Modification and photosensitization of size-quantized particulate CdS film photoelectrodes with bacteriorhodopsin (BR)

Bacteriorhodopsin (BR) was used to modify the surface of a novel size-quantized particulate CdS photoelectrode fabricated by electro-deposition. The photovoltaic features and interfacial electron transfer of the electrodes were studied by surface photovoltaic spectroscopy and a photoelectrochemical method. The results show that BR-modified CdS film photoelectrodes achieve a higher photocurrent yield due to the incorporation of the proton pump BR. On the basis of the observations, the mechanisms of photosensitization and interfacial electron transfer are proposed.     

不同六方氮化硼向立方氮化硼的转化行为

 利用X射线衍射法分析了7种六方氮比硼原料的结晶度、晶粒度和晶格常数，研究了高温高压下六方氮比硼（hBN）向立方氮比硼（cBN）的转化行为和转化率。结果表明，结晶度高和晶粒度细的六方氮化硼易于转化，有利于cBN的成核。     

第二类四阶变分不等式解的存在唯一性

本文考虑弹性力学平板理论中的单侧稳定问题,讨论了重调和方程边值问题及第二类四阶变分不等式,并证明它们的等价性,从而可以把高阶偏微分方程转化为相应的变分不等式加以解决,同时也为求解重调和方程提供了更多的方法和理论依据。并且最后给出了该类变分不等式解的存在唯一性的证明。     

γ辐射引发淀粉目由基衰减的动力学研究

用ESR方法研究了红薯淀粉在y射线预辐照下,产生的淀粉自由基特性及其室温下的自由基衰减动力学反应。结果表明在室温条件下,淀粉自由基的相对浓度随辐射剂量的增大而增加。自由基相对浓度的室温衰减用二级反应动力学处理,求得了衰减速率常数和淀粉自由基反应的半衰期。     

Some results on odd factors of graphs

A {1, 3, …,2n ? 1}-factor of a graph G is defined to be a spanning subgraph of G, each degree of whose vertices is one of {1, 3, …, 2n ? 1}, where n is a positive integer. In this paper, we give a sufficient condition for a graph to have a {1, 3, …, 2n ? 1}-factor.     

Effects of the curvature radius of a cylindrical shell on the stress intensity factors of surface cracks

The effects of the curvature radius of a cylindrical shell on stress intensity factors are investigated in circumferential (inner and outer) semielliptical surface cracks in a cylindrical shell. What is new in this paper is to have given: (1) The stress intensity factors for surface cracks in a cylindircal shell are determined by photoelastic technique. (2) By a special method photoelastic slices are handled for obtaining a clear caustic curve, and the stress intensity factors for surface cracks in a cylindrical shell are determined by the caustic method. (3) An approximate equation of curvature correction factor F_c is proposed. (4) Effects of the curvature radius R of a cylindrical shell on the stress intensity factors of surface cracks are obtained. The results of this paper are in fair agreement with already existing analytical results. The approximate equation of curvature correction factor F_c can be widely used for engineering purposes.     

Effects of radiation crosslinking on structures and properties of SBS triblock copolymer

There is considerable interest in the effect of high energy radiation on triblock copolymer, SBS. Basheer and Dole have done some works about that(Basheer and Dole, 1982). In this paper, we study the effects of radiation crosslinking on the structure and mechanical properties of SBS, about which there have been no reports up to now. The following scientific problems are discussed: The variation of glass transition temperatures with dose; The effects of the ratio of B/S on the gel content; Mechanical properties of the irradiated samples.     

赤霉酸甲酯及其类似物的2D NMR研究

应用¹H-¹H COSY,NOESY,¹³C-¹H COSY等2DNMR和DEPT技术,完成了赤霉酸甲酯(2),13-O-乙酰基赤霉素甲酯(3)及其3位差向异构体(4)的¹H和¹³CNMR化学位移的全指定,并探讨了它们的相对构型,相关质子间的偶合常数也支持所得结果。     

复Monge－Ampere方程的特征值问题

讨论了复空间中强拟凸域上的复Ｍｏｎｇｅ－Ａｍｐｅｒｅ方程的特征值问题，证明了特征值问题解的存在唯一性，并给出了这个特征值与一类复空间中复Ｌａｐｌａｃｅ算子的第一特征值的关系，最后利用特征值及特征函数的存在性讨论了一类复Ｍｏｎｇｅ－Ａｍｐｅｒｅ方程的解的存在性及其分歧．