PH, PD和PT分子常数理论研究

采用内收缩多参考组态相互作用(MRCI)方法和包含Davidson修正(+Q) 的MRCI方法结合相关一致基aug-cc-pV5Z研究了PH (X³Σ^-, a¹Δ和A³∏)分子的势能曲线. 在同位素质量识别的基础上对势能曲线进行拟合, 得到PH, PD和PT分子各个电子态的光谱常数(T_e, R_e, ω_e, ω_ex_e, α_e和 B_e). 通过与已有实验数据的比较发现, 本文的结果与实验结果非常一致. 对于PH, PD和PT分子的Σ^-电子态, 计算得到了J = 0时的前12个振动态. 对于每一个振动态, 还分别计算了它的振动能级、惯性转动常数和离心畸变常数. 与其他理论结果和实验数据进行比较可知, 本文的结果更精确、更完整. 文中PD和PT分子的光谱常数和分子常数均属首次报导.     

激光调频连续波测距的精度评定方法研究

基于双光纤光路等光频重采样原理,提出了一种距离精度的评定方法.通过推导噪声背景下等光频重采样信号中距离参量的克拉美-罗下边界,得到了影响系统测距精度的两个重要因素:信噪比和扫描带宽,并进行了实验验证.实验表明,该评价方法并不会受到任何距离估算方法的影响,根据此方法可以选择一个最优的距离估算方法.通过对两个影响精度的因素进行仿真分析可知,在扫描带宽为2.2 nm时,若将测量光路的信噪比提升至70 dB以上,系统可获得低于10μm的测距精度.该精度评定方法可为后续改善调频连续波测距系统性能提供理论参考.     

Surface anchoring energy and the first order Fréedericksz transition of a NLC cell

Many authors have suggested new forms to describe the surface anchoring energy of the liquid crystal-wall interface, replacing the Rapini-Papoular (RP) formula g s = (1/2) A sin2 theta. If the RP function is considered as the primary approximation, and a lowest order modification is included, then the surface anchoring energy can be represented by g s = (1/2) A sin2 theta(1 + zeta sin2 theta). zeta characterizes the modification to the RP formula and varies for the different energy forms. It is well known that the RP formula predicts a second order Freedericksz transition. This paper points out that the transition can be first order if the modification is taken into account, in which case at the threshold point the tilt angle of the director at the middle layer of the cell, thetam, is finite. The conditions for the existence of the first order transition are obtained; zeta < 0 is required for a first order transition. The approximate expression of the threshold field is also given.     

SYNTHESIS OF CeO2 NANOPARTICLES IN W/ O MICROEMULSION

The phase composition and properties of microemulsion system of Titron N-101 / n-pentanol/ n-octane/ water (ammonia solution) were studied. CeO₂ nanopaticles were prepared by the reaction of cerous nitrate.     

两种测定果汁中钾磷含量方法的比较与分析

采用微波消解-等离子体发射光谱法同时测定果汁中K、P含量,优化了实验所需的各种条件。与国家标准方法湿法消解-分光光度法的测定结果作了实验比较,结果表明本实验方法更简单、高效,节省了样品的前处理时间,减小了最终结果的误差。该法灵敏度高、线性范围宽、加标回收率高,结果令人满意。     

Open‐cage fullerenes as tailor‐made container for a single water molecule

Water is the most important liquid on earth. Clusters of water have been investigated extensively in an effort to understand the bulk property of water. But the behavior of single water molecule without H‐bond has been rarely studied. Open‐cage [60]fullerenes have been shown to trap a single water molecule selectively over molecules with comparable size and act as the smallest “water bottle”. Copyright © 2013 John Wiley & Sons, Ltd.     

Diels–Alder dimerization of Morita–Baylis–Hillman acetates catalyzed by organocatalysts

DABCO-catalyzed dimerization of Morita–Baylis–Hillman acetates to synthesize a series of 3-alkyl-4-(E)-alkenyl-cyclohex-1-ene-1,4-dicarbonyl compounds in excellent yields with modest to excellent diastereoselectivity is reported. A plausible reaction mechanism is also proposed on the basis of previous literature and preliminary investigation the asymmetric version of the reaction.     

Determination of bulk viscosity of liquid water via pulse duration measurements in stimulated Brillouin scattering

We present a method by which to determine the bulk viscosity of water from pulse duration measurements of stimulated Brillouin scattering （SBS）. Beginning from a common model of Brillouin scattering, the bulk viscosity is shown to play an important role in Brillouin linewidth determination. Pulse durations of SBS back-reflected optical pulses are measured over the temperature range of 5-40℃. SBS linewidths are de- termined via Fourier transformation of the time-domain results, and the bulk viscosity of water is measured and derived from the obtained values. Our results show that the proposed method for measurement of pulse durations is an effective approach for determining bulk viscosity. The method can be easily extended to determine bulk viscosities of other Newtonian liquids.     

悬浮二维晶体材料反射光谱和光致发光光谱的周期性振荡现象

研究了在二氧化硅/硅衬底上制备的悬浮石墨烯以及二硫化钼的反射光谱以及悬浮二硫化钼的光致发光光谱.研究发现:悬浮多层石墨烯的反射光谱表现出明显的振荡现象,并且该振荡具有一定的周期性;振荡周期的大小不依赖于悬浮多层石墨烯的层数,而是随着衬底上沉孔深度(空气层厚度)的增加而减小.利用多重光学干涉模型可以解释这种振荡现象以及振荡周期随沉孔深度改变的变化趋势.该模型计算结果表明,只有当沉孔深度达到微米量级时这种振荡现象才会显著出现;并且可由振荡周期定量地确定出沉孔深度.对于悬浮的二硫化钼样品,其反射光谱和光致发光光谱也出现了类似的振荡现象.这表明这种振荡现象是在各种衬底上悬浮二维材料反射光谱和光致发光光谱的一种普遍性结果,也预示悬浮二维材料器件的电致发光光谱也会出现类似的振荡现象,对悬浮二维晶体材料的物理性质和器件性能研究具有一定的参考价值.