全文获取类型
收费全文 | 1248篇 |
免费 | 34篇 |
国内免费 | 5篇 |
专业分类
化学 | 836篇 |
晶体学 | 1篇 |
力学 | 45篇 |
数学 | 215篇 |
物理学 | 190篇 |
出版年
2023年 | 7篇 |
2019年 | 11篇 |
2018年 | 14篇 |
2017年 | 12篇 |
2016年 | 26篇 |
2015年 | 29篇 |
2014年 | 26篇 |
2013年 | 62篇 |
2012年 | 54篇 |
2011年 | 49篇 |
2010年 | 28篇 |
2009年 | 31篇 |
2008年 | 48篇 |
2007年 | 48篇 |
2006年 | 41篇 |
2005年 | 39篇 |
2004年 | 42篇 |
2003年 | 37篇 |
2002年 | 52篇 |
2001年 | 16篇 |
2000年 | 17篇 |
1999年 | 16篇 |
1998年 | 15篇 |
1997年 | 13篇 |
1996年 | 13篇 |
1995年 | 13篇 |
1994年 | 12篇 |
1993年 | 15篇 |
1992年 | 22篇 |
1991年 | 12篇 |
1990年 | 21篇 |
1989年 | 8篇 |
1988年 | 22篇 |
1987年 | 13篇 |
1986年 | 12篇 |
1985年 | 27篇 |
1984年 | 24篇 |
1983年 | 29篇 |
1982年 | 21篇 |
1981年 | 16篇 |
1980年 | 29篇 |
1979年 | 22篇 |
1978年 | 26篇 |
1977年 | 26篇 |
1976年 | 32篇 |
1975年 | 16篇 |
1974年 | 17篇 |
1973年 | 10篇 |
1972年 | 9篇 |
1971年 | 7篇 |
排序方式: 共有1287条查询结果,搜索用时 15 毫秒
41.
Henri Cohen. 《Mathematics of Computation》1996,65(216):1681-1699
We show how the usual algorithms valid over Euclidean domains, such as the Hermite Normal Form, the modular Hermite Normal Form and the Smith Normal Form can be extended to Dedekind rings. In a sequel to this paper, we will explain the use of these algorithms for computing in relative extensions of number fields.
42.
Quoc Thong Nguyen Kim Phuc Tran Henri L. Heuchenne Thi Hien Nguyen Huu Du Nguyen 《商业与工业应用随机模型》2019,35(5):1253-1268
In many industrial manufacturing processes, the ratio of the variance to the mean of a quantity of interest is an important characteristic to ensure the quality of the processes. This ratio is called the coefficient of variation (CV). A lot of control charts have been designed for monitoring the CV of univariate quantity in the literature. However, the CV control charts for multivariate quantity have not received much attention yet. In this paper, we investigate a variable sampling interval (VSI) Shewhart control chart for monitoring multivariate CV. The time between two consecutive samples is allowed to vary according to the previous value of the multivariate CV, which will help the chart to detect the process shifts faster. The comparison with the fixed sampling interval Shewhart chart is implemented to highlight the advantage of the VSI method. Finally, an illustrative example is demonstrated on real data. 相似文献
43.
Develay S Tripier R Le Baccon M Patinec V Serratrice G Handel H 《Dalton transactions (Cambridge, England : 2003)》2006,(28):3418-3426
The host-guest interaction between orthophosphate, pyrophosphate and triphosphate anions and three cyclen based macrotricyclic ligands possessing ortho- (TOC), meta- (TMC) and para-xylenyl (TPC) linkers was investigated by potentiometric measurements. The ternary species present in solution and their stability constants have been determined. The different behaviours are explained in terms of hydrogen bond formation and coulombic attraction between the organic host and the inorganic guest. The selectivity, illustrated with species distribution diagrams, is discussed. The results unambiguously showed the importance of the distance between the two cyclen cores and emphasized the increasing of the triphosphate species selectivity together with the cavity size of the ligand. A comparison of the present results with those obtained with their mono-bridged homologues is also discussed. 相似文献
44.
45.
H. K. Barrenscheen Margarete Frey F. Feigl L. T. Fairhall M. Settimj D. Ganassini A. Necke H. Müller Ch. Badham H. B. Taylor G. Moillère F. Weyrauch St. Litzner F. Grendel N. Schoorl H. Begemann A. Berat G. Widmark B. Vahlquist E. M. P. Widmar S. L. Oerskov J. P. Gregersen P. Iversen H. W. Mook D. D. van Sluke W. M. Kirjan W. C. Stadie E. C. Ross K. Lang H. Waelsch Gertrud Klepetar I. St. Lorant L. Kopetz J. W. Heim W. W. Práwdicz-Neminski Z. Babitsch J. F. Reith Th. von Fellenberg R. G. Turner Mina Z. Weeks A. Castille V. Henri 《Analytical and bioanalytical chemistry》1934,98(3-4):147-160
46.
The synthesis, IR, 1H NMR and UV spectra of optically active square pyramidal cyclopentadienyldicarbonyl-molybdenum and -tungsten complexes with Schiff bases, derived from methyl-substituted pyridine carbaldehyde(2) and S-(—)-α-methylbenzylamine, are described. The epimerisation of these complexes, measured polarimetrically at 75–97°C in DMF, follows a 1st order rate law and represents a regular pentatopal skeletal rearrangement. The inductive effect of a methyl group in the para position of a pyridine ring leads to a retardation of the epimerisation compared to unsubstituted complexes. The rate constants decrease even more if an ortho methyl group is introduced into the pyridine system, since additional steric effects are introduced. If the metal complex contains a 4,6-dimethyl-substituted Schiff base as a chelating ligand, the contributions of a 4- and a 6-methyl group are additive. A benzene ring fused to the 5,6-positions of the pyridine system also leads to stabilisation of the configuration. 相似文献
47.
Par Henri Edouard Audier Arielle Milliet Jean-Claude Tabet 《Helvetica chimica acta》1980,63(2):344-358
Isomerization of Protonated Aldehyde and Ketone Ions in the Mass-Spectrography Before the Loss of Water In mass spectrometry, protonated aldehyde and ketone ions isomerize before the loss of a molecule of water. In order to specify this process, the spectra of deuterium labelled protonated aldehydes and ketones have been compared to the spectra of the corresponding isomer ions. 相似文献
48.
Reaction of the 1-substituted-3-cyano-isothioureas 6 with hydroxylamine gave mixtures of the 5-amino-3-substituted-amino-1,2,4-oxadiazoles 1 and the isomeric 3-amino-5-substituted-amino-1,2,4-oxadiazoles 8 in which 1 usually predominated. The structural assignment of these products is discussed. In a second method, the 2-hydroxy-1-methyl-1-phenyl-guanidine 15 was converted to the corresponding 3-disubstituted-amino-5-trichloromethyl-1,2,4-oxadiazole 16 , a precursor to the 5-amino derivatives 17 by nucleophilic displacement of the trichloromethyl group. 相似文献
49.
Schrekker HS Gelesky MA Stracke MP Schrekker CM Machado G Teixeira SR Rubim JC Dupont J 《Journal of colloid and interface science》2007,316(1):189-195
A surface-enhanced Raman spectroscopy (SERS) study of imidazolium ionic liquid stabilized gold(0) nanoparticles (GNPs) furnished previously unknown knowledge about the coordination and stabilization mode of the imidazolium cation. GNPs were prepared by hydrazine reduction of a chloroauric acid solution in 1-triethylene glycol monomethyl ether-3-methylimidazolium methanesulfonate 2 as ether-functionalized room-temperature ionic liquid (RTIL). UV-vis spectroscopy showed the presence of GNP aggregates as absorptions extended to the NIR region. A parallel coordination mode for the imidazolium cation of RTIL 2 on the GNP surface was observed by SERS, which occurred without the simultaneous coordination of the 1-triethylene glycol monomethyl ether-functionality. Instead of this, the ether-functionality was directed away from the GNP surface and acted as steric barrier between the GNPs/GNP aggregates, thus preventing further aggregation. These new insights suggest that the imidazolium cation is responsible for electrosteric stabilization. 相似文献