Computer-generated kinoforms of real-existing full-color 3D objects using pure-phase look-up-table method

A computational method based on pure-phase look-up-table (LUT) is proposed for generating kinoforms of full-color real-existing three-dimensional (3D) objects. The principle of the pure-phase LUT method is described. 3D depth as well as color information of a full-color 3D object is obtained by the full-color 3D profile measurement approach based on binocular vision. The obtained full-color 3D data is decomposed into red (R), green (G), and blue (B) channels, and kinoforms of each channel are calculated from the depth map and color information of the corresponding channel using the pure-phase LUT method. In order to reduce the speckle noise of reconstructed full-color 3D image, sequential kinoforms of each color channel are generated by adding dynamic-pseudorandom phase factor into the object domain. Numerical reconstruction and optical reconstruction with a phase-only spatial light modulator (SLM) show that, with the proposed method, full-color holographic 3D display of real-existing full-color 3D objects is available.     

Femtosecond laser nanostructuring of silver film

In this paper, we report an evolution of surface morphology of silver film irradiated by a 1 kHz femtosecond laser. By SEM observations, it is noted that different nanostructures with respective surface features depend highly on the number of pulses and the laser fluence. Especially when the laser fluence is below the threshold fluence of film breakdown, a textured nanostructure including many nanobumps and nanocavities will appear on the surface of silver film. In order to determine an optimal regime for nanostructuring silver film and to further study the underlying mechanism, we perform a quantitative analysis of laser fluence and pulse number. The results show that this nanostructure formation should be due to a sequential process of laser melting, vapor bubbles bursting, heat stress confinement, and subsequent material redistribution. As a potential application, we find this nanostructured silver film can be used as the active substrate for surface enhanced Raman scattering effect.     

高氯酸-硫酸消化植物样品防止氮素损失的研究

本文研究利用加纯水缓冲的方法,使H_2SO_4-HClO_4消煮液的氧化能力随消化时间的推移而逐渐增强,与植物材料分解前易后难的规律相吻合,有效地防止了氮在消煮过程中的损失。比较表明,该方法准确度和精密度都达到K氏法水平,同时还具有操作简便、省时,对磷和钾的测定无干扰等特点,尤其适用于作物诊断样中氮、磷、钾的联合消化。     

Generation of a hollow laser beam by a multimode fiber

A simple method to generate a hollow laser beam by multimode fiber is reported. A dark hollow laser beam is generated from a multimode fiber and the dependence of the output beam profile on the incident angle of laser beam is analyzed. The results show that this hollow laser beam can be used to trap and guide cold atoms.     

电活性聚合物圆柱壳静态与动态电压下的响应及稳定性

摘要：在电活性聚合物圆柱壳内外表面施加电压,圆柱壳会变薄并且伸长,因此相同的电压会在圆柱壳内产生更大的电场。这个正反馈可能使圆柱壳厚度不断变薄,最终导致其失稳破坏。本文研究了电活性聚合物圆柱壳在静态和周期电压作用下的响应及稳定性问题。采用neo-Hookean材料模型得到描述圆柱壳表面运动的非线性常微分方程。给出了圆柱壳在不同厚度和边界条件下外加电压随圆柱壳变形的变化曲线,结果表明存在一个临界电压,当外加电压大于这一临界值时,圆柱壳将被破坏。同时,也讨论了厚度和边界条件对临界电压的影响。圆柱壳在正弦周期电压作用下,其运动随时间的变化是周期性的或拟周期性的非线性振动。给出了圆柱壳振动固有频率的计算结果,采用打靶法得到圆柱壳振动的周期解,并且用数值法研究了周期解的稳定性。采用数值仿真得到圆柱壳振动振幅随外加动态电压激励频率的变化曲线,结果表明圆柱壳会发生多频共振,共振时圆柱壳振幅发生跳跃,导致圆柱壳失稳破坏。最后给出共振点临近点的振动曲线和相图,并对其振动特性进行讨论。     

压电材料反平面III型裂纹电塑性区的分析

本文对反平面III型裂纹电塑性区进行了分析。采用条带模型得到了电塑性区大小的表达式。对于电塑性区的边界条件采用了两种处理方式,一是采用机械位移连续性边界条件,另一种是假设电塑性区的切应力保持为常数的假设。其中后一种处理方式消除了电场和应力在裂纹尖端的奇异性,与实际情况相符合。两种处理方式得到了相同的电塑性区的大小的表达式,并根据两种处理方式计算了能量释放率。类比Irwin的应力松弛模型,本文采用电位移松弛模型同样得到了电塑性区的大小。将条带模型得到的结果与电位移松弛模型得到的结果进行比较发现,在小范围塑性变形条件下,两种方法所得的结果比较接近,从而说明这两种方法的有效性,得到了比较满意的结果。     

均布荷载作用下功能梯度简支梁弯曲的解析解

利用应力函数半逆解法,研究了均布载荷作用下、材料属性在厚度上任意变化的功能梯度简支梁弯曲的解析解,给出了各向应力应变与位移的解析显式表达式.首先根据平面应力状态的基本方程,得出了功能梯度梁的应力函数应满足的偏微分方程,并根据应力边界条件得出了各应力分布的表达式;进而根据功能梯度材料的本构方程和位移边界条件,得出了应变和位移的分布.最后,通过将本文的解退化到均质各向同性梁并与经典弹性解比较,证明了本文理论的正确性,并求解了材料组分呈幂律分布的功能梯度梁的应力和位移分布,分析了上下表层材料的弹性模量比λ与组分材料体积分数指数n对应力和位移分布的影响.     

CuBr2/N,N,N′,N′‐Tetra[(2‐pyridal)methyl]ethylenediamine/Tertiary Amine as a Highly Active and Versatile Catalyst for Atom‐Transfer Radical Polymerization via Activator Generated by Electron Transfer

Summary: A highly active and versatile CuBr₂/N,N,N′,N′‐tetra[(2‐pyridal)methyl]ethylenediamine (CuBr₂/TPEN)‐tertiary amine catalyst system has been developed for atom transfer radical polymerization via activator‐generated‐by‐electron‐transfer (AGET ATRP). The catalyst mediates good control of the AGET ATRPs of methyl acrylate, methyl methacrylate, and styrene at 1 mol‐% catalyst relative to initiator. A mechanism study shows that tertiary amines such as triethylamine reduces the CuBr₂/TPEN complex to CuBr/TPEN.

The GPC traces of PSt, PMA, and PMMA prepared by AGET ATRP at 1 mol‐% of catalyst relative to initiator are monomodal and have low polydispersities.     

A new method to retrieve aerosol optical thickness from satellite images on a parallel system

A wide variety of algorithms have been developed to monitor aerosol burden from satellite images. Still, few solutions currently allow for real-time and efficient retrieval of aerosol optical thickness （AOT）, mainly due to the extremely large volume of computation necessary for the numeric solution of atmospheric radiative transfer equations. Taking into account the efforts to exploit the SYNergy of Terra and Aqua Modis （SYNTAM, an AOT retrieval algorithm）, we present in this paper a novel method to retrieve AOT from Moderate Resolution Imaging Spectroradiometer （MODIS） satellite images, in which the strategy of block partition and collective communication was taken, thereby maximizing load balance and reducing the overhead time during inter-processor communication. Experiments were carried out to retrieve AOT at 0.44, 0.55, and 0.67μm of MODIS/Terra and MODIS/Aqua data, using the parallel SYNTAM algorithm in the IBM System Cluster 1600 deployed at China Meteorological Administration （CMA）. Results showed that parallel implementation can greatly reduce computation time, and thus ensure high parallel efficiency. AOT derived by parallel algorithm was validated against measurements from ground-based sun-photometers; in all cases, the relative error range was within 20%, which demonstrated that the parallel algorithm was suitable for applications such as air quality monitoring and climate modeling.     

Structural and electrochemical investigations of the high fluoride affinity of sterically hindered 1,8-bis(boryl)naphthalenes

The reaction of 10-bromo-9-oxa-10-boraanthracene with the tetrakis(tetrahydrofuran)lithium salt of dimesityl-1,8-naphthalenediylborate in diethyl ether affords 1-(dimesitylboryl)-8-(10'-bora-9'-oxaanthryl)naphthalene (2). This diborane reacts with [Me3SiF2][S(NMe2)3)] to afford the anionic complex [2-mu2-F]-, which has been isolated as a [S(NMe2)3]+ salt. The cyclic voltammograms of diborane 2 as well as 1-(dimesitylboryl)-8-(10'-bora-9'-thiaanthryl)naphthalene (1) exhibit two reversible reductions at E(1/2) = -2.200 and -2.566 V (vs FcH/FcH+) for 1 and E(1/2) = -2.248 and -2.620 V (vs FcH/FcH+) for 2 corresponding to the sequential reduction of the two boron centers. These two waves simultaneously disappear upon fluoride addition, thus indicating the formation of fluoride chelate complexes [1-mu2-F]- and [2-mu2-F]-. To identify the origin of the high fluoride affinity displayed by these diboranes, the structures of 2 and [2-mu2-F]- have been studied experimentally and computationally. The crystallographic studies show that the structure of 2 is distorted, thus indicating the presence of important steric repulsions between the neighboring boryl moieties. By contrast, the structure of the anionic complex [2-mu2-F]- is much more sterically relaxed than that of 2, as indicated by a reduction of the B-B distance from 3.279(4) A in 2 to 2.922(7) A in [2-mu2-F]-. The structural results suggest that the high fluoride affinity displayed by 2 results, at least in part, from the relief of steric repulsions induced by fluoride binding. Finally, the nature of the bonding as well as the strength of the interactions involved in the B-F-B bridge of [2-mu2-F]- has been studied using density functional theory calculations and Atoms-In-Molecules analyses. These calculations indicate that the enthalpic gain associated with the formation of two B-F bonds in [2-mu2-F]- only amounts to a fraction of the energy of a terminal B-F bond. These calculations also suggest that the relief of steric repulsions induced by fluoride binding in 2 may contribute to the high fluoride affinity of these types of molecules.