Synthesis and photophysical properties of novel organic–inorganic hybrid materials covalently linked to a europium complex

A novel sol–gel derived hybrid material (classed as Eu-DBM-Si) covalently grafted with Eu(DBM-OH)₃·2H₂O (where DBM-OH = o-hydroxydibenzoylmethane) was prepared through the primary β-diketone ligand DBM-OH. All the synthesized ligands were characterized by ¹H NMR, elemental analyses and Fourier transform infrared spectra (FTIR). The resultant Eu-DBM-Si material exhibited good transparent and homogenous property. Compared to the Eu-DBM hybrid prepared by physically doped silicon dioxide with Eu(DBM-OH)₃·2H₂O, the Eu-DBM-Si hybrid presented more efficient ligand-to-Eu³⁺ energy transfer and a significant improvement in the measured emission quantum yield. Furthermore, the photophysical properties of these hybrid materials, such as the photoluminescence (PL) spectra, PL intensities, symmetry properties, lifetime decays, and Judd-Ofelt parameters were also investigated in detail.     

Ytterbium(II) complex bearing a diaminobis(phenolate) ligand: synthesis, structure, and one-electron-transfer and epsilon-caprolactone polymerization reactions

The first divalent ytterbium complex supported by a diaminobis(phenolate) ligand, YbL(THF)2.0.5C7H8 (1; THF = tetrahydrofuran), was synthesized in good yield by the amine elimination reaction of Yb[N(SiMe3)2]2(THF)2 with H2L (L = [Me2NCH2CH2N(CH2-2-OC6H2-3,5-But2)2]) in a 1:1 molar ratio. X-ray structural determination shows complex 1 to be a THF-solvated monomer, which adopts a distorted octahedral coordination geometry around the Yb atom. Complex 1 can react with PhNCO and PhCCH, as a single electron-transfer reagent, to give the corresponding reduction coupling product [(YbLOCNPh)(THF)]2.4THF (2) and the alkynide complex YbLCCPh(DME) (3; DME = 1,2-dimethoxyethane). Complexes 2 and 3 have been characterized by X-ray crystal structural analysis. In complex 2, the dianionic oxamide ligand resulting from the reductive coupling of two phenyl isocyanate molecules coordinates to two Yb atoms in a mu,eta4 fashion. Complex 3 has a monomeric structure with a Yb-C(terminal phenylacetynide) bond length of 2.374(3) A. Complex 1 is also a highly efficient catalyst for ring-opening polymerization of epsilon-caprolactone.     

In situ synthesis of di-n-butyl l-tartrate–boric acid complex chiral selector and its application in chiral microemulsion electrokinetic chromatography

A novel procedure for in situ assembling a complex chiral selector, di-n-butyl l-tartrate–boric acid complex, by the reaction of di-n-butyl l-tartrate with boric acid in a running buffer was reported and its application in the enantioseparation of β-blockers and structural related compounds by chiral microemulsion electrokinetic chromatography (MEEKC) has been demonstrated. In order to achieve a good enantioseparation, the effect of dibutyl l-tartrate and sodium tetraborate concentration, surfactant identity and concentration, cosurfactant, buffer pH and composition, organic modifiers, as well as applied voltage and capillary length were investigated. Ten pairs of enantiomers that could not be separated with only dibutyl l-tartrate, obtained good chiral separation using the complex chiral selector; among them, seven pairs could be baseline resolved under optimized experimental conditions. The fixation of chiral centers by the formation of five-membered rings, and being oppositely charged with basic analytes were thought to be the key factors giving the complex chiral selector a superior chiral recognition capability. The effect of the molecular structure of analytes on enantioseparation was discussed in terms of molecular interaction.     

Crack tip field in a linear elastic–plastic strain-hardening material

The strip necking model for strain-hardening materials is studied in this paper, in which the stress distributed over the strip necking zone is assumed to be ultimate stress. The bi-linear stress–strain relation which can model certain features of plastic flow is adopted in this model. The stress and strain fields are calculated based on this model in this paper. The size of the strip necking region is determined by balancing the stress intensity factor due to remote loading with that due to assumed closing forces equal to the ultimate tensile strength of the material distributed over the strip necking zone. It is interesting that the strip necking region size and the crack tip opening displacement depend not only on the remote load, but also the material hardening parameters, which is different from the results of strip yield model. The results agree with experiments well, and the model has wider application.     

变截面含筋夹层复合材料悬臂结构刚度特性规律研究

含筋夹层复合材料悬臂结构现已在舰船工程应用中得到关注,然而因为变量众多,在方案设计阶段对弯曲刚度特性的把握往往较为困难.对此,首先基于典型结构应用背景需求,建立了变截面含筋夹层复合材料梁弯曲刚度理论计算模型;进而制作结构模型,开展刚度特性试验研究,通过试验与计算结果的对比,验证了计算方法的有效性;最后探讨了各主要构件材料参数、面板混杂纤维含量、面腹板截面分配以及腹板铺层比例对刚度的影响规律,所得结论可为变截面含筋夹层复合材料悬臂结构方案设计提供参考.     

EFFECT OF MAGNETIC NANOPARTICLES ON THE MECHANICAL PROPERTIES OF TYPE-II SUPERCONDUCTORS

In this paper, the effect of magnetic nanoparticles on the mechanical properties of a type-II superconductor is investigated both theoretically and numerically. Magnetic part of the pinning force associated with the interaction between a finite-size spheroidal magnetic inclusion and an Abrikosov vortex is calculated in the London approximation. It is found that the size and shape of magnetic nanoparticles result in different enhancements of vortex pinning in large-κtype-II superconductors. Meanwhile, the screening current induced by a magnetic spheroid suffer the action of Lorentz force, which will lead to prestress in the superconductor, so further numerical calculations are needed to explore the interaction between the spheroidal magnetic particle and superconductor. The distribution of displacement, stress and strain in the superconductor are finally obtained. It is shown that different sizes and shapes of nanoparticles also can change the distributions of these quantities.     

Ramsey interaction with transverse decay

The Ramsey fringe contrast of a pulsed optically pumped cold atom clock is strongly affected by the transverse decay of the atomic sample. This letter calculates the Ramsey fringe with focus on transverse decay, and analyzes the Ramsey fringe contrast with different transverse decay rates. By fitting the experimental data, we obtain the transverse decay rate in a cold atom sample at an approximate value of 30.5 s1 , which is much smaller than that in a cell.     

可扩展的用于量子信息处理的刻槽平面离子芯片设计

研究设计了一个有效的可扩展的二维刻槽离子芯片。为了减少激光在离子芯片表面的散射,使被囚禁离子更加稳定,并使激光容易控制和探测成行的被囚禁离子,在每两个平行的射频电极中间刻槽使冷却光和探测光路径可穿过芯片。把控制离子运动的直流电极跟射频电极分开,减轻了不同电压对被囚禁离子的干扰,改进了对离子的控制。用有限元分析的方法对芯片表面上方的电势分布做了计算模拟。模拟结果表明,在这种新型的刻槽可扩展芯片上可以生成一个可扩展的离子阱阵列。这种结构提供了一个新颖的刻槽二维平面离子芯片,被囚禁其上的线形离子阵列可用来进行大型的量子信息处理。     

亏损系统模态优化控制Riccati方程的求解方法

讨论亏损重复特征值的Ｒｉｃｃａｔｉ方程的模态控制算法．由于亏损特征值的Ｊｏｒｄａｎ块矩阵的阶数ｍ小于状态方程的阶数ｎ,即ｍ＜＜ｎ;所提出的模态控制算法可极大地减少计算工作量．其中的数值例子说明了该方法的有效性．