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61.
Two oxynitrides of the LnSiDN system were studied by IR spectroscopy : Nd2Si3O3N4, with a melilite-like structure and Nd4Si2O7N2 with a cuspidine-like structure. The first compound belongs to the space group D32d(P4̄21m) with two formula units per unit cell. There are 10 vibrations of B2 species and 18 of E species active in the IR. A preliminary study by neutron diffraction displayed that the oxygen and nitrogen atoms are perfectly ordered, and that two silicon atoms are bridged by an oxygen. In the present work, we compare the (SiON2)2O IR vibrations with those of silicon oxynitride previously studied and |Si2O7|6? ion in akermanite. The space group of cuspidine is C52h (P21/c with 4 formula units per unit cell. So, 21 vibrations of Au species and 21 of Bu species are active in IR absorption for Nd4Si2O7N2. The absorption bands are not as sharp as the bands in Nd2Si3O3N4. This fact might be explained by a disordered structure as the nitrogen position has not been exactly determined. 相似文献
62.
63.
The kinetics of the degradation of N-amino-3-azabicyclo[3,3,0]octane by chloramine has been studied by GC and HPLC in stoichiometric conditions in a solution buffered with NaOH/KH2PO4 and Na2B4O7.10 H2O between pH = 10.5 and 13.5. The second-order reaction exhibits specific acid catalysis which indicates competitive oxidation between the haloamine and the neutral and ionic forms of the bicyclic hydrazine. The enthalpy and entropy of activation were determined at pH = 12.89. In a nonbuffered solution, the interaction is autocatalyzed due to acidification of the mixture by the ammonium ions. In basic medium, the reaction forms an endocyclic hydrazone. A mathematical treatment based on an implicit equation allows a quantitative interpretation of all the phenomena observed over the above pH interval. This takes both the acid/base dissociation equilibria and the alkaline hydrolysis of the chloro-derivative into account. © 1995 John Wiley & Sons, Inc. 相似文献
64.
65.
M. Guillot A. Marchand F. Tchéou P. Feldmann H. Le Gall 《Zeitschrift für Physik B Condensed Matter》1981,44(1-2):41-52
The magnetic properties of single crystals of erbium iron garnet (ErIG) were studied in applied fields up to 150kOe between 1.4 and 300K. At low temperature, the macroscopic easy direction of the bulk magnetization is [100]; below the compensation temperature (80±2K), the magnetization presents non-linear field evolution. On the assumption of an isolated ground doublet, the anisotropy constantsK
i
(i=1,2) of ErIG are given byK
i
(Er)+K
i
(YIG); theK
i
are calculated as a function of theG andg tensor components. It is worthwhile noting that theK
i
(Er) are strongly temperature dependent; so at low temperature the anisotropy of the garnet is determined by the rare earth ions, while in the 50 K regionK
1(Er) becomes comparable toK
1(YIG) with the opposite sign which results in a very weak anisotropy of the garnet. Above 50 K,K
1(YIG) is predominant and the Fe3+ ions determine the garnet anisotropy. 相似文献
66.
67.
We derive microscopically precise identities for the geometry of small clusters in the equilibrium states of the two-dimensional Ising model with emphasis on near-critical phenomena. 相似文献
68.
Simon G. Bott Alan P. Marchand Sulejman Alihodzic Kaipenchy A. Kumar 《Journal of chemical crystallography》1998,28(4):251-258
The crystal structures of three compounds formed via ultimate nucleophilic attack of unsaturated hydrocarbon fragments are reported. Geometries of the bis(vinyl)-, mono(vinyl), and bis(ethynyl)-substituted PCU species are unexceptional. The crystal structures are dictated by the availability of intermolecular hydrogen bonding. 相似文献
69.
Sebastián Ceria Cécile Cordier Hugues Marchand Laurence A. Wolsey 《Mathematical Programming》1998,81(2):201-214
We investigate the use of cutting planes for integer programs with general integer variables. We show how cutting planes arising from knapsack inequalities can be generated and lifted as in the case of 0–1 variables. We also explore the use of Gomory's mixed-integer cuts. We address both theoretical and computational issues and show how to embed these cutting planes in a branch-and-bound framework. We compare results obtained by using our cut generation routines in two existing systems with a commercially available branch-and-bound code on a range of test problems arising from practical applications. © 1998 The Mathematical Programming Society, Inc. Published by Elsevier Science B.V.Corresponding author.This research was partly performed when the author was affiliated with CORE, Université Catholique de Louvain. 相似文献
70.