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41.
42.
B. Wunderlich 《Journal of Thermal Analysis and Calorimetry》1987,32(6):1949-1955
It is shown that it should be possible to construct a single-run heat conduction type DSC that records heat capacity directly, eliminating the present need for three separate runs. A simplified mathematical derivation of the needed computation is given and some suggestions about improved DSC construction are presented.
The work has been supported by a Grant from the Hercules Co. to ATHAS. 相似文献
Zusammenfassung Es wird gezeigt, daß es möglich sein müßte, ein single-run DSC vom Wärmeleittyp zu konstruieren, mit dessen Hilfe man anstelle der bisherigen drei separaten Durchgänge die Wärmekapazität direkt registrieren kann. Es werden für die notwendigen Berechnungen eine vereinfachte mathematische Ableitung und für den Bau des verbesserten DSC einige Anregungen gegeben.
, , , , . .
The work has been supported by a Grant from the Hercules Co. to ATHAS. 相似文献
43.
Kollmar M Steinhagen H Janssen JP Goldfuss B Malinovskaya SA Vázquez J Rominger F Helmchen G 《Chemistry (Weinheim an der Bergstrasse, Germany)》2002,8(14):3103-3114
All possible (eta(3)-allyl)palladium complexes (1-4) of the ligand (4S)-[2-(2'-diphenylphosphanyl)phenyl]-4,5-dihydro-4-(2-propyl)-oxazole (L 1) and eta(3)-allyl ligands with one to three phenyl substituents at the terminal allylic centers were synthesized and characterized by X-ray crystal structure analysis and, with respect to allylic isomers, by NMR investigations. Equilibrium geometries, electronic structures, and relative energies of isomeric complexes were computed by restricted Hartree-Fock (RHF) and density functional theory (DFT) calculations; experimentally determined isomer ratios could be reproduced. The results allowed important conclusions to be drawn regarding the mechanism of Pd-catalyzed asymmetric allylic substitutions. 相似文献
44.
Henning Knutsen 《General Relativity and Gravitation》1984,16(8):777-788
A model for a time-dependent relativistic gas sphere is given. Both pressurep and density are positive inside the outer boundary of the sphere, and they both drop to zero at the boundary itself. Their respective gradients are negative. For expanding models the pressure and the density are decreasing, and for contracting models the pressure and the density are increasing. The adiabatic sound speed is thus real, and for the layers close to the surface of the sphere it is found that the adiabatic sound speed is less than the speed of light. For these layers the condition>3p is also fulfilled. However, the area 4R
2 for a sphere of constantr is not an increasing function of comoving radial coordinater. 相似文献
45.
Automatic computer programs are developed to calculate one- two-, and three-dimensional Debye functions. Prior tables of these functions are critically reviewed. Also, strategies are derived to calculate Debye temperatures from heat capacities. Both, simple three-dimensional Debye analyses and Tarasov analyses were carried out on 35 linear macromolecules. The experimental heat capacities for these analyses were collected in the ATHAS data bank. It is shown that the skeletal heat capacity of linear macromolecules is often best represented by only two vibrations per chain atom. For most of the all-carbon chain macromolecules the intramolecular skeletal heat capacity can be given by Cvs=D1[520 (28/MW)1/2] whereMW is the molecular mass andD
1 represents the one-dimensional Debye function. Polyoxides show a higher intramolecular theta temperature, but a lower intermolecular theta temperature. Double bonds and phenylene groups in the chain increase the intramolecular theta temperature.Dedicated to Prof. Dr. F. H. Müller.On leave from the Lumumba Peoples' Friendship University, Moscow, USSR. 相似文献
46.
J. N. Spencer S. K. Berger C. R. Powell B. D. Henning G. S. Furman W. M. Loffredo E. M. Rydberg R. A. Neubert C. E. Shoop D. N. Blauch 《Journal of solution chemistry》1981,10(7):501-509
Enthalpies of solution and of transfer of amides for the solvents chloroform (CHCl3), methylenechloride (CH2Cl2), carbontetrachloride (CCl4), cyclohexane (C6H12), N,N-dimethylformamide (DMF), N,N-dimethylacetamide (DMA), and ethylacetate (EtOAc) have been used to isolate and quantify the solvation interactions of amides in chlorinated solvents. Specific interactions at the aminde carbonyl and N–H groups have been identified. An analysis of the transfer enthalpies of pyrrole and methylpyrrole from cyclohexane to the chlorinated solvents shows that specific interactions between the pyrroles and these solvents are similar in nature. A means of calculating differences in the transfers of different solutes between the same solvent pair is given.Work done at Lebanon Valley College. 相似文献
47.
J. C. M. Henning J. H. den Boef 《Applied Physics A: Materials Science & Processing》1978,16(4):353-357
A novel method for measuring magnetostriction constants is presented. A strain, periodic in time, applied to the sample, causes a modulation of the ferromagnetic resonance line position. The height of the signal obtained after phase-sensitive detection is proportional to the strain modulation depth. The appropriate magnetostriction constant λ is obtained by comparing the height of the SMFMR signal with that of the FMR line, as recorded by means of magnetic field modulation. Features of the new technique are:
- high sensitivity: λmin? 10?9 forM=100 Oe and linewidth ΔH d=1 Oe;
- λ's belonging to distinct precession modes are separately determined;
- applicable to thin layers for which strain gauge techniques cannot be used;
- wide temperature range: 1.2 K<T<300 K;
- uniform stress.
48.
49.
Frank Seela Ping Ding Xiaohua Peng Henning Eickmeier Hans Reuter 《Acta Crystallographica. Section C, Structural Chemistry》2007,63(10):o600-o602
The title compound, 2,4‐diamino‐5‐bromo‐7‐(2‐deoxy‐2‐fluoro‐β‐d ‐arabinofuranosyl)‐7H‐pyrrolo[2,3‐d]pyrimidine, C11H13BrFN5O3, shows two conformations of the exocyclic C4′—C5′ bond, with the torsion angle γ (O5′—C5′—C4′—C3′) being 170.1 (3)° for conformer 1 (occupancy 0.69) and 60.7 (7)° for conformer 2 (occupancy 0.31). The N‐glycosylic bond exhibits an anti conformation, with χ = −114.8 (4)°. The sugar pucker is N‐type (C3′‐endo; 3T4), with P = 23.3 (4)° and τm = 36.5 (2)°. The compound forms a three‐dimensional network that is stabilized by several intermolecular hydrogen bonds (N—H...O, O—H...N and N—H...Br). 相似文献
50.
A three-dimensional X-ray diffraction study has shown that the product obtained by bromination of
- or
-menthone is 2,4-dibromomenthone [2(a), 6(e)-dibromo-2(e)-isopropyl-5(e)methyl cyclohexanone]. The two Br atoms are trans, and the isopropyl and methyl groups are also trans. There are four molecules in the unit cell, which has symmetry P212121 and dimensions a = 13·58, b = 13·81 and c = 6·25 Å. One intermolecular Br … Br contact of 3·52 ± 0·01 Å occurs, a distance which is about 0·4 Å shorter than the van der Waals distance. 相似文献