An efficient synthesis of pentasubstituted pyrroles: one-pot four-component reaction of arylamine,acetylenedicarboxylate, arylglyoxal,and symmetrical 1,3-dicarbonyl compounds

An efficient and catalyst-free for the synthesis of dialkyl 5-(aryl)-4-(1,3-dicarbonyl)-1-(aryl)-1H-pyrrole-2,3-dicarboxylate via a novel one-pot four-component reaction of arylamine, acetylenedicarboxylate, arylglyoxal, and 1,3-dicarbonyl compounds in ethanol is reported. All the products were obtained in excellent yields and their structures were established from their spectroscopic data.     

Sensitive Detection of Histamine at Metal-Organic Framework (Ni-BTC) Crystals and Multi-Walled Carbon Nanotubes Modified Glassy Carbon Electrode

Russian Journal of Electrochemistry - In this study a new electrochemical histamine sensor was proposed by using Ni-based metalorganic framework (Ni-BTC, BTC = 1,3,5-benzenetricarboxylate) crystals...     

Connectionist intelligent model estimates of convective heat transfer coefficient of nanofluids in circular cross-sectional channels

Journal of Thermal Analysis and Calorimetry - The effect of Na2CO3 additive on the steam gasification characteristics of Sunjiahao (SJH) coal char was studied in the present paper. Na2CO3-catalyzed...     

A New Application of the Differential Quadrature Element-Incremental Method in Moving-Boundary Problems

Upper bounds on the permeability of random porous media are presented, which improve significantly on existing bounds. The derived bounds rely on a variational formulation of the upscaling problem from a viscous flow at the pore scale, described by Stokes equation, to a Darcy formulation at the macroscopic scale. A systematic strategy to derive upper bounds based on trial force fields is proposed. Earlier results based on uniform void or interface force fields are presented within this unified framework, together with a new proposal of surface force field and a combination of them. The obtained bounds feature detailed statistical information on the pore morphology, including two- and three-point correlation functions of the pore phase, the solid–fluid interface and its local orientation. The required spatial correlation functions are explicitly derived for the Boolean model of spheres, in which the solid phase is modelled as the union of penetrable spheres. Existing and new bounds are evaluated for this model and compared to full-field simulations on representative volume elements. For the first time, bounds allow to retrieve the correct order of magnitude of permeability for a wide range of porosity and even improve on some estimates. However, none of the bounds reproduces the non-analytic behaviour of the permeability–porosity curve at low solid concentration.     

Bifunctional aminosilane-functionalized Fe3O4 nanoparticles as efficient sorbent for preconcentration of cobalt ions from food and water samples

Research on Chemical Intermediates - Magnetic Fe3O4 nanoparticles were synthesized by a coprecipitation method, then their surface was covered and modified by...     

Oxidative dimerization of thiols to disulfide using recyclable magnetic nanoparticles

Research on Chemical Intermediates - Dimerization of thiol groups to disulfide is an important transformation in chemical processes. In this study, magnetic ion exchanged Montmorillonite-k10 was...     

A quantitative structure–mobility relationship of organic acids using solvation parameters

A quantitative structure–mobility relationship (QSMR) is proposed to estimate the electrophoretic mobility of diverse sets of analyses in capillary zone electrophoresis using Abraham solvation parameters of analyses, such as the excess molar refraction, polarizability, hydrogen bond acidity, basicity, and molar volume. QSMR was developed for prediction the electrophoretic mobility of 231 organic acids using the solvation parameters calculated by Abraham. Multiple linear regression (MLR) as a linear model and artificial neural network (ANN) methods were used to evaluate the nonlinear behavior of the involved parameters. The prediction results are obtained by nonlinear model, ANN, seem to be superior over MLR and were in good agreement with experimental data. In the proposed ANN–QSMR model, the overall mean percentage deviation values were 5.6, 5.4, and 5.3% and the coefficients of determinations (R²) were 0.84, 0.84, and 0.84 for training, test, and verification set, respectively. To investigate the robustness of the model, cross-validation methods have been established, i.e., leave-one-out and leave-N-out (N?=?5 and 10) and model is showed good predictive ability against data variation in cross-validation process. This model is not only able to accurately predict the migration order of a diverse set of organic acids but also model finds that solvation parameters are responsible in separation mechanism.     

Spinel cobalt manganese oxide nano-composites grown hydrothermally on nanosheets for enhanced photocatalytic mineralization of Acid Black 1 textile dye: XRD,FTIR, FESEM,EDS and TOC studies

Spinel cobalt manganese oxide nano-composites were grown on nanosheets using acetate precursors in mono-ethylene glycol. Crystal structures and morphologies of nano-composites were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy and energy dispersive X-ray spectroscopy to characterize the element composition. Fourier transform infrared spectroscopy was used for structural characterization and UV–Vis diffuse reflectance spectra (UV–Vis DRS) for optical properties. XRD results showed tetragonal spinel cobalt manganese oxide (Co,Mn)(Co,Mn)₂O₄ and cubic spinel cobalt manganese oxide MnCo₂O_4.5 structural phases. The crystallite size calculated by the Scherrer’s equation was 17 nm. The morphological studies displayed the existence of 40–63 nm nano-powders grown on nanosheets with a good degree of crystallization. Optical properties of cobalt manganese oxide nano-composites exhibit absorbance edge, and the band gap calculated from UV–Vis DRS results was 1.78 eV. FTIR spectra indicated that hydroxyl and oxide groups were major active sites. The absorption bands observed at 656 and 568 cm^?1 are related to stretching vibrations of Mn–O and Co–O, respectively. The photocatalytic activities of nano-composites for photocatalytic mineralization of Acid Black 1 textile dye showed an outstanding performance. Photocatalytic process yielded 91% total organic carbon removals within 2.5 h of irradiation. The enhanced photocatalytic activity was attributed to better charge separation of the photo-generated electron–hole pairs in nano-composite.