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111.
Cheng Wang Qing N. Chan Renlin Zhang Sanghoon Kook Evatt R. Hawkes Guan H. Yeoh Paul R. Medwell 《Journal of nanoparticle research》2016,18(5):127
The thermophoretic sampling of particulates from hot media, coupled with transmission electron microscope (TEM) imaging, is a combined approach that is widely used to derive morphological information. The identification and the measurement of the particulates, however, can be complex when the TEM images are of low contrast, noisy, and have non-uniform background signal level. The image processing method can also be challenging and time consuming, when the samples collected have large variability in shape and size, or have some degree of overlapping. In this work, a three-stage image processing sequence is presented to facilitate time-efficient automated identification and measurement of particulates from the TEM grids. The proposed processing sequence is first applied to soot samples that were thermophoretically sampled from a laminar non-premixed ethylene-air flame. The parameter values that are required to be set to facilitate the automated process are identified, and sensitivity of the results to these parameters is assessed. The same analysis process is also applied to soot samples that were acquired from an externally irradiated laminar non-premixed ethylene-air flame, which have different geometrical characteristics, to assess the morphological dependence of the proposed image processing sequence. Using the optimized parameter values, statistical assessments of the automated results reveal that the largest discrepancies that are associated with the estimated values of primary particle diameter, fractal dimension, and prefactor values of the aggregates for the tested cases, are approximately 3, 1, and 10 %, respectively, when compared with the manual measurements. 相似文献
112.
Nickel-cobalt binary oxide/reduced graphene oxide (G-NCO) composite with high capacitance is synthesized via a mild method for electrochemical capacitors. G-NCO takes advantages of reduced graphene oxide (RGO) and nickel-cobalt binary oxide. As an appropriate matrix, RGO is beneficial to form homogeneous structure and improve the electron transport ability. The binary oxide owns more active sites than those of nickel oxide and cobalt oxide to promote the redox reaction. Attributed to the well crystallinity, homogeneous structure, increased active sites, and improved charge transfer property, the G-NCO composite exhibits highly enhanced electrochemical performance compared with G-NiO and G-Co3O4 composites. The specific capacitance of the G-NCO composite is about 1750 F g?1 at 1 A g?1 together with capacitance retention of 79 % (900/1138 F g?1) over 10,000 cycles at 4 A g?1. To research its practical application, an asymmetric supercapacitor with G-NCO as positive electrode and activated carbon as negative electrode was fabricated. The asymmetric device exhibits a prominent energy density of 37.7 Wh kg?1 at a power density of 800 W kg?1. The modified G-NCO composite shows great potential for high-capacity energy storage. 相似文献
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116.
Many real-world networks such as the protein–protein interaction networks and metabolic networks often display nontrivial correlations between degrees of vertices connected by edges. Here, we analyse the statistical methods used usually to describe the degree correlation in the networks, and analytically give linear relation in the degree correlation. It provides a simple and interesting perspective on the analysis of the degree correlation in networks, which is usefully complementary to the existing methods for degree correlation in networks. Especially, the slope in the linear relation corresponds exactly to the degree correlation coefficient in networks, meaning that it can not only characterize the level of degree correlation in networks, but also reflects the speed that the average nearest neighbours’ degree varies with the vertex degree. Finally, we applied our results to several real-world networks, validating the conclusions of the linear analysis of degree correlation. We hope that the work in this paper can be helpful for further understanding the degree correlation in complex networks. 相似文献
117.
研究结果表明,只有当以k>3)为奇数时,偶q相干态呈现振幅k次方压缩性质;无论k为偶数还是奇数,奇q相干态均不呈现压缩性质。 相似文献
118.
Angelika Jungmann R. Claessen R. Zimmermann Ge Meng P. Steiner S. Hüfner S. Tratzky K. Stöwe H. P. Beck 《Zeitschrift für Physik B Condensed Matter》1995,97(1):25-34
The electronic structure of the layered compounds LaI2 and CeI2 was investigated by photoemission and electron energy loss spectroscopy. From the experimental results we are able to confirm the metallic nature of these compounds, and by using photon energy dependent measurements of the valence band we can identify the orbital character of the conduction band as essentially 5d1-like. A detailed analysis of the Ce 3d and 4f spectra yields a remarkably small 4f-5d hybridization strength, almost completely decoupling the f-electron from the conduction band, which makes CeI2 a somewhat unusual system compared to other metallic Ce compounds. Band structure calculations by Jepsen and Andersen [1] confirm these experimental results. 相似文献
119.
The adsorption of L-alanine on Cu(111) surface is studied by means of scanning tunnelling microscopy under ultra-high vacuum conditions. The results show that the adsorbates are chemisorbed on the surface, and can form a two-dimensional gas phase, chain phase and solid phase, depending on deposition rate and amount. The adsorbed molecules can be imaged as individual protrusions and parallel chains in gas and chain phases respectively. It is also found that alanine can form (2 × 2) superstructure on Cu(111) and copper step facet to (110) directions in solid phase. On the basis of our scanning tunnelling microscopic images, a model is proposed for the Cu(111)(2 ×2)-alanine superstructure. In the model, we point out the close link between (110)-direction hydrogen bond chains with the same direction copper step faceting. 相似文献
120.
The dynamical properties of Rydberg hydrogen atom near a metal surface are presented by using the methods of phase space analysis
and closed orbit theory. Transforming the coordinates of the Hamiltonian, we find that the phase space of the system is divided
into vibrational and rotational region. Both the Poincaré surface of section and the closed orbit theory verify the same conclusion
clearly. In this paper we choose the atomic principal quantum number asn=20. The dynamical character of the exited hydrogen atom depends sensitively on the atom-surface distanced. Whend is sufficiently large, the atom-surface potential can be expressed by the traditional van der Waals force and the system
is integrable. Whend becomes smaller, there exists a critical valued
c. Ford>d
c, the system is near-integrable and the motion is regular. While chaotic motion appears ford<d
c, and the system tends to be non-integrable. The trajectories become unstable and the electron might be captured onto the
metal surface. 相似文献