氯代5-氟脲嘧啶卟啉的红外光谱特性的研究

本文对新合成的对位及间位两类氯代苯基 5 氟脲嘧啶卟啉的红外光谱吸收峰进行了归属和总结 ,讨论了其红外吸收频率随取代基位置变化的规律。指出了苯环上的取代基为电负性强的基团时 ,由于场效应的存在 ,使被测化合物的羰基伸缩振动吸收峰的相对强度发生改变。同时 ,表明了嘧啶环上N原子发生了取代 ,形成单、双取代 5 氟脲嘧啶卟啉化合物的红外光谱特性。     

技术不确定环境下新产品策略的设计应用

技术的动态发展和企业间的竞争对企业新产品策略有很大影响,直接决定新产品的引进周期。本文在产业技术动态变化的随机环境下构建随机动态规划模型,关注产业技术进步、投资成本和产品市场竞争等影响因素,探讨企业进行新产品引进的周期选择,对新产品引进的周期和质量决策进行方法设计和应用举例。利用随机动态规划模型得出新产品引进的最优时间周期,用算例分析技术进步和产品研发成本对企业引进周期策略的影响,采取策略迭代的方法进行求解,发现技术进步较快时企业的新产品引进步伐也较快,研发成本的提高使企业的新产品引入步伐降低。     

In situ observation of NaBi(WO4)2 dendrite growth and the study on microstructure of solidification

The dendrite growth process of transparent NaBi(WO₄)₂ with small prandtl and high melting point was studied by using the in-situ observation system. According to the dynamic images and detailed information, there are two kinds of restriction effect on the dendrite growth, the competition between arms and branches and the convection in the melt. The dendrite growth rate was time dependent, and the rate of arm growth reached the maximum 5.8 mm/s in the diffusive-advective region and rapidly decreased in the diffusive-convective region. The growth rate of branch had the same change trends as the arm’s. Based on the EPMA-EDS data of solidification structure of quenched NaBi(WO₄)₂ melt, it was found that there were component differences from stoichiometric concentration in the melt near the interface during the growth process. Supported by the National Natural Science Foundation of China (Grant No. 50331040) and the Innovation Funds from Shanghai Institute of Ceramics, Chinese Academy of Sciences (Grant No. SCX0623)     

GaAs1-xPx中混晶无序与Fe深中心的性质

对不同组分的掺FeⅢ-Ⅴ族混晶GaAs1-xPx,测量了Fe深受主中心空穴热发射的非指数恒温暗电容瞬态及DLTS谱。用混晶无序使Fe深能级展宽的模型理论拟合实验结果,得到Fe能级Gauss型展宽的半宽和中心能级的热发射率,并确定出基态空穴跃迁的中心能级的焓变与组分的关系:先是减少,而后增大,与由光电容方法得到的Gibbs自由能变量与组分x的关系明显不同。 进一步讨论表明,上述两种测量方法得到的Fe中心的激活能不同,可能反映Fe中心的键合状态和混晶无序诱导的品格弛豫的影响。     

单晶和多晶纯铝蠕变过程中的内耗

研究了单晶和多晶纯铝蠕变过程中的低频内耗. 在单晶纯铝中观察到: 内耗在蠕变初期单调下降, 在蠕变第一阶段后期出现了一个显著的时间内耗峰, 在蠕变第二阶段内耗趋于稳定值. 多晶纯铝在类似实验条件下则不出现时间内耗峰. 文中分析了出现时间内耗峰的条件和原因, 认为它是由于蠕变第一阶段中运动位错的阻尼系数逐渐增大所引起的. 文中还从蠕变过程中位错运动的微观机制出发, 推导出了蠕变过程中内耗的表达式, 满意地解释了实验结果. 关键词：     

一种基于粒子滤波的测向定位跟踪算法

基于多站测向定位提供的目标辐射源方位角信息,提出了一种基于粒子滤波的测向定位跟踪算法.该算法采用序贯蒙特卡罗的粒子滤波技术,对目标辐射源方位信息进行粒子滤波融合处理,实现了对机动目标辐射源的无源定位跟踪.仿真实验表明,该算法适用于非线性模型和非高斯噪声的目标跟踪,与传统的基于卡尔曼滤波的多传感器融合跟踪算法相比,定位跟踪更为精确,从而对提高战场电子目标定位跟踪和精确打击具有广泛的应用价值.     

On the Bounded Complex of an Affine Oriented Matroid

We prove that the bounded complex of an affine oriented matroid is pure and collapsible. We also generalize Zaslavsky's central decomposition theorem for hyperplane arrangements to affine oriented matroids.     

Bivariate Recursive Equations on Excess-of-loss Reinsurance

This paper investigates bivariate recursive equations on excess-of-loss reinsurance. For an insurance portfolio, under the assumptions that the individual claim severity distribution has bounded continuous density and the number of claims belongs to R1 （a, b） family, bivariate recursive equations for the joint distribution of the cedent＇s aggregate claims and the reinsurer＇s aggregate claims are obtained.