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71.
Hiroshi Aoki Ken Hosoya Tomohisa Norisuye Nobuo Tanaka Daisuke Tokuda Norio Ishizuka Kazuki Nakanishi 《Journal of polymer science. Part A, Polymer chemistry》2006,44(2):949-958
An investigation was made of the gelation of dimethacrylate‐type crosslinking agents in view of an application for separation media. The study mainly centered on a crosslinking agent, glycerol dimethacrylate (GDMA), which is relatively hydrophilic because of a hydroxyl group in the middle of its structure. The gelation of GDMA was compared with that of other hydrophobic crosslinking agents such as ethylene glycol dimethacrylate and 1,6‐hexanediol dimethacrylate. The diluents used in the study were toluene, toluene with methanol, and cyclohexanol. The gelation was observed in real time with a charge coupled device camera and dynamic light scattering (DLS). Also, the separated dry gels were extensively characterized with scanning electron microscopy, BET (N2 absorption and desorption isotherm), and Fourier transform infrared. DLS analysis showed a stronger molecular interaction of GDMA gelation in toluene, whereas this interaction was much weaker in an alcoholic solvent such as toluene with methanol or cyclohexanol. This indicated that GDMA gelation might proceed through hydrogen bonding as well as a crosslinking reaction of vinyl groups. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 949–958, 2006 相似文献
72.
Mana Ito Takashi Ishizone 《Journal of polymer science. Part A, Polymer chemistry》2006,44(16):4832-4845
Anionic polymerization of N‐methoxymethyl‐N‐isopropylacrylamide ( 1 ) was carried out with 1,1‐diphenyl‐3‐methylpentyllithium and diphenylmethyllithium, ‐potassium, and ‐cesium in THF at ?78 °C for 2 h in the presence of Et2Zn. The poly( 1 )s were quantitatively obtained and possessed the predicted molecular weights based on the feed molar ratios between monomer to initiators and narrow molecular weight distributions (Mw/Mn = 1.1). The living character of propagating carbanion of poly( 1 ) either at 0 or ?78 °C was confirmed by the quantitative efficiency of the sequential block copolymerization using N,N‐diethylacrylamide as a second monomer. The methoxymethyl group of the resulting poly( 1 ) was completely removed to give a well‐defined poly(N‐isopropylacrylamide), poly(NIPAM), via the acidic hydrolysis. The racemo diad contents in the poly(NIPAM)s could be widely changed from 15 to 83% by choosing the initiator systems for 1 . The poly(NIPAM)s obtained with Li+/Et2Zn initiator system possessed syndiotactic‐rich configurations (r = 75–83%), while either atactic (r = 50%) or isotactic poly(NIPAM) (r = 15–22%) was generated with K+/Et2Zn or Li+/LiCl initiator system, respectively. Atactic and syndiotactic poly(NIPAM)s (42 < r < 83%) were water‐soluble, whereas isotactic‐rich one (r < 31%) was insoluble in water. The cloud points of the aqueous solution of poly(NIPAM)s increased from 32 to 37 °C with the r‐contents. These indicated the significant effect of stereoregularity of the poly(NIPAM) on the water‐solubility and the cloud point in water © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 4832–4845, 2006 相似文献
73.
Kazuhiko Hashimoto Hiroshi Saito Ryo Ohsawa 《Journal of polymer science. Part A, Polymer chemistry》2006,44(16):4895-4903
Two kinds of new glycopolymers, (P(VB‐1‐GlcaH‐co‐AAm), 9 ) and (P(VB‐1‐Glco‐co‐AAm), 10 ), were synthesized through the radical copolymerization of styrene derivatives bearing pendant D ‐glucaric and D ‐gluconic moieties, N‐(p‐vinylbenzyl)‐1‐D ‐glucaramide (VB‐1‐GlcaH, 7 ), and N‐(p‐vinylbenzyl)‐D ‐gluconamide (VB‐1‐Glco, 8 ), with acrylamide (AAm). Glycopolymer 9 bearing the pendant glucaric moiety at the first position inhibited the hydrolysis of a model compound for xenobiotics‐β‐glucuronide conjugates, p‐nitrophenyl β‐D ‐glucuronide, uncompetitively, in contrast to the competitive inhibition in the presence of the corresponding isomeric glycopolymer bearing the pendant D ‐glucaric unit at the sixth position (P(VB‐6‐GlcaH‐co‐AAm), 3 ) reported in our previous article. On the other hand, another copolymer 10 bearing the gluconic moiety was found not to inhibit the hydrolysis as well as the corresponding copolymer bearing pendant gulonic unit (P(VB‐6‐Glco‐co‐AAm), 4 ). These results indicate that the hydrolysis is influenced not only by existence of pendant carboxyl units but also by the direction on the linkage of the glyco‐units to the polymer frame. Therefore the configurational position of hydroxy groups in pendant glyco‐units in macromolecular inhibitors may be essential for the interaction with β‐glucuronidase. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 4895–4903, 2006 相似文献
74.
Masahiro Nakao Chikako Yamazaki Hiroshi Tominaga Takako Yamaguchi Yoshikazu Fujita 《Analytical sciences》2006,22(2):313-316
A simple and highly sensitive spectrophotometric method for the determination of anthracycline anticancer agents, such as Daunorubicin hydrochloride (DAU), was established by using aluminum(III) and Chromazurol S (CAS) in a nonionic surfactant micellar medium. In the case of determination of DAU, the apparent molar absorptivity was 1.3 x 10(5) dm3 mol(-1) cm(-1) at 615 nm. Beer's law was obeyed in the concentration range of 0.028 - 2.82 microg ml(-1) for DAU. Owing to no need for solvent extraction, this method could be applied to assays of DAU and related drugs in pharmaceutical preparations. 相似文献
75.
Following a previous systematic theoretical study of the ground-state properties of over 7000 nuclei from the proton drip line to the neutron drip line in the relativistic mean field model [Prog. Theor. Phys. 113 (2005) 785], which is in fair agreement with existing experimental data, we observe a few spurious shell closures, i.e. proton shell closures at Z = 58 and Z = 92. These spurious shell closures are found to persist in all the effective forces of the relativistic mean field model, e.g. TMA, NL3, PKDD and DD-ME2. 相似文献
76.
77.
Atiya MS Chiang I Frank JS Haggerty JS Ito MM Kycia TF Li KK Littenberg LS Stevens A Strand RC Louis WC Akerib DS Marlow DR Meyers PD Selen MA Shoemaker FC Smith AJ Azuelos G Blackmore EW Bryman DA Felawka L Kitching P Kuno Y Macdonald JA Numao T Padley P Poutissou J Poutissou R Roy J 《Physical review letters》1990,65(1):21-24
78.
It is proved that if a graphG has maximum degreed, then its vertices can be represented by distinct unit vectors inR
2d so that two vectors are orthogonal if and only if the corresponding vertices are adjacent. As a corollary it follows that if a graph has maximum degreed, then it is isomorphic to a unit distance graph inR
2d. 相似文献
79.
Hiroshi Maehara 《Annals of the Institute of Statistical Mathematics》1988,40(4):665-670
Consider a unit sphere on which are placed N random spherical caps of area 4p(N). We prove that if % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGGipm0dc9vqaqpepu0xbbG8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaWaa0aaaeaaca% qGSbGaaeyAaiaab2gaaaWaaeWaaeaacaWGWbWaaeWaaeaacaWGobaa% caGLOaGaayzkaaGaai4Taiaad6eacaGGVaGaaeiBaiaab+gacaqGNb% Gaaeiiaiaad6eaaiaawIcacaGLPaaacqGH8aapcaaIXaaaaa!454E!\[\overline {{\rm{lim}}} \left( {p\left( N \right)\cdotN/{\rm{log }}N} \right) < 1\], then the probability that the sphere is completely covered by N caps tends to 0 as N , and if % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGGipm0dc9vqaqpepu0xbbG8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaWaaWaaaeaaca% qGSbGaaeyAaiaab2gaaaWaaeWaaeaacaWGWbWaaeWaaeaacaWGobaa% caGLOaGaayzkaaGaai4Taiaad6eacaGGVaGaaeiBaiaab+gacaqGNb% Gaaeiiaiaad6eaaiaawIcacaGLPaaacqGH+aGpcaaIXaaaaa!4551!\[\underline {{\rm{lim}}} \left( {p\left( N \right)\cdotN/{\rm{log }}N} \right) > 1\], then for any integer n>0 the probability that each point of the sphere is covered more than n times tends to 1 as N . 相似文献
80.
Hiroshi Konno 《Mathematical Programming》1988,41(1-3):185-193
We will consider a concave minimization problem associated with a series production system in which raw material is processed inm consecutive facilities. The products at some facility are either sent to the next facility or stocked in the warehouse. The amount of demand for the final products during periodi, i = 1,,n, are known in advance. Our problem is to minimize the sum of processing, holding and backlogging cost, all of which are assumed to be concave.The origin of this model is the classical economic lot size problem of Wagner and Whitin and was extensively studied by Zangwill. This model is very important from the theoretical as well as practical point of view and this is one of the very rare instances in which polynomial time algorithm has been constructed for concave minimization problems.The purpose of this paper is to extend the model further to the situation in which time lag is associated with processing at each facility. We will propose an efficient O(n
4
m) algorithm for this class of problems. 相似文献