Solvent effects on competitive intramolecular electron transfer and energy transfer in a covalently linked porphyrin-phthalocyanine heterodimer

Photophysical properties of a porphyrin-phthalocyanine heterodimer covalently linked with a dipentoxy chain have been studied.Absorption spectra show that there is weak exciton coupling between the two chromophores in the ground state.Fluorescence spectra show that intramolecular energy transfer from porphyrin to phthalocyanine moiety occurs in competition with electron transfer.The efficiency of these two processes depends upon the mutual orientation of the two chromophores.The effect of solvent polarity on the intramolecular processes is also discussed.     

碱处理浓度对预脱铝ZSM-5成孔过程及其MTG反应性能的影响

在80℃水浴条件下,对ZSM-5分子筛进行酸碱处理改性;重点考察了碱处理溶液浓度对酸预处理脱铝后ZSM-5分子筛微观结构及其催化甲醇制汽油(MTG)性能的影响。通过BET、XRD、FT-IR、NH₃-TPD和TEM等手段对样品进行表征。结果表明,单独酸处理没有改变分子筛孔结构,单独碱处理产生了并不明显的介孔。酸预处理后再碱处理可促进介孔的产生,产生更为显著的介孔结构;而且随着碱处理强度的增加,分子筛样品的介孔/微孔比表面积比例和孔体积均先增大后降低。酸浓度2mol·L^-1,碱浓度0.4mol·L^-1条件处理得到的分子筛,介孔比表面积比例和孔容均达到最大,酸量和酸强度最低。在400℃,0.1MPa,WHSV=2.1h^-1条件下,甲醇制汽油反应性能最佳:汽油收率由未改性时的30wt%提高到34wt%,寿命更是由16h延长到135h,芳烃含量由原来的73wt%降至20wt%。     

多孔硅镶嵌正丁胺/激光染料复合膜的荧光谱

The photoluminescence (PL) of the compound films made by implanting n-butylamine/ Rhodamine into the porous silicon films was studied. Comparison and discussion of the difference of PL of the compound films and the dyes were carried out. The PL of the compound films with different substrates was measured.     

Anion-Coordination-Assisted Assembly of Supramolecular Charge-Transfer Complexes Based on Tris(urea) Ligands

Charge-transfer (CT) complexes, formed by noncovalent bonding between electron-rich (donor, D) and electron-deficient (acceptor, A) molecules (or moieties) have attracted considerable attention due to their fascinating structures and potential applications. Herein, we demonstrate that anion coordination is a promising strategy to promote CT complex formation between anion-binding, electron-rich tris(urea) donor ligands (D) and electron-deficient viologen cation acceptors (A), which form co-crystals featuring infinite ⋅⋅⋅DADA⋅⋅⋅ or discrete (circular DADA or three-decker DAD) π-stacking interactions. These CT complexes were studied by X-ray diffraction, UV/Vis spectroscopy, electric conductivity measurements, charge displacement curve (CDC) calculations, and DFT computations.     

高CO耐性的金属间PtBi纳米片用于甲醇电氧化

我们通过热注入的方法制备了一种高CO耐性的金属间PtBi纳米片。所制备的金属间PtBi纳米片在甲醇氧化反应(MOR)中展现出优异的催化性能和良好的稳定性能,最大的质量活性高达4.09 A·mg_Pt^-1,接近商业Pt/C的3.2倍。计时电流-时间(I-t)稳定性测试之后,活性仅仅衰减5.7%,远低于商业Pt/C。CO吸附-脱附(CO-Stripping)曲线和循环伏安演变(CV-Evolution)曲线证实了金属间PtBi纳米片高的CO耐受性。     

Effect of intermediate principal stress on flat-ended punch problems

The intermediate principal stress has certain effects on the yield strength of metallic materials under complex stress states. The flat-ended punch problem is a classical and fundamental problem in plasticity theory and mechanical engineering in which the metal beneath a flat-ended punch is under complex stress states. Using the finite difference codes, fast Lagrangian analysis of continua and Unified Strength Theory, the effect of the intermediate principal stress on the flat-ended punch problem is analyzed in this paper. First, the limit pressures of strip and circular punches pressed into an elastoplastic and homogeneous metallic medium are calculated by the two-dimensional finite difference method. The problems of square and rectangular punches are analyzed by the three-dimensional finite difference method. Finally, the effect of the intermediate principal stress on flat-ended punch problems with different punch geometries is analyzed.     

Effects of a bar on optical transmission through Z-shaped metallic slit arrays

We investigate the effects of a bar on optical transmission through Z-shaped metallic slit arrays by using the finite-difference time domain (FDTD) method. A new hybrid Fabry-Perot (FP) surface plasmon polariton (SPP) mode emerges when changing the geometric parameters of the bar, and this mode can be viewed as a coupling between FP mode and SPP mode. In addition, an obvious dip appears in a featured area when the bar deviates from the central line, and a small displacement of the bar leads to tremendous change of the dip. These behaviors can be attributed to the phase resonance. In short, the structure is very sensitive to the metal bar. Furthermore, it combines photonic device miniaturization with sensitivity, which is useful for making optical switches.     

Group Connectivity of 3-Edge-Connected Chordal Graphs

Let A be a finite abelian group and G be a digraph. The boundary of a function f: E(G)ZA is a function ‘f: V(G)ZA given by ‘f(v)=~_{e leaving v}f(e)m~_{e entering v}f(e). The graph G is A-connected if for every b: V(G)ZA with ~_{v] V(G)} b(v)=0, there is a function f: E(G)ZA{0} such that ‘f=b. In [J. Combinatorial Theory, Ser. B 56 (1992) 165-182], Jaeger et al showed that every 3-edge-connected graph is A-connected, for every abelian group A with |A|̈́. It is conjectured that every 3-edge-connected graph is A-connected, for every abelian group A with |A|̓ and that every 5-edge-connected graph is A-connected, for every abelian group A with |A|́.¶ In this note, we investigate the group connectivity of 3-edge-connected chordal graphs and characterize 3-edge-connected chordal graphs that are A-connected for every finite abelian group A with |A|́.