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991.
A hot rolled API X-70 steel plate and its heat-affected zone (the region with the maximum hardness and lowest toughness of the welded joint made using this steel) were employed to obtain the material’s room temperature elasto-plastic fracture toughness, JIc, by means of small punch tests (SPTs) using both conventional un-notched samples and longitudinally-notched SPT specimens. In the latter case, the notches were manufactured by micromachining different notch depth-to-thickness ratios (a/t?=?0.3 and 0.4). The representative toughness parameter used with the conventional SPT tests was the maximum strain measured directly in the failed region, while in the case of the notched samples, the consumed energy until the initiation of a crack from the tip of the notch was considered the most useful parameter of choice. The onset of crack initiation was determined directly from the load-displacement plot of each test with the aid of scanning electron microscope observations performed on different samples over which interrupted tests had been conducted. These tests were interrupted at different percentages of the maximum registered load. A simple correlation between the energy consumed until the initiation of crack growth in the notched SPT sample and the critical J value obtained using standard tests (J-R curves) was determined, defining an easy and promising way to derive fracture toughness from miniature SPT tests. 相似文献
992.
γ-Carboxylation of β-diketones, 1, can be improved using samples containing 100% of ketoenol tautomers, 3, prepared by mild hydrolysis of the corresponding copper(II) complexes 2. Cyclization of the so formed 4-alkyl-3,5-dioxohexanoic acids, 4, affords 5-alkyl-4-hydroxy-6-methyl-2-pyrones, 5. 相似文献
993.
Nicolás D. Gómez Violeta D'Accurso V. Mariana Freytes Francisco A. Manzano Jorge Codnia M. Laura Azcárate 《国际化学动力学杂志》2013,45(5):306-313
An experimental setup that coupled IR multiple‐photon dissociation (IRMPD) and laser‐induced fluorescence (LIF) techniques was implemented to study the kinetics of the recombination reaction of dichlorocarbene radicals, CCl2, in an Ar bath. The CCl2 radicals were generated by IRMPD of CDCl3. The time dependence of the CCl2 radicals’ concentration in the presence of Ar was determined by LIF. The experimental conditions achieved allowed us to associate the decrease in the concentration of radicals to the self‐recombination reaction to form C2Cl4. The rate constant for this reaction was determined in both the falloff and the high‐pressure regimes at room temperature. The values obtained were k0 = (2.23 ± 0.89) × 10?29 cm6 molecules?2 s?1 and k∞ = (6.73 ± 0.23) × 10?13 cm3 molecules?1 s?1, respectively. 相似文献
994.
995.
A fast procedure has been developed for the direct determination of paint solvents. The method is based on the injection of small volumes of untreated solvent mixtures into a heated Pyrex glass reactor in which the sample is volatilized and introduced by means of a flow of nitrogen into an IR multiple pass gas cell and the spectrum in the mid-IR region is registered as a function of time. Data found for samples are interpolated in calibration graphs obtained by injecting different volumes of pure compounds which constitute the solvent mixture. A methylisobutylketone (MIBK) toluene mixture was used as test system to develop the proposed procedure. The method provides a limit of detection of the order of 1–4 μg, a relative standard deviation of the order of 0.4 to 2% for five independent measurements, and recovery percentage values from 99.8 till 103.6 %. A commercial sample of polyurethane paint solvent has been analysed by the developed procedure. 相似文献
996.
Sonia Dopico‐García Ana Ares‐Pernas Jorge Otero‐Canabal Mar Castro‐López José M. López‐Vilariño Victoria González‐Rodríguez María J. Abad‐López 《先进技术聚合物》2013,24(8):723-731
Nowadays, there is a growing availability of biodegradable industrial materials intended to food contact applications whose service life behavior needs to be further investigated. This article is focused on the degradation of two materials based on polylactic acid. The correlation between the rate of degradation and the amount of trapped degradation products was investigated applying three characterization techniques in parallel, namely rheology, high‐performance liquid chromatography (HPLC), and matrix‐assisted laser desorption/ionization (MALDI). The rate of degradation was studied through the evaluation of their rheological properties and calculation of the number of average molecular weights, and weight‐average molecular weights. Water‐soluble oligomers and lactic acid were quantified by HPLC‐ultraviolet. Changes in cyclic and linear oligomers were monitored by MALDI‐time‐of‐flight mass spectrometry. Specimens of 4‐mm thickness of each biopolymer were subjected to hydrolysis in deionized water up to 6 months at two temperatures, simulating service conditions of food packaging. The diminution in viscosity and consequently in molecular weight distribution (20–60%) showed the degradation of the molecular structure of both polylactic acids. The chain scission was followed through the increasing values of lactic acid and hydrolyzed oligomers (twofold to eightfold), and the predominant signal of the linear oligomers over the cyclic ones with aging. Rheology, HPLC, and MALDI showed to be complementary tools to better understand the changes in the molecular structure. The obtained results showed the necessity of adding suitable stabilizers for each particular food packaging application. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
997.
Abstract The influence of the composition of the initiator system used in the polymerization of PGE is studied. Structural studies of intermediate species by NMR and IR spectroscopies are made which allow confirmation of some characteristics on the previously proposed mechanism and clarification of the mechanism leading to the chlorinated insoluble polymer fraction. This can be explained by the formation of halogenated oligomers in the first stage of the reaction which interchange with different aluminum alkoxides to give another type of initiator system. 相似文献
998.
Soft molecular electrostatic potentials (SMEP or SEMP) have been recently defined substituting the point-like proton by a Gaussian positive charge distribution. In the present paper an additional step is taken forward, transforming SMEP into a completely soft MEP (CoSMEP). Such transformation is carried out using a charge distributed proton as in SMEP and also a Gaussian positive nuclear charge distribution, instead of the classical point-like nuclear charges. The general form of MEP is roughly preserved, but new features can be noticed. Such new point of view is also associated to the possibility to redefine the molecular charge density. Definition of CoSMEP is thus connected to the definition of total molecular density functions (DF), where to the negative electronic DF is summed up the soft nuclear DF, made of linear combinations of Gaussian distributions of nuclear charges. 相似文献
999.
1000.