全文获取类型
收费全文 | 11874篇 |
免费 | 264篇 |
国内免费 | 50篇 |
专业分类
化学 | 6772篇 |
晶体学 | 99篇 |
力学 | 403篇 |
数学 | 2198篇 |
物理学 | 2716篇 |
出版年
2022年 | 130篇 |
2021年 | 193篇 |
2020年 | 184篇 |
2019年 | 197篇 |
2018年 | 198篇 |
2017年 | 176篇 |
2016年 | 289篇 |
2015年 | 236篇 |
2014年 | 263篇 |
2013年 | 692篇 |
2012年 | 481篇 |
2011年 | 579篇 |
2010年 | 400篇 |
2009年 | 345篇 |
2008年 | 498篇 |
2007年 | 434篇 |
2006年 | 398篇 |
2005年 | 368篇 |
2004年 | 379篇 |
2003年 | 316篇 |
2002年 | 302篇 |
2001年 | 202篇 |
2000年 | 187篇 |
1999年 | 152篇 |
1998年 | 124篇 |
1997年 | 140篇 |
1996年 | 169篇 |
1995年 | 130篇 |
1994年 | 141篇 |
1993年 | 163篇 |
1992年 | 164篇 |
1991年 | 170篇 |
1990年 | 125篇 |
1989年 | 128篇 |
1988年 | 140篇 |
1987年 | 188篇 |
1986年 | 157篇 |
1985年 | 207篇 |
1984年 | 188篇 |
1983年 | 146篇 |
1982年 | 178篇 |
1981年 | 184篇 |
1980年 | 179篇 |
1979年 | 173篇 |
1978年 | 171篇 |
1977年 | 167篇 |
1976年 | 150篇 |
1975年 | 161篇 |
1974年 | 132篇 |
1973年 | 132篇 |
排序方式: 共有10000条查询结果,搜索用时 125 毫秒
61.
Starting from the total Hamiltonian of an excited exciton–biexciton system, nonresonant renormalizations in the electronic spectrum of a coherently driven direct semiconductor are considered. Stringent group-theoretical inclusion of the particle spin in the Hamiltonian allows one to account for the dependence of different renormalization effects on polarizations of the incident laser fields. On the example of circularly polarized driving and probing pulses it is shown that the kind of observed renormalization is defined by the pump-and-probe polarization geometry. Thus, the exciton optical Stark effect must appear in the case of co-circular pump-and-probe, whereas a mixing of the polariton and biexciton spectra is possible only in the case of counter-circular pump-and-probe. The polariton--biexciton dispersion renormalization may manifest itself as synchronous splittings of the exciton--polariton and biexciton spectra under resonant pumping at a frequency of the polariton--biexciton transition, or in their shifts in opposite directions under near-resonant pumping. The mechanisms of both kinds of renormalization effects are analyzed, and the dependence of their characteristics on the pump parameters and microscopic parameters of the exciton–biexciton–photon system is established. An evaluation of the characteristics shows that the effect of polariton–biexciton dispersion renormalization dominates in the spectra of semiconductors with stable biexciton formation. Results of the theoretical study provide an adequate explanation of available experimental data. 相似文献
62.
Thi Thi Nge Naruhito Hori Akio Takemura Hirokuni Ono Tsunehisa Kimura 《Journal of Polymer Science.Polymer Physics》2003,41(7):711-714
A high magnetic field of 5 T was used to fabricate a magnetically aligned, optically anisotropic, liquid‐crystalline chitin/poly(acrylic acid) composite. The aligned mesophase was fixed by photoinitiated free‐radical polymerization. From an examination of polarized optical micrographs and an X‐ray diffraction study, a high degree of orientation of 0.70 was observed for the composite with a higher liquid‐crystalline chitin concentration (10.70 wt %); the orientation was reduced with a decreased chitin concentration at a given acrylic acid concentration. The X‐ray data for the developed composite showed a uniplanar orientation for the chitin crystallites, with its molecular long axes perpendicular to the direction of the magnetic field. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 711–714, 2003 相似文献
63.
S. V. Bobashev R. V. Vasil’eva A. V. Erofeev T. A. Lapushkina S. A. Poniaev D. M. Van Wie 《Technical Physics》2003,48(2):177-184
Effective ways for controlling shock wave configurations by means of external actions are sought. One such way is a local effect of electric and magnetic fields. In this paper, the local effect of external fields is implemented by current localization in a limited region of a diffuser. The experiment is carried out in a diffuser providing the complete internal compression of the gas with a Mach number at the inlet M=4.3. As a working medium, a xenon plasma is used. The plasma flow is formed in a shock tube equipped with an accelerating nozzle. Two ways of current localization are tested. In the first one, the diffuser inlet is a short channel of Faraday generator type. In this case, the ponderomotive force basically decelerates or accelerates the flow depending on the direction of the electric field. In the second way, the current flows through a narrow near-wall region between adjacent electrodes. In this case, the ponderomotive force compresses or expands the gas. In both cases, it is shown that the angle of an attached shock due to MHD interaction can be both decreased and increased. The central problem with the MHD control of shock waves is near-electrode and near-wall phenomena. 相似文献
64.
Jean Van Schaftingen 《Comptes Rendus Mathematique》2004,338(1):23-26
A simpler proof of a recent inequality of Bourgain, Brezis and Mironescu is given. To cite this article: J. Van Schaftingen, C. R. Acad. Sci. Paris, Ser. I 338 (2004). 相似文献
65.
Vitali Vogel Jean‐Franois Gohy Bas G. G. Lohmeijer Jacomina A. Van Den Broek Winfried Haase Ulrich S. Schubert Dieter Schubert 《Journal of polymer science. Part A, Polymer chemistry》2003,41(20):3159-3168
In aqueous solutions, amphiphilic block copolymers in which a polystyrene (PS) segment is connected to a poly(ethylene oxide) (PEO) block via a bis(2,2′:6′,2″‐ terpyridine ruthenium) complex can form micelles. Such micelles of the protomer type PS20‐[Ru]‐PEO70, according to the preparation procedure representing frozen micelles, were studied by sedimentation velocity and sedimentation equilibrium analysis in an analytical ultracentrifuge and by transmission electron microscopy, with different techniques applied for the sample preparation. The particles obtained were surprisingly multifarious in size. In ultracentrifugation experiments performed at relatively low salt concentrations, the distributions of the sedimentation coefficient s20,w showed a pronounced peak at 9.6 S and a broad, only partly separated second peak around 14 S. The molar mass of the particles at the peak was around 430,000 g/mol, corresponding to an aggregation number of approximately 85. The average hydrodynamic diameter of the particles in the peak fraction was approximately 13 nm. In electron micrographs of negatively stained samples, spheres of diameters between 10 and 25 nm were the most abundant particles, but larger ones with a wide size range were also visible. The latter particles apparently were composed of smaller ones. The data from both sedimentation analysis and electron microscopy showed that (1) the studied compound formed primary micelles of diameters around 20 nm and (2) the primary micelles had a tendency toward aggregation. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3159–3168, 2003 相似文献
66.
In this paper we provide an error bound estimate and an implicit multifunction theorem in terms of smooth subdifferentials and abstract subdifferentials. Then, we derive a subdifferential calculus and Fritz–John type necessary optimality conditions for constrained minimization problems. 相似文献
67.
68.
E. A. Klop B. J. Lommerts J. Veurink J. Aerts R. R. Van Puijenbroek 《Journal of Polymer Science.Polymer Physics》1995,33(2):315-326
Differential scanning calorimetry and high temperature x-ray diffraction were used to study the perfectly alternating copolymer of ethene and carbon monoxide (polyketone; POKC2). It was found that oriented POK-C2 fibers show a crystalline phase transition at a temperature between 110–125°C with a 10% change in crystalline density. At this temperature, the crystal structure reported recently (POK-α) is transformed to a crystal structure that was reported in the past for room temperature imperfectly alternating polyketone. The latter structure will be designated as POK-β. The influence of chain defects on the crystal structure was studied by synthesizing terpolymers (POK-C2/C3), in which small amounts of propylene-CO units are incorporated into the polymer backbone. The resulting terpolymers differ from the copolymer by the presence of methyl groups randomly distributed along the polyketone backbone chain. Evidence is presented that indicates that the methyl groups are built into the crystal lattice as defects. With more than 5 mole-% propene the terpolymer fibers crystallize exclusively in the β-modification. Below this level the α/β ratio (at room temperature) increases with decreasing amounts of propene. Both as-synthesized and as-spun POK-C2 were found to consist of both POK-α and POK-β; the α/β ratio depends on the method of preparation. Because the drawn POK-C2 fibers studied here consist exclusively of POK-α, the process of spinning and drawing leads to the transformation of unoriented β-rich material into oriented POK-α. © 1995 John Wiley & Sons, Inc. 相似文献
69.
W.-H. Steeb M. A. Van Wyk R. Stoop 《International Journal of Theoretical Physics》1998,37(10):2653-2655
We describe a one-dimensional chaotic map wherethe Liapunov exponent is a smooth function of a controlparameter. 相似文献
70.