graphene (GO)-supported ruthenium nanoparticle hybrid materials. Among them, Ru@CDs exhibited controllable size and excellent dispersibility and exhibited outstanding HER activity and good stability. Ru@CDs were found to require a low overpotential of 22 mV to reach a current density of 10 mA·cm−2. Moreover, we observed the presence of an intermediate state between the molecules and CDs and demonstrated that the intermediate state exhibits no confinement effect. Furthermore, we found that with increasing calcination temperature, the intermediate state gradually changes to CDs. The unique spatial confinement between CDs and metal ions is key to the formation of monodisperse Ru nanoparticles. Our results confirmed that Ru@CDs serve as excellent HER catalyst supports. This work not only reveals the effect of the unique spatial confinement of CDs on the supported metals and their promoting effect on electrocatalytic activity but also provides guides the future development of CD-based metal hybrid electrocatalysts. 相似文献
983.
In this review, we check out the number of published literature in the field of ECL biosensors trends during nearly a decade, and compare the research status of four different types of biosensors; summarize the application forms of nanomaterials in ECL biosensor. We have an overview of the building patterns and application example of the four main types of biosensors in the paper. 相似文献
984.
Xin Sheng Li Yao Jun Zhang Qin Xin Chun Xin Ji Yan Fen Miao Li Wang 《Reaction Kinetics and Catalysis Letters》1996,57(1):177-182
Volumetric H2-uptake measurements on an Mo2N (79 m2g–1) sample reduced at 673 K have been carried out and the uptake isotherms in the temperature range of 308–623 K have been determined. Both the total and reversible hydrogen uptake increased with the uptake temperature. The irreversible hydrogen uptake increased abruptly when the uptake temperature was raised up to 423 K. The maximum of irreversible hydrogen uptake was measured at 473 K. The HIR/Mo ratio calculated from the uptakes obtained in the temperature range of 308–623 K varies in the range of 0.0010–0.0202. One possible mechanism for hydrogen adsorption is proposed to be heterolytic dissociation on Mo-N paris, in which the molybdenum atoms are in unsaturated coordination. 相似文献
985.
用ab initio能量解析梯度法,在UHF(RHF)/3-21G水平上优化得到AlCn,AlCn+(n=1~3)的四十三个构型,在RHF(UHF)/3-21G水平上优化得到AlC4,AlC4+的二十六个构型,CISD能量.从能量角度所研究的AlCn,AlCn+(n=1~4)构型中,最稳定的构型均是线性构型,且Al全都在端点上,同文献报导的理论和实验结果相一致.此外,还研究了原子簇的离子化能,原子平均结合能以及原子簇的碎片化通道和碎片化能,并计算了上述最稳定构型的谐振动光谱常数. 相似文献
986.
987.
本文报导的方法是在南京大学高鸿教授研究的K_3Fe(CN)_6示波极谱滴定法(在PH8的K_2HPO_4—KH_2PO_4—KBr底液中,用0.04660mol/LK_3Fe(CN)_6标准溶液对纯抗坏血酸测定)的基础上,考虑到L—抗坏血酸(以下简称V_e)在碱性、中性介质中稳定性差,如用于V_e含量很微的果蔬测定,对结果影响大。本文改为H_2C_2O_4—KBr的酸性介质作底液,用 相似文献
988.
Wei Luo Xiang Kai Fu Li Hua Ma 《中国化学快报》2007,18(7):883-886
The high quality TiO2, MoO3-doped WO3 electrochromic film was prepared by the sol–gel method for the first time. The sol, which has hydrogen peroxide (H2O2) and oxalic acid (H2C2O4), was very stable at room temperature and quite suitable for the deposition of films. The WO3 electrochromic film prepared from this doped sol had excellent performance, such as short response time, no cracks, good adhesion to the substrate, high coloring efficiency and longevity of service. 相似文献
989.
Equations between the differential order and the maximum of the fractional-order differential for the specified peak signals are developed based on the variation of the maximum of the specified peak signals at different orders. Also, equations between the differential order and the zero-crossing of the fractional-order differential of the specified peak signals are proposed according to the variation of the zero-crossing of the specified peak signals at different orders. Characteristic paramters of the Gaus- sian peak, Lorentzian peak, and Tsallis peak can be estimated using estimator I and estimator II which are obtained by the equations above. As a result, a new method is presented to resolve the overlapped peaks signal. Firstly, a fractional-order differential of the specified peak signals is obtained with the fractional-order differentiation filter. Then, characteristic paramters of the specified peak signals can be extracted using estimator I and estimator II. Finally, the Tsallis peak is used as a model to assign the overlapping peak signals correctly. Experimental results show that the proposed method is efficient and effective for the simulated overlapping peaks and detected overlapping voltammetric peak signals. 相似文献
990.
To obtain new materials with synergetic or complementary behaviors, polyaniline composite filled with ZnO rods in ramification-like
structure was prepared by a hydrothermal approach. Comparative experiments of ZnO preparation in the presence of some metal
ions were also carried out. The results indicated that the morphology of ZnO was strongly affected by the preparation condition.
The method to grow ZnO rods in the presence of polyaniline offers a simple approach to obtain polyaniline composite filled
with linear ZnO structure. The results of X-ray photoelectron spectroscopy show that the strong interaction between ZnO and
polyaniline possibly exists to cause the charge transfer. 相似文献