A contribution to the ternary phase diagram Co-Sb-Te

The melting behaviour, some phase boundaries and the lattice parameters in the region of the NiAs-type phase in the ternary system cobalt-antimony-tellurium have been determined by differential thermal analysis and X-ray diffraction. A projection of the liquidus surface and the phase relationships in different sections with constant antimony/tellurium ratios are presented. The peculiar variation of the lattice parameters with the composition of the nonstoichiometric NiAs-type phase is discussed in terms of the defect structure.Dedicated to Prof. K. L. Komarek on the occasion of his 65th birthday     

Asymmetric synthesis of 6-(2′,3′,4′,5′,6′-pentafluorophenyl)-δ-lactones via “allyl”boranes: application for the synthesis of fluorinated analog of key pharmacophore of statin drugs

Asymmetric “allyl”boration of pentafluorobenzaldehyde with various α-pinene based “allyl”boranes provides homoallylic alcohols in high de and ee; the alcohols have been converted into δ-lactones via acryloylation, ring-closing metathesis and hydrogenation. Pentafluorophenyl analog of key pharmacophore of statin drugs has been synthesized using diastereoselective epoxidation and regioselective reduction as key steps.     

Rückbezüge des Mathematikunterrichts und der Methodik des Mathematikunterrichts in der DDR auf historische Vorausentwicklungen

The author discusses at some examples exemplarily, how the pedagogy of mathematics education in the GDR from curricular and educational/psychological knowledge from the time before 1945 has developed scientifically.     

Atomic coherence effects in the ion-trap laser

The influence of atomic coherence effects on the statistical and spectral properties of the ion-trap laser is investigated. Various pump configurations are considered for a realistic level scheme using a Ca ion. Compared to previous suggestions, 50% more output is obtained.     

The complexity of many cells in arrangements of planes and related problems

We consider several problems involving points and planes in three dimensions. Our main results are: (i) The maximum number of faces boundingm distinct cells in an arrangement ofn planes isO(m ^2/3 n logn +n ²); we can calculatem such cells specified by a point in each, in worst-case timeO(m ^2/3 n log³ n+n ² logn). (ii) The maximum number of incidences betweenn planes andm vertices of their arrangement isO(m ^2/3 n logn+n ²), but this number is onlyO(m ^3/5– n ^4/5+2 +m+n logm), for any>0, for any collection of points no three of which are collinear. (iii) For an arbitrary collection ofm points, we can calculate the number of incidences between them andn planes by a randomized algorithm whose expected time complexity isO((m ^3/4– n ^3/4+3 +m) log² n+n logn logm) for any>0. (iv) Givenm points andn planes, we can find the plane lying immediately below each point in randomized expected timeO([m ^3/4– n ^3/4+3 +m] log² n+n logn logm) for any>0. (v) The maximum number of facets (i.e., (d–1)-dimensional faces) boundingm distinct cells in an arrangement ofn hyperplanes ind dimensions,d>3, isO(m ^2/3 n ^d/3 logn+n ^d–1). This is also an upper bound for the number of incidences betweenn hyperplanes ind dimensions andm vertices of their arrangement. The combinatorial bounds in (i) and (v) and the general bound in (ii) are almost tight.Work on this paper by the first author has been supported by Amoco Fnd. Fac. Dev. Comput. Sci. 1-6-44862 and by NSF Grant CCR-8714565. Work by the third author has been supported by Office of Naval Research Grant N00014-87-K-0129, by National Science Foundation Grant DCR-82-20085, by grants from the Digital Equipment Corporation, and the IBM Corporation, and by a research grant from the NCRD—the Israeli National Council for Research and Development. An abstract of this paper has appeared in theProceedings of the 13th International Mathematical Programming Symposium, Tokyo, 1988, p. 147.