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991.
Generally, bacteriochlorophyllides were responsible for the photosynthesis in bacteria. Seven types of bacteriochlorophyllides have been disclosed. Bacteriochlorophyllides a/b/g could be synthesized from divinyl chlorophyllide a. The other bacteriochlorophyllides c/d/e/f could be synthesized from chlorophyllide a. The chemical structure and synthetic route of bacteriochlorophyllides were summarized in this review. Furthermore, the potential applications of bacteriochlorophyllides in photosensitizers, immunosensors, influence on bacteriochlorophyll aggregation, dye-sensitized solar cell, heme synthesis and for light energy harvesting simulation were discussed. 相似文献
992.
Nie Weidong Fan Wenlin Jiang Anqi Wu Guanghao Liu Houli Huang Li-Li Xie Hai-Yan 《中国科学:化学(英文版)》2021,64(11):1999-2009
Science China Chemistry - Insufficient tumor tropism, MHC class I molecules (MHC-I) defects of tumor cells, and immunosuppressive tumor micro-environment (TME) seriously imperil the efficacy of... 相似文献
993.
994.
WeiPing Liu ZhiHong Li JiangJun He XiaoDong Tang Gang Lian Zhu An JianJun Chang Han Chen QingHao Chen XiongJun Chen ZhiJun Chen BaoQun Cui XianChao Du ChangBo Fu Lin Gan Bing Guo GuoZhu He Alexander Heger SuQing Hou HanXiong Huang Ning Huang BaoLu Jia LiYang Jiang Shigeru Kubono JianMin Li KuoAng Li Tao Li YunJu Li Maria Lugaro XiaoBing Luo HongYi Ma ShaoBo Ma DongMing Mei YongZhong Qian JiuChang Qin Jie Ren YangPing Shen Jun Su LiangTing Sun WanPeng Tan Isao Tanihata Shuo Wang Peng Wang YouBao Wang Qi Wu ShiWei Xu ShengQuan Yan LiTao Yang Yao Yang XiangQing Yu Qian Yue Sheng Zeng HuanYu Zhang Hui Zhang LiYong Zhang NingTao Zhang QiWei Zhang Tao Zhang XiaoPeng Zhang XueZhen Zhang ZiMing Zhang Wei Zhao Zuo Zhao Chao Zhou JUNA Collaboration 《中国科学:物理学 力学 天文学(英文版)》2016,59(4):642001
Jinping Underground laboratory for Nuclear Astrophysics(JUNA) will take the advantage of the ultra-low background of CJPL lab and high current accelerator based on an ECR source and a highly sensitive detector to directly study for the first time a number of crucial reactions occurring at their relevant stellar energies during the evolution of hydrostatic stars. In its first phase, JUNA aims at the direct measurements of~(25)Mg(p,γ)~(26)Al,~(19)F(p,α)~(16)O,~(13)C(α,n)~(16)O and ~(12)C(α,γ)~(16)O reactions. The experimental setup,which includes an accelerator system with high stability and high intensity, a detector system, and a shielding material with low background, will be established during the above research. The current progress of JUNA will be given. 相似文献
995.
Selenium nanoparticles (SeNPs) are considered to be the new selenium supplement forms with high biological activity and low toxicity; however, the molecular mechanism by which SeNPs exert the biological function is unclear. Here, we reported that biocompatibility SeNPs possessed intrinsic oxidase-like activity. Using Na2SeO3 as a precursor and glutathione as a reductant, biocompatibility SeNPs were synthesized by the wet chemical reduction method in the presence of bovine serum albumin (BSA). The results of structure characterization revealed that synthesized SeNPs were amorphous red elementary selenium with spherical morphology, and ranged in size from 25 to 70 nm size with a narrow distribution (41.4 ± 6.7 nm). The oxidase-like activity of the as-synthesized SeNPs was tested with 3,3′,5,5′-tetramethylbenzidine (TMB) as a substrate. The results indicated that SeNPs could catalyze the oxidization of TMB by dissolved oxygen. These SeNPs showed an optimum catalytic activity at pH 4 and 30 °C, and the oxidase-like activity was higher as the concentration of SeNPs increased and the size of SeNPs decreased. The Michaelis constant (K m) values and maximal reaction velocity (V max) of the SeNPs for TMB oxidation were 0.0083 mol/L and 3.042 μmol/L min, respectively. 相似文献
996.
Variable electron-phonon coupling in isolated metallic carbon nanotubes observed by Raman scattering
Wu Y Maultzsch J Knoesel E Chandra B Huang M Sfeir MY Brus LE Hone J Heinz TF 《Physical review letters》2007,99(2):027402
We report the existence of broad and weakly asymmetric features in the high-energy (G) Raman modes of freely suspended metallic carbon nanotubes of defined chiral index. A significant variation in peak width (from 12 cm(-1) to 110 cm(-1)) is observed as a function of the nanotube's chiral structure. When the nanotubes are electrostatically gated, the peak widths decrease. The broadness of the Raman features is understood as the consequence of coupling of the phonon to electron-hole pairs, the strength of which varies with the nanotube chiral index and the position of the Fermi energy. 相似文献
997.
We report in situ high-resolution transmission electron microscopy observing the shrinkage of single-layer giant fullerenes (GF). At temperatures approximately 2000 degrees C, the GF volume reduces by greater than one 100-fold while the fullerene shell remains intact, evolving from a slightly polygonized to a nearly spherical shape with a smaller diameter. The number of carbon atoms in the GF decreases linearly with time until the small subbuckyball cage opens and rapidly disappears. Theoretical modeling indicates that carbon atoms are removed predominantly from the weakest binding energy sites, i.e., the pentagons, leading to the constant evaporation rate. The fullerene cage integrity is attributed to the collective behavior of interacting defects. These results constitute the first experimental evidence for the "shrink-wrapping" and "hot-giant" fullerene formation mechanisms. 相似文献
998.
J.-H. Huang S.-Y. Zhu 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2007,44(3):557-575
The normalized second-order
correlation of the emission fields from a driven four-level atomic
ensemble is investigated theoretically by using the state vector
method. The violation of Cauchy-Schwarz inequality, which indicates
the establishment of non-classical correlation between two emission
fields, has been found. The effects of various decays and time delay
on the correlation are discussed in detail, which are helpful in
finding the ways to obtain high non-classical correlation. This
technique for the generation of non-classical light is operable
based on the current experimental technology and will lead to some
potential applications in quantum information science. 相似文献
999.
In this paper we study the semileptonic decays of the Bc meson in the light-cone sum rule (LCSR) approach. The result for each channel depends on the corresponding distribution amplitude
(DA) of the final meson. For the case of Bc decaying into a pseudoscalar meson, to twist-3 accuracy only the leading twist distribution amplitude is involved if we start
from a chiral current. If we choose a suitable chiral current in the vector meson case, the main twist-3 contributions are
also eliminated and we can consider the leading twist contribution only. The leading twist distribution amplitudes of the
charmonium and other heavy mesons are given by a model approach in a reasonable way. Employing this charmonium distribution
amplitude we find a cross section that is consistent with Belle and BaBar data. Based on this model, we calculate the form factors for various Bc decay modes in the corresponding regions. Extrapolating the form factors to the whole kinetic regions, we get the decay widths
and branching ratios for various Bc decay modes including their τ modes when they are kinematically accessible.
PACS 13.20.He; 13.20.Fc; 11.55.Hx 相似文献
1000.