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991.
Y. Ohtsu O. Shirota T. Ogawa I. Tanaka T. Ohta O. Nakata Y. Fujiyama 《Chromatographia》1987,24(1):351-356
Summary A new type of column packing material designed for preparative liquid chromatography, silicone polymer-coated silica gel modified
with octadecyl group (S/S-C18), was applied to chromatographic purification of a lipophilic biotechnological product. Triglycerides containing γ-linolenic
acid were separated from the curde oil that consisted of triglycerides, diglycerides, free fatty acids, sterols and other
polar substances, using a S/S-C18 packed column (150 mm I.D. × 1000 mm). No column deterioration was observed after more than 1500 times of sample introductions. 相似文献
992.
Interface equations are derived for both binary diffusive and binary fluid systems subjected to nonequilibrium conditions,
starting from coarse-grained (mesoscopic) models. The equations are used to describe thermocapillary motion of a droplet in
both purely diffusive and fluid cases, and the results are compared with numerical simulations. A mesoscopic chemical potential
shift owing to the temperature gradient, and associated mesoscopic corrections involved in droplet motion, are elucidated. 相似文献
993.
994.
Kyozo Kanamoto Sheng Lan Naoki Ikeda Yoshimasa Sugimoto Kiyoshi Asakawa Hiroshi Ishikawa 《光学学报》2003,23(Z1)
Single photonic crystal defects based on an air-bridge structure were fabricated. We obtained sharp defect modes with quality factors higher than 600 and observed their response to ultrashort optical pulses by utilizing two-photon absorption. 相似文献
995.
Hideki Matsubara Shun-Ichiro Hata Yosuke Kondo Yasuyuki Ishida Hiroshi Takigawa Hajime Ohtani 《Analytical sciences》2006,22(11):1403-1407
The cross-linking structure of the ultra violet (UV)-cured resin prepared from dipentaerithritol hexacrylate (DPHA) was characterized by matrix-assisted laser desorption/ionization mass spectrometry (MALDI-MS) combined with supercritical methanolysis. The MALDI-mass spectrum of the decomposition products obtained by supercritical methanolysis contained a series of peaks of sodium-cationized methyl acrylate (MA) oligomers up to around m/z = 4000 formed through selective cleavage and methylation occurred at ester linkages in UV-cured DPHA. Furthermore, in order to observe widely distributed sequence lengths in the cross-linking junctions, the decomposed products of the cured resin were then fractionated using size exclusion chromatography followed by the MALDI-MS measurements of the individual fractions. The MALDI-mass spectra of the lower molar mass fractions mainly consisted of a series of peaks of MA oligomers around m/z values of several thousands, whereas those of higher molecular weight showed a broad peak up to m/z ca. 180000. The observed distributions of the supercritical methanolysis products suggested that the network junctions in the given UV-cured resin were composed of up to around 2000 acrylate units. 相似文献
996.
Hiroshi Sasaki Atsushi Nakagawa Tomonari Muramatsu Megumi Suganuma Yoriko Sawano Masaki Kojima Keiko Kubota Kenji Takahashi Masaru Tanokura 《Proceedings of the Japan Academy. Series B, Physical and biological sciences》2004,80(9):435
Aspergilloglutamic peptidase from Aspergillus niger is a novel pepstatin-insensitive acid endopeptidase distinct from the well-studied aspartic peptidases, and thus is an interesting target for protein structure/function studies. In the present study, we have determined the three-dimensional structure of the enzyme by X-ray crystallography to a 1.4-Å resolution. The results revealed that the enzyme has a unique structure, composed of two seven-stranded anti-parallel β-sheets which form a β-sandwich structure and appear to have a partial two-fold symmetry, suggesting its possible evolution by gene duplication and that the glutamic acid-110 and glutamine-24 in the heavy chain form a catalytic dyad, consistent with our results obtained by site-directed mutagenesis. 相似文献
997.
Ken Hosoya Hiroshi Aoki Takuya Kubo Masashi Teramachi Nobuo Tanaka Jun Haginaka 《Journal of polymer science. Part A, Polymer chemistry》2005,43(12):2556-2566
Highly crosslinked polymer networks were characterized in terms of structural differences based on the crosslinked network structures with their chromatographic molecular retentivity for some polyaromatic hydrocarbons (PAHs). Because PAHs and some sterically bulky solutes were used in the chromatographic characterization, tiny differences in the crosslinked polymer networks were observed in terms of the chromatographic molecular retentivity. Ethylene dimethacrylate afforded molecular retentivity for anthracene, and this recognition ability changed with the polymerization time. In addition, 1,4‐butanediol dimethacrylate afforded molecular retentivity for pyrene, and this retentivity was larger than that for anthracene. The polymerization methods also affected the resulting polymer networks drastically. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 2556–2566, 2005 相似文献
998.
Preparation of Cu2ZnSnS4 thin films by hybrid sputtering 总被引:2,自引:0,他引:2
Tooru Tanaka Takeshi Nagatomo Mitsuhiro Nishio Akihiro Wakahara Hiroshi Ogawa 《Journal of Physics and Chemistry of Solids》2005,66(11):1978-1981
In order to fabricate Cu2ZnSnS4 thin films, hybrid sputtering system with two sputter sources and two effusion cells is used. The Cu2ZnSnS4 films are fabricated by the sequential deposition of metal elements and annealing in S flux, varying the substrate temperature. The Cu2ZnSnS4 films with stoichiometric composition are obtained at the substrate temperature up to 400 °C, whereas the film composition becomes quite Zn-pool at the substrate temperature above 450 °C. The Cu2ZnSnS4 film shows p-type conductivity, and the optical absorption coefficient and the band gap of the Cu2ZnSnS4 film prepared in this experiment are suitable for fabricating a thin film solar cell. 相似文献
999.
Portfolio optimization under D.C. transaction costs and minimal transaction unit constraints 总被引:1,自引:0,他引:1
This paper addresses itself to a portfolio optimization problem under nonconvex transaction costs and minimal transaction unit constraints. Associated with portfolio construction is a fee for purchasing assets. Unit transaction fee is larger when the amount of transaction is smaller. Hence the transaction cost is usually a concave function up to certain point. When the amount of transaction increases, the unit price of assets increases due to illiquidity/market impact effects. Hence the transaction cost becomes convex beyond certain bound. Therefore, the net expected return becomes a general d.c. function (difference of two convex functions). We will propose a branch-and-bound algorithm for the resulting d.c. maximization problem subject to a constraint on the level of risk measured in terms of the absolute deviation of the rate of return of a portfolio. Also, we will show that the minimal transaction unit constraints can be incorporated without excessively increasing the amount of computation. 相似文献
1000.
Dependence of Stokes dynamics in stimulated Brillouin scattering generated in optical fibers on the pump power, the nonlinear refractive index, the fiber length, and the feedback powers of the pump and the Stokes is numerically analyzed. The Stokes power fluctuation becomes complicated and chaotic as the nonlinear refractive index and the input pump power increase in a fiber of sufficient length. The Stokes dynamics is less complicated and the chaotic region decreases in a pump power-reflectivity domain in a short fiber. The chaotic behavior appears without regular tendency in relation to the feedback power. Taking into account the pump feedback, the chaotic region expands and some Stokes behaviors are different in the PP-R domain graph, compared with the case with the Stokes feedback alone, although this feedback does play an essential role in Stokes dynamics. 相似文献