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61.
Joseph R. Lakowicz Zakir Murtaza Wayne E. Jones Jr. Kihan Kim Henryk Szmacinski 《Journal of fluorescence》1996,6(4):245-249
We report the first observation of polarized emission from a rhenium-phenanthroline complex, Re(CO)3(phen)Cl. Highly luminescent rhenium complexes are known, with quantum yields near 0.5 and lifetimes in excess of 10 s. The detection of polarized emission suggests the use of rhenium complexes as probes of the hydrodynamics of large macromolecular complexes and for use in fluorescence polarization immunoassays with gated detection. 相似文献
62.
Photolysis of complexes of the type M(2)(CO)(6)(RC(5)H(4))(2) (where M = W, Mo, Cr and R = H (Cp) or CH(3) (Cp')) leads to the production of short lived 17-electron radicals. Direct electrochemical characterization of these intermediates has been achieved using a technique known as photomodulated voltammetry (PMV). The results from PMV analysis are in excellent agreement with literature estimates for CpMo(CO)(3)(*) and CpCr(CO)(3)(*). However, CpW(CO)(3)(*) is found to be shifted oxidatively 115 mV relative to previous literature estimates. The change in the value for the tungsten complex changes previous estimates to the bond dissociation energy for tungsten metal hydrides by 3.0 +/- 0.9 kcal/mol. Lifetime information on the radicals is also reported based on the phase shift of the electrochemical signal observed by PMV under limiting current conditions. 相似文献
63.
64.
We prove the existence of periodic solutions of the nonlinear wave equation satisfying either Dirichlet or periodic boundary conditions on the interval [O, π]. The coefficients of the eigenfunction expansion of this equation satisfy a nonlinear functional equation. Using a version of Newton's method, we show that this equation has solutions provided the nonlinearity g(x, u) satisfies certain generic conditions of nonresonance and genuine nonlinearity. © 1993 John Wiley & Sons, Inc. 相似文献
65.
66.
Using recently developed theoretical techniques it has been possible to achieve an exact variational solution of the Schrödinger equation within a modest basis set or one-eleltron functions. The full configuration interaction for this system included a total of 256473 1A1 spin-and space-adapted configurations. Comparison with many-body perturbation theory proves to be quite interesting. 相似文献
67.
Cyrille Ceugniet Ltitia Lepetit Nancy Lauth De Viguerie Henry Jammes Nicole Peyrot Monique Rivire 《Journal of chromatography. A》1998,810(1-2):237-240
A high-performance liquid chromatographic (HPLC) procedure was developed to allow the rapid separation, in a single run, of a mixture of the main retinal isomers (all-trans, 13-cis, 9-cis), all-trans-retinol, and of the two major photooxygenated photoproducts (5,8-peroxyretinal and 5,6-epoxyretinal). The mixture was separated by HPLC on an octadecyl (ODS) column with 16% (v/v) diethyl ether in hexane as mobile phase and anthracene as the internal standard. A commercial type cosmetic formulation containing 0.05% all-trans-retinal was analyzed successfully for this analyte. 相似文献
68.
David M. Dastrup Steven M. Weinreb James R. Henry Andrew J. Lechleiter 《Tetrahedron》2004,60(4):901-906
β-Tosylethylhydrazine (6) can be prepared efficiently in one step from commercially available p-tolyl vinyl sulfone (7) and hydrazine hydrate. This hydrazine reacts with both 1,3-diketones and conjugated ynones in glacial acetic acid to provide a variety of N-tosylethyl-protected (TSE) pyrazoles in good yields. The TSE group can be removed from the pyrazoles using potassium t-butoxide in THF at −30 °C-rt. In addition, hydrazine 6 condenses with β-ketonitriles and β-aminoacrylonitriles to afford 5-aminopyrazoles, which can be deprotected by brief treatment with NaOEt in EtOH/DMSO at 45 °C. 相似文献
69.
The oxidation of uric acid has been studied by thin-layer spectroelectrochemistry using an optically transparent gold minigrid electrode and enzymatically using peroxidase. Under both enzymatic and electrochemical conditions a u.v.-absorbing intermediate (λmax=302–304 nm between pH 7–9.3) is observed. This intermediate is proposed to be an imine-alcohol species formed by rapid hydration of the primary reaction product which is a diimine. Under the conditions employed in both the enzymatic electrochemical studies the imine-alcohol intermediate is hydrated in a first order reaction with an observed rate constant of 3.5×10?3s?1 between pH 7–9.3. This study establishes the similarity between the electrochemical and enzymatic oxidation of uric acid and indicates that electrochemical investigations of the redox behavior of purines can provide unique insights into their biological redox properties. 相似文献
70.
Jakub Kołacz Henry G. Gotjen Robel Y. Bekele Jason D. Myers Jesse A. Frantz Michael Ziemkiewicz 《Liquid crystals》2020,47(4):531-539
ABSTRACTIn a planar dielectric waveguide, weak confinement of a propagating mode in a high index core leads to a measurable evanescent interaction with the cladding. In this work, we study the effect of a reorientable anisotropic cladding on the behaviour of Transverse Electric (TE) and Transverse Magnetic (TM) mode polarisations using a liquid crystal (LC)-clad waveguide architecture. The polarised evanescent field of a guided mode interacts with a voltage-tunable birefringent LC cladding to deflect an out-coupled beam. Experimental measurements are coupled with a theoretical framework and show good consistency with simulation results. We isolate the effect of mode confinement by changing the thickness of the high index core. Interactions between the LC index ellipsoid and the mode polarisation are probed by changing the initial alignment of the LC. Finally, we examine the difference in deflection between TE and TM modes, which incorporates both a change in mode confinement and a difference in LC index components. 相似文献