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81.
Eu3+掺杂铌酸盐玻璃的光谱性质 总被引:6,自引:1,他引:5
研究了Eu^3 掺杂铌磷与铌硅系列玻璃的发射光谱,声子边带谱及^5D0能级寿命,计算了样品的强度参数。随着Nb2O5浓度的增加,Eu-O键强增大,共价性增强,Eu^3 的局域环境对称性降低,电-声子耦合增强,^5D0能级的无辐射过程加快,寿命变短,温度猝灭加剧。研究了从77-690K铌磷与铌硅系列玻璃中Eu^3 离子在488nm激光激发下的变温荧光发射特性,求出了温度猝灭速率。分析了发光强度增强与减弱的原因,即热布居与无辐射过程随温度的变化关系,研究了谱线宽度与峰值位置随温度的变化关系。 相似文献
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84.
Yu-jie Zhang Hong-guo Zhang Hong-wei Zhang Jing-lan Chen Guang-heng Wu 《Journal of magnetism and magnetic materials》2010,322(15):2251-809
A series of rare-earth doped BiFeO3 samples, Bi1−xRxFeO3 (x=0-1, R=La, Nd, Sm, Eu and Tb), were prepared in this work. X-ray diffraction analysis showed that the structure of rare-earth doped BiFeO3 was transformed from rhombohedral lattice to orthorhombic one by increasing x. The lattice constants and unit-cell volume decreased with the increasing of the doping content, while both the Néel temperature and magnetization were enhanced. A magnetic phase transition was observed at about 35 K for BiFeO3. The variation of the magnetization with temperature depended on applied field strength and magnetizing history, which was explained according to the antiferromagnetic exchange interaction between Fe and R sites in Bi1−xRxFeO3(x>0). The magnetocrystalline anisotropy contributed by Fe sublattice gave rise to a large coercivity in BixNd1−xFeO3 with an orthorhombic structure. 相似文献
85.
Based on the isomorphism between the space of star-shaped sets and the space of continuous positively homogeneous real-valued functions, the star-shaped differential of a directionally differentiable function is defined. Formulas for star-shaped differential of a pointwise maximum and a pointwise minimum of a finite number of directionally differentiable functions, and a composite of two directionaUy differentiable functions are derived. Furthermore, the mean-value theorem for a directionaUy differentiable function is demonstrated. 相似文献
86.
针对当前自适应网站实现领域研究的不足,尤其是缺乏对网站自身拓扑结构的分析,站在用户的角度,结合Web日志挖掘和站点拓扑分析,提出地标系数这一指标来衡量网站结点的重要性.在此基础上,提出自适应网站的实现架构,并给出智能推荐(包括高亮显示和动态地图)和缓冲预取两种自适应策略.最后,对一个原型系统进行实验分析.结果表明,提出的自适应策略可提高网站访问者的访问效率. 相似文献
87.
考虑一类具有阶段结构和Holling-TannerⅡ类功能反应的Leslie周期系统,利用重合度理论得到该系统正周期解存在的充分条件. 相似文献
88.
ECR离子源的等离子体阻抗对其微波传输与阻抗匹配设计至关重要。在中国科学院近代物理研究所现有的2.45 GHz ECR 质子源上,对等离子体阻抗进行了测量。首先用水吸收负载代替等离子体负载测量得到了所用微波窗阻抗,然后根据质子源测量数据,推算得到了等离子体阻抗。实验结果表明,脊波导输出端阻抗与后续负载不完全匹配,等离子体阻抗随微波功率变化呈非线性。这些结果为ECR离子源过渡匹配和微波窗的设计提供了参考依据。Plasma impedance of an ECR ion source is important for microwave transmission and impedance matching design. Plasma impedance was measured indirectly with the 2.45 GHz ECR proton source at the Institute of Modern Physics, Chinese Academy of Sciences. In the test, we got microwave window mpedance by using water absorption load instead of plasma load, and the source plasma impedance was derived from the test data with the 2.45 GHz ECR proton source and microwave window impedance. The experimental results show that ridge waveguide output impedance and the subsequent load does not exactly match, plasma impedance variation is nonlinear with microwave power. The achievedresult is useful in the design of ridged waveguide and microwave window. 相似文献
89.
Utilizing the well-known aggregation technique, we propose a smoothing sample average approximation (SAA) method for a stochastic linear complementarity problem, where the underlying functions are represented by expectations of stochastic functions. The method is proved to be convergent and the preliminary numerical results are reported. 相似文献
90.
Wei-peng Li Yu-cheng Zhu Yan-jun Zhou Hong-wei Yang Cheng-jian Zhu 《Tetrahedron》2019,75(12):1647-1651
We developed a method to synthesize fluorinated 1,4-unsaturated dicarbonyl compounds via photoredox catalyzed radical addition process. Commercially available ethyl bromodifluoroacetate (BrCF2CO2Et) as fluoroalkyl source, the corresponding fluoro-containing dicarbonyl compounds could be obtained in moderate to good yields. 相似文献