细胞毒活性二萜Wangzaozin A的晶体结构

采用单晶X射线衍射技术对对映-贝壳杉烷化合物WangzaozinA的晶体结构进行了研究.研究结果表明,在最小不对称单元中存在两个构象稍有差异(键长和键角不同)的分子,其中两者的3个六元环均为椅式构象,而五元环为扭曲信封式构象.WangzaozinA晶体结构属正交晶系,P2₁2₁2₁空间群,晶胞参数a=0.66485(8)nm,b=2.5796(4)nm,c=1.0473(2)nm,Z=4.分子通过分子内氢键O₃-H₃0…O₂和O₃'-H₃0'…O₂'以及分子间氢键O1-H10…O₃,O1'-H10'…O₃',O₂-H₂0…O₄'和O₂'-H₂0'…O₄形成网络结构,并在晶体中沿c轴排列.体外抗肿瘤实验证实,标题化合物具有显著的细胞毒活性,由SRB法测试其抗Bel-7402及HO^-8910细胞株的IC₅₀值分别为(5.32±0.79)和(4.10±1.00)μmol/L.     

离子色谱法测定生产废水中的毕克草

建立了用离子色谱测定毕克草含量的方法。选用NJ-SA-4A型阴离子分析柱,以7.2 mmol/L碳酸钠-1.5 mmol/L碳酸氢钠作淋洗液,流速为1.5 mL/min,电导检测器检测。该方法具有良好的线性关系,精密度高,检出限为0.026 mg/L,两个加标水平下的回收率分别为99.88%和99.78%,相对标准偏差分别为0.27%和0.34%。     

Microwave-assisted Extraction of Rutin and Quercetin from Flos Sophorae

Three microwave-assisted extraction(MAE) procedures were studied. The first procedure was household microwave oven dynamic extraction(HMODE). The second procedure was special microwave oven bath extraction (SMOBE). The third procedure was microwave resonant cavity dynamic extraction (MRCDE). The results obtained by the three microwave-assisted extraction procedures were compared with those obtained by using traditional Soxhlet extraction. The results indicate that the MAE not only took a shorter time, but also simplified the procedure, and made the extraction a higher yield. At the same time the results obtained by the three MAE procedures were also compared with each other.     

三角架结构席夫碱单核稀土配合物的合成、表征以及配体的抗氧化性

三角架结构席夫碱单核稀土配合物的合成、表征以及配体的抗氧化性     

含C60的聚电解质自组装膜微摩擦性能的研究

通过自由基引发溶液聚合反应,合成星状C₆₀-苯乙烯-丙烯酸聚合物,其钠盐作为高聚物负离子,与高聚物正离子的重氮树脂在云母上自组装成膜,利用紫外光照射反应,使膜层间连接的离子键转化成共价键.用原子力显微镜(AFM)和摩擦力显微镜(FFM)研究了不同链长和不同层数自组装膜的表面形貌及微摩擦性能.     

具有周期输入Hopfield型神经网络的全局渐近性质

在不假定非线性激励函数有界和可微的条件下,应用Mawhin的重合度理论及Liapunov函数法给出一类具有周期输入的Hopfield型神经网络存在周期解及其全局指数稳定的充分条件。     

风暴潮流运动的数值模拟

采用风暴潮全流运动方程组,对标准海域的风暴潮流运动进行数值模拟,利用以往的计算结果验证了数值模式,研究了开阔海域中,风暴气压、海域深度及底坡变化对风暴增水及流场的影响,分析了流速、潮位随时间和空间定量变化的规律。所建立的数值模型是进一步研究风暴潮流场中物质输运的基础。     

Aerodynamic force and flow structures of two airfoils in flapping motions

Aerodynamic force and flow structures of two airfoils in a tandem configuration in flapping motions are studied, by solving the Navier-Stokes equations in moving overset grids. Three typical phase differences between the fore- and aftairfoil flapping cycles are considered. It is shown that: (1) in the case of no interaction (single airfoil), the time average of the vertical force coefficient over the downstroke is 2.74, which is about 3 times as large as the maximum steady-state lift coefficient of a dragonfly wing; the time average of the horizontal force coefficient is 1.97, which is also large. The reasons for the large force coefficients are the acceleration at the beginning of a stroke, the delayed stall and the “pitching-up” motion near the end of the stroke. (2) In the cases of two-airfoils, the time-variations of the force and moment coefficients on each airfoil are broadly similar to that of the single airfoil in that the vertical force is mainly produced in downstroke and the horizontal force in upstroke, but very large differences exist due to the interaction. (3) For in-phase stroking, the major differences caused by the interaction are that the vertical force on FA in downstroke is increased and the horizontal force on FA in upstroke decreased. As a result, the magnitude of the resultant force is almost unchanged but it inclines less forward. (4) For counter stroking, the major differences are that the vertical force on AA in downstroke and the horizontal force on FA in upstroke are decreased. As a result, the magnitude of the resultant force is decreased by about 20 percent but its direction is almost unchanged. (5) For 90°-phase-difference stroking, the major differences are that the vertical force on AA in downstroke and the horizontal force on FA in upstroke are decreased greatly and the horizontal force on AA in upstroke increased. As a result, the magnitude of the resultant force is decreased by about 28% and it inclines more forward. (6) Among the three cases of phase angles, inphase flapping produces the largest vertical force (also the largest resultant force); the 90°-phase-difference flapping results in the largest horizontal force, but the smallest resultant force.     

铒掺杂富硅热氧化SiO2/Si发光薄膜的显微结构

利用金属蒸气真空弧 (MEVVA)离子源将稀土元素Er离子掺杂到富硅热氧化SiO2 /Si薄膜中。卢瑟福背散射 (RBS)和X 射线电子能谱仪 (XPS)分析表明 ,Er浓度可达原子百分数 (x)～ 10 ,即Er的原子体浓度为～ 10 2 1·cm-3 。XPS研究发现 ,随着Si注量增大 ,退火态样品表面硅含量增多 ,热氧化硅含量减少。反射式高能电子衍射 (RHEED)和原子灵敏度因子法 (AFM)研究表明 ,样品表面没有大量Er析出或铒硅化物形成 ,退火后表层中Si外延再生长、有针状微晶硅颗粒形成。在 77K及室温下 ,研究了Er掺杂富硅热氧化SiO2 /Si薄膜的近红外区 1 5 4μm附近光致发光光谱     

石墨炉原子吸收法测定土壤中镉的测量不确定度评定

石墨炉原子吸收法测定土壤中镉的不确定度主要来源于称量样品、定容样品消解液、测定样品消解液中镉的质量浓度及测定土壤水分引入的不确定度。对各不确定度分量进行了计算,求得合成标准不确定度和扩展不确定度分别为0.0026、0.005mg/kg。镉测量不确定度的主要来源是测定样品消解液中镉质量浓度引入的不确定度。