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11.
12.
Mohammad Ali Bigdeli Abbas Rahmati Hossein Abbasi-Ghadim Gholam Hossein Mahdavinia 《Tetrahedron letters》2007,48(26):4575-4578
Aromatic amines have been synthesized efficiently from enamines using SnCl4 and SbCl5 in CH2Cl2 at room temperature. 相似文献
13.
In the present study, to remove methylene blue (MB) from aqueous solution, some agricultural residues and cheap bioadsorbents such as sawdust of palm trees, eucalyptus, and sour lemon were used. To do this, significant parameters like contact time, temperature, pH, initial concentration, and adsorbent dosage were checked. The results affirmed that the best conditions for MB adsorption from aqueous solution were obtained such as the temperature of 25?°C, pH of 8, adsorbent dosage of 2g/L, contact time of 120?minutes, and dye concentration of 5?mg/l which under these conditions the adsorption efficiencies determined were 95.8, 93.4, and 92.8% using sawdust of palm tree, eucalyptus, and sour lemon, respectively. Also, the equilibrium behavior of adsorbents showed that the Freundlich model could better predict the adsorption behavior of the process due to having a larger correlation coefficient (R2). The maximum biosorption capacities by Langmuir isotherm model were also obtained 54, 53.5, and 52.4?mg/g for sawdust of palm trees, eucalyptus, and lemon, respectively, which were significant amounts. In addition, kinetic behavior of adsorption showed that pseudo-second-order model can describe the kinetics of the adsorption process better than the pseudo-first-order model. Moreover, kinetic, equilibrium, and thermodynamic behaviors of adsorption affirmed that the biosorption process was desirable, physisorption, spontaneous, and exothermic. 相似文献
14.
Majid M. Heravi Khadijeh Bakhtiari Negar M. Javadi Hossein A. Oskooie Fatemeh F. Bamoharram 《Monatshefte für Chemie / Chemical Monthly》2007,138(5):445-447
Summary. Acetylation of various alcohols and benzyl amine was tested in the presence of H6[PMo9V3O40], a mixed addenda heteropolyacid, in ethyl acetate under reflux condition. Phenols and anilines are not affected under the
reaction conditions. Selective transestrification of alcohols can be achieved in the presence of phenol and aniline derivatives
using this method. 相似文献
15.
Hadis Azin Mohammad Hossein Heydari Fakhrodin Mohammadi 《Mathematical Methods in the Applied Sciences》2022,45(1):411-422
In this paper, the Vieta–Fibonacci wavelets as a new family of orthonormal wavelets are generated. An operational matrix concerning fractional integration of these wavelets is extracted. A numerical scheme is established based on these wavelets and their fractional integral matrix together with the collocation technique to solve fractional pantograph equations. The presented method reduces solving the problem under study into solving a system of algebraic equations. Several examples are provided to show the accuracy of the method. 相似文献
16.
Hossein Fazli HongGuang Sun Juan J. Nieto 《Mathematical Methods in the Applied Sciences》2022,45(1):197-205
We consider the solvability of fractional differential equations involving the Riesz fractional derivative. Our approach basically relies on the reduction of the problem considered to the equivalent nonlinear mixed Volterra and Cauchy-type singular integral equation and on the theory of fractional calculus. By establishing a compactness property of the Riemann–Liouville fractional integral operator on Lebesgue spaces and using the well-known Krasnoselskii's fixed point theorem, an existence of at least one solution is gleaned. An example is finally included to show the applicability of the theory. 相似文献
17.
In a position-space renormalization group (PSRG) approach to percolation one calculates the probabilityR(p,b) that a finite lattice of linear sizeb percolates, wherep is the occupation probability of a site or bond. A sequence of percolation thresholdsp
c
(b) is then estimated fromR(p
c
,b)=p
c
(b) and extrapolated to the limitb to obtainp
c
=p
c
(). Recently, it was shown that for a certain spanning rule and boundary condition,R(p
c
,)=R
c
is universal, and sincep
c
is not universal, the validity of PSRG approaches was questioned. We suggest that the equationR(p
c
,b)=, where isany number in (0,1), provides a sequence ofp
c
(b)'s thatalways converges top
c
asb. Thus, there is anenvelope from any point inside of which one can converge top
c
. However, the convergence is optimal if =R
c
. By calculating the fractal dimension of the sample-spanning cluster atp
c
, we show that the same is true aboutany critical exponent of percolation that is calculated by a PSRG method. Thus PSRG methods are still a useful tool for investigating percolation properties of disordered systems. 相似文献
18.
Nitro aromatic compound can be obtained in high yields via nitration of aromatic compound with wet carbon-based solid acid and NaNO_3 under solvent free oxidation at room temperature. 相似文献
19.
A simple and selective method for rapid and efficient concentration and determination of μg l−1 levels of Au(III) ions in aqueous solution using octadecyl silica membrane disks modified by pentathia-15-crown-5 and flame atomic absorption spectrometry is presented. The influence of flow rates of eluent and sample solution, amount of ligand, types and least amount of eluent for elution of Au from disks were investigated. Break through volume and limit of detection of the membrane disks modified by 5 mg of the thiacrown ether was found to be 2.0 l and 1.0 μg l−1, respectively. The effects of various cationic interferences on percent recovery of gold were studied. The method was successfully applied for the determinations of gold in some pharmaceutical samples and for the recovery of trace Au3+ ions from synthetic and water samples. 相似文献
20.
Summary A study has been undertaken to develop a solvent extraction system for mercury using Alamine 304 in aqueous chloride medium. The parameters investigated included reagent concentration, acid concentration, pH, aqueous to organic phase ratio, and rate of extraction and stripping. The study shows that mercury can be extracted rapidly and efficiently from aqueous chloride solutions. A number of aqueous stripping reagents removed more than 90% of the mercury from the organic phase with only one equilibrium. These include HNO3, NaOH and EDTA.
Extraktion von Quecksilber mit Alamin 304
Zusammenfassung Die Extraktion von Quecksilber aus der wäßrigen Lösung des Chlorids mit Alamin 304 wurde untersucht. Die Konzentration des Reagens, der Säure, das pH, das Verhältnis der wäßrigen zur organischen Phase sowie das Extraktionsverhältnis wurden geprüft. Die Extraktion verläuft rasch und wirkungsvoll. Eine Reihe wäßriger Reagenzien entzieht mehr als 90% des Quecksilbers aus der organischen Phase. Dazu gehören Salpetersäure, Natronlauge und EDTA.相似文献