全文获取类型
收费全文 | 3948篇 |
免费 | 87篇 |
国内免费 | 32篇 |
专业分类
化学 | 2580篇 |
晶体学 | 31篇 |
力学 | 115篇 |
数学 | 662篇 |
物理学 | 679篇 |
出版年
2021年 | 37篇 |
2020年 | 43篇 |
2019年 | 37篇 |
2018年 | 30篇 |
2017年 | 25篇 |
2016年 | 56篇 |
2015年 | 62篇 |
2014年 | 63篇 |
2013年 | 190篇 |
2012年 | 179篇 |
2011年 | 192篇 |
2010年 | 112篇 |
2009年 | 96篇 |
2008年 | 201篇 |
2007年 | 181篇 |
2006年 | 218篇 |
2005年 | 191篇 |
2004年 | 154篇 |
2003年 | 126篇 |
2002年 | 148篇 |
2001年 | 60篇 |
2000年 | 41篇 |
1999年 | 57篇 |
1998年 | 63篇 |
1997年 | 55篇 |
1996年 | 48篇 |
1995年 | 42篇 |
1994年 | 51篇 |
1993年 | 56篇 |
1992年 | 40篇 |
1991年 | 45篇 |
1990年 | 46篇 |
1989年 | 39篇 |
1988年 | 38篇 |
1987年 | 32篇 |
1986年 | 34篇 |
1985年 | 56篇 |
1984年 | 69篇 |
1983年 | 58篇 |
1982年 | 60篇 |
1981年 | 72篇 |
1980年 | 47篇 |
1979年 | 37篇 |
1978年 | 58篇 |
1977年 | 52篇 |
1976年 | 62篇 |
1975年 | 50篇 |
1974年 | 52篇 |
1973年 | 39篇 |
1972年 | 23篇 |
排序方式: 共有4067条查询结果,搜索用时 754 毫秒
961.
Jeffrey M. McMahon Anne-Isabelle Henry Kristin L. Wustholz Michael J. Natan R. Griffith Freeman Richard P. Van Duyne George C. Schatz 《Analytical and bioanalytical chemistry》2009,394(7):1819-1825
Finite element method calculations were carried out to determine extinction spectra and the electromagnetic (EM) contributions
to surface-enhanced Raman spectroscopy (SERS) for 90-nm Au nanoparticle dimers modeled after experimental nanotags. The calculations
revealed that the EM properties depend significantly on the junction region, specifically the distance between the nanoparticles
for spacings of less than 1 nm. For extinction spectra, spacings below 1 nm lead to maxima that are strongly red-shifted from
the 600-nm plasmon maximum associated with an isolated nanoparticle. This result agrees qualitatively well with experimental
transmission electron microscopy images and localized surface plasmon resonance spectra that are also presented. The calculations
further revealed that spacings below 0.5 nm, and especially a slight fusing of the nanoparticles to give tiny crevices, leads
to EM enhancements of 1010 or greater. Assuming a uniform coating of SERS molecules around both nanoparticles, we determined that regardless of the
separation, the highest EM fields always dominate the SERS signal. In addition, we determined that for small separations less
than 3% of the molecules always contribute to greater than 90% of the signal.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
962.
Henry Towsner 《Annals of Pure and Applied Logic》2009,157(2-3):269-280
963.
Gevrenova R Voutquenne-Nazabadioko L Harakat D Prost E Henry M 《Magnetic resonance in chemistry : MRC》2006,44(7):686-691
The assignments of 1H and 13C NMR spectra of two new aminoacyl triterpene saponins from roots of Gypsophila trichotoma Wend. are reported. In addition to 1D NMR methods, 2D NMR techniques (COSY, TOCSY, ROESY, HSQC, HMBC, and HSQC-TOCSY) were used for the assignments. The structures were completed by analysis of HR-ESI-MS and ESI-MS(n). 相似文献
964.
Nozière B Voisin D Longfellow CA Friedli H Henry BE Hanson DR 《The journal of physical chemistry. A》2006,110(7):2387-2395
To investigate the link between molecular structure, reactivity, and partitioning of oxygenated organic compounds in acidic aerosols, the uptake of three compounds found in the atmosphere, methyl vinyl ketone (MVK), methacrolein (MACR), and 2-methyl-3-butene-2-ol (MBO), by sulfuric acid solutions has been measured using a rotated wetted-wall reactor (RWW) coupled to a chemical ionization mass spectrometer (CIMS). MVK was found to partition reversibly into 20-75 wt % H(2)SO(4) solutions, and we report Henry's law coefficients between 20 and 7000 M atm(-1) over this range. A chemical reaction for MVK was likely responsible for the uptake observed for 80-96 wt % H(2)SO(4) solutions. We derive an upper limit to the aldol self-reaction rate coefficient for MVK in 80 wt % solution of approximately 3 M(-1) s(-1). MACR partitioned reversibly over most of the acidity range, and in contrast to that for MVK, the Henry's law coefficient was relatively independent of H(2)SO(4) content. These differences indicate that the increase of the coefficient with acidity is likely due to the ability of the carbonyl molecule to form an enol. These results indicate that aldol condensation can be facile in concentrated sulfuric acid solutions, but it should be negligibly slow in dilute acid solutions such as tropospheric aerosols. MBO uptake could be explained by a Henry's law coefficient that decreases slightly as acid content varies from 20 to 55 wt % H(2)SO(4); we also measured the value in water, 70 M atm(-1) at 298 K. A steady-state uptake of MBO was observed onto 40-80 wt % H(2)SO(4) solutions, a reaction product was observed, and the reaction was tentatively identified as Pinacol rearrangement. Similar rearrangements could be at the origin of some substituted oxygenated species found in atmospheric aerosols. 相似文献
965.
The requirements necessary to extend an ECP basis set for the calculation of electric and linear optical properties to the transition metals are studied. Previously an augmentation of the SBK basis set for 39 elements with s and p electron only valences (H-Rn, excluding Ga, In, and Tl) [J. Comput. Chem., 2005, 26, 1464-1471] was presented. In this work, electric dipole moments, polarizabilities, and anisotropies of selected metal hydrides, sulfides, and bromides, cisplatin, and the Fe, Ru, and Os metallocene derivatives along with many other systems are calculated and discussed. ECP calculations of molecules containing 3d and 4d metal centers among main group atoms have good agreement, often within 1-2% of the all-electron result at the time-dependent Hartree-Fock (TDHF)/Sadlej level of theory. Molecules with a 5d metal center have a large difference from and are more accurate than the all-electron results due to the inclusion of relativistic effects in the ECPs. The polarizability as calculated with and without ECPs of metallic clusters and surfaces is increasingly different as atomic number increases, again due to a lack of relativistic effects in the all-electron calculations. The augmented ECP calculations are consistent with relativistic all-electron results, while the Sadlej calculations are consistent with other nonrelativistic results. Both relativistic and basis set effects are less noticeable when the metal is in a formally positive state. 相似文献
966.
Schinzel S Bindl M Visseaux M Chermette H 《The journal of physical chemistry. A》2006,110(39):11324-11331
Density functional theory calculations were used to study a given complex for the whole series of lanthanide cations: [Ln(C3H5)Cp(OMe)] (1) [Ln = La (Z = 57)-Lu (Z = 71)], the radioactive lanthanide promethium (Z = 61) excepted. Contrary to the common assumptions, the calculations suggested a significant, albeit indirect, contribution of f electrons to bonding. Relativistic effects were considered in the calculations of the bonding energies, as well as in geometry optimizations in both spin-restricted and unrestricted formalisms. The unrestricted orbitals were finally used for the analysis of the charges and the composition of the frontier orbitals. It was confirmed that the ionic character was more pronounced for complexes of the late lanthanides. 相似文献
967.
Khalil M Marcus MA Smeigh AL McCusker JK Chong HH Schoenlein RW 《The journal of physical chemistry. A》2006,110(1):38-44
In this study, we perform steady-state and time-resolved X-ray absorption spectroscopy (XAS) on the iron K-edge of [Fe(tren(py)3)](PF6)2 dissolved in acetonitrile solution. Static XAS measurements on the low-spin parent compound and its high-spin analogue, [Fe(tren(6-Me-py)3)](PF6)2, reveal distinct spectroscopic signatures for the two spin states in the X-ray absorption near-edge structure (XANES) and in the X-ray absorption fine structure (EXAFS). For the time-resolved studies, 100 fs, 400 nm pump pulses initiate a charge-transfer transition in the low-spin complex. The subsequent electronic and geometric changes associated with the formation of the high-spin excited state are probed with 70 ps, 7.1 keV, tunable X-ray pulses derived from the Advanced Light Source (ALS). Modeling of the transient XAS data reveals that the average iron-nitrogen (Fe-N) bond is lengthened by 0.21+/-0.03 A in the high-spin excited state relative to the ground state within 70 ps. This structural modification causes a change in the metal-ligand interactions as reflected by the altered density of states of the unoccupied metal orbitals. Our results constitute the first direct measurements of the dynamic atomic and electronic structural rearrangements occurring during a photoinduced FeII spin crossover reaction in solution via picosecond X-ray absorption spectroscopy. 相似文献
968.
Hybrid density functional calculations with effective core potential basis sets are performed for monomeric group 13/15 and group 14/14 analogues of cyclohexane, as well as for three different pseudo-two-dimensional structures that can be formed from expanding one and two concentric rings around the central one (trans-fused chairs, a rolling combination of trans- and cis-fused chairs, and cis-fused boats). Varying contributions from torsional strain, angle strain, electrostatics, and nontraditional H-H hydrogen bonding lead to different orderings and magnitudes of motif energies in the various systems: Homoatomic SiSi and GeGe systems prefer the trans-fused chair alternative and heteroatomic systems GaN, SiC, and GeC prefer the rolling chair. Decomposition of structure energies into characteristic fragment contributions indicates that pseudo-one-dimensional rods of poly(imidogallane) are thermodynamically more stable than any of the pseudo-two-dimensional structures. 相似文献
969.
Jacquemin D Femenias A Chermette H Ciofini I Adamo C André JM Perpète EA 《The journal of physical chemistry. A》2006,110(17):5952-5959
We have optimized the ground-state geometry of nine series of increasingly long oligomers, using six hybrid density functionals (O3LYP, B3LYP, B97-1, B98, PBE0, and BHHLYP) combined with three different atomic basis sets. In each case, the obtained bond length alternation (BLA) is compared to the corresponding MP2 values. Three phenomenological categories have been set up. In the first, the BLA exponentially decreases, in which case all the tested functionals give results in very good agreement with MP2. In the second category fall the symmetric oligomers that, due to the Peierls theorem, show large BLA. For these chains, BHHLYP tends to give too large and quickly converging BLA wrt chain length, while O3LYP often leads to the opposite misjudgments, and the remaining hybrids provide valuable results. In the third category, one finds asymmetric compounds presenting significantly unequal bond lengths, for which the divergence between DFT and wave function approaches can be dramatic. Indeed, all hybrids yield too small BLA values, especially for long chain lengths. We also study the effect of chain conformation on the BLA. 相似文献
970.
Engstrom K Henry R Hollis LS Kotecki B Marsden I Pu YM Wagaw S Wang W 《The Journal of organic chemistry》2006,71(14):5369-5372
A stereoselective synthesis of the hydroxyethylene dipeptide isostere 1 is described. The route employs a substrate-directed kinetic protonation of an alpha/gamma-substituted lactone to afford the desired stereochemistry. A method for converting the diastereomerically enriched intermediate lactone to the ring-open form with retention of stereochemistry is demonstrated. A novel procedure for utilizing N,N-dibromo-5,5-dimethylhydantoin in Hofmann rearrangements is disclosed. This route was used to prepare amino alcohol 1, the core portion of the HIV protease inhibitor A-792611, in 46% yield from phenylalanine-derived epoxide 2. 相似文献