Ueber den kolloiden Zustand der radioaktiven Stoffe

Ohne Zusammenfassung Vorgelegt der Warschauer Gesellschaft der Wissenschaften am 1. Dezember 1916.     

Ueber die Adsorption der Neutralsalze

Ohne Zusammenfassung     

Structure of bis(2-acetyloximephenolato) nitrosylcobalt,a nitrosyl containing a bent Co-N-O group

The crystal and molecular structure of [Co(NO)(ketox)₂], where ketoxH is 2-hydroxyacetophenoneoxime, have been determined. This nitrosyl crystallizes in the orthorhombic system,a=14.741,b=6.853,c=32.442 A,Z=8, space groupPbca. The structure was determined by the heavy-atom method, using Mokα diffractometer data, and refined by full-matrix least squares toR=0.041 for 1768 observed reflections. The molecule excluding the nitrosyl group is approximately planar. The cobalt atom is 5-coordinate in an essentially square pyramidal arrangment with the basal plane defined bytrans bidentate oximato ligands between which are strong hydrogen bonds. The nitrosyl group occupies the apical position and the Co-N-O angle is 126.3°.     

X-ray photoelectron spectroscopic studies of electrode surfaces using a new controlled transfer technique: Part I. Description of apparatus and preliminary studies

The design and use of an apparatus suitable for the controlled transfer of an electrode from an electrolyte solution to a high vacuum spectrometer chamber is described. Preliminary experiments with a nickel electrode illustrate the ability to transfer a non-noble metal without oxidation of the surface. Polarisation of a stainless steel electrode at progressively more cathodic potentials shows the gradual reduction of the oxide film present on the ‘as received’ material.